Membraneless enzymatic biofuel cells based on graphene nanosheets
The possibility of employing graphene sheets as a potential candidate for the construction of biofuel cells is reported in this paper. Initially, graphene sheets were chemically synthesized and characterized by surface characterization techniques. Following this, graphene was employed to fabricate t...
Gespeichert in:
| Veröffentlicht in: | Biosensors & bioelectronics 2010-03, Vol.25 (7), p.1829-1833 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1833 |
|---|---|
| container_issue | 7 |
| container_start_page | 1829 |
| container_title | Biosensors & bioelectronics |
| container_volume | 25 |
| creator | Liu, Chang Alwarappan, Subbiah Chen, Zhongfang Kong, Xiangxing Li, Chen-Zhong |
| description | The possibility of employing graphene sheets as a potential candidate for the construction of biofuel cells is reported in this paper. Initially, graphene sheets were chemically synthesized and characterized by surface characterization techniques. Following this, graphene was employed to fabricate the anode and cathode in the biofuel cell. The anode of the biofuel cell consists of a gold electrode on which we co-immobilized graphene – glucose oxidase using silica sol–gel matrix. Voltammetric measurements were conducted to quantitatively evaluate the suitability of employing graphene sheets as an electrode dopant and its performance was compared with single walled carbon nanotubes (SWCNTs). The cathode of the biofuel cell was constructed in a similar method except that graphene was co-immobilized with bilirubin oxidase. Finally, two membraneless enzymatic biofuel cells, one using graphene sheets and the other using SWCNTs, were constructed and their performances were compared. Upon comparison, graphene based biofuel cell exhibited a maximum power density of about 24.3±4μW (N=3), which is nearly two times greater than that of the SWCNTs biofuel cell, and the performance of the graphene biofuel cell lasted for 7 days. |
| doi_str_mv | 10.1016/j.bios.2009.12.012 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_877573841</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0956566309006630</els_id><sourcerecordid>877573841</sourcerecordid><originalsourceid>FETCH-LOGICAL-c417t-197593250663dcb377d25e7a05166fdbb89bbe95c4d40a2492a2355f22119e583</originalsourceid><addsrcrecordid>eNqFkE1P3DAURS3UCqa0f6ALlE3FKumzHcexxAahUiqBuoG1ZTsvxaN8DH6ZSvDr69FMy46u3ubcq_sOY585VBx483Vd-ThTJQBMxUUFXByxFW-1LGsh1Tu2AqOaUjWNPGEfiNYAoLmBY3aSI6qpQa7Y5R2OPrkJByQqcHp5Ht0SQ5Gb-y0ORcBhoMI7wq6Yp-JXcptHnLCY3DTTI-JCH9n73g2Enw73lD1cf7u_uilvf37_cXV5W4aa66XkRisjhYI8pwteat0JhdqB4k3Td963xns0KtRdDU7URrj8hOqF4NygauUpO9_3btL8tEVa7BhpNy-Pn7dkW62Vlm3N_0tqKZWQrYBMij0Z0kyUsLebFEeXni0Hu3Ns13bn2O4cWy5sdpxDZ4f6rR-x-xf5KzUDXw6Ao-CGPusNkV450UC2YTJ3secwa_sdMVkKEaeAXUwYFtvN8a0dfwDeZZij</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>733523820</pqid></control><display><type>article</type><title>Membraneless enzymatic biofuel cells based on graphene nanosheets</title><source>MEDLINE</source><source>Elsevier ScienceDirect Journals</source><creator>Liu, Chang ; Alwarappan, Subbiah ; Chen, Zhongfang ; Kong, Xiangxing ; Li, Chen-Zhong</creator><creatorcontrib>Liu, Chang ; Alwarappan, Subbiah ; Chen, Zhongfang ; Kong, Xiangxing ; Li, Chen-Zhong</creatorcontrib><description>The possibility of employing graphene sheets as a potential candidate for the construction of biofuel cells is reported in this paper. Initially, graphene sheets were chemically synthesized and characterized by surface characterization techniques. Following this, graphene was employed to fabricate the anode and cathode in the biofuel cell. The anode of the biofuel cell consists of a gold electrode on which we co-immobilized graphene – glucose oxidase using silica sol–gel matrix. Voltammetric measurements were conducted to quantitatively evaluate the suitability of employing graphene sheets as an electrode dopant and its performance was compared with single walled carbon nanotubes (SWCNTs). The cathode of the biofuel cell was constructed in a similar method except that graphene was co-immobilized with bilirubin oxidase. Finally, two membraneless enzymatic biofuel cells, one using graphene sheets and the other using SWCNTs, were constructed and their performances were compared. Upon comparison, graphene based biofuel cell exhibited a maximum power density of about 24.3±4μW (N=3), which is nearly two times greater than that of the SWCNTs biofuel cell, and the performance of the graphene biofuel cell lasted for 7 days.</description><identifier>ISSN: 0956-5663</identifier><identifier>EISSN: 1873-4235</identifier><identifier>DOI: 10.1016/j.bios.2009.12.012</identifier><identifier>PMID: 20056403</identifier><language>eng</language><publisher>Kidlington: Elsevier B.V</publisher><subject>Bacterial Physiological Phenomena ; Bioelectric Energy Sources - microbiology ; Biofuel cell ; Biological and medical sciences ; Biomedical device ; Biotechnology ; Enzyme ; Equipment Design ; Equipment Failure Analysis ; Fundamental and applied biological sciences. Psychology ; Glucose ; Glucose - chemistry ; Graphene nanosheets ; Graphite - chemistry ; Membranes, Artificial ; Miniaturized power source ; Nanostructures - chemistry ; Nanostructures - ultrastructure ; Nanotubes, Carbon - chemistry ; Nanotubes, Carbon - ultrastructure ; Sol–gel</subject><ispartof>Biosensors & bioelectronics, 2010-03, Vol.25 (7), p.1829-1833</ispartof><rights>2009 Elsevier B.V.</rights><rights>2015 INIST-CNRS</rights><rights>(c) 2009 Elsevier B.V. All rights reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c417t-197593250663dcb377d25e7a05166fdbb89bbe95c4d40a2492a2355f22119e583</citedby><cites>FETCH-LOGICAL-c417t-197593250663dcb377d25e7a05166fdbb89bbe95c4d40a2492a2355f22119e583</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0956566309006630$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=22601979$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/20056403$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Liu, Chang</creatorcontrib><creatorcontrib>Alwarappan, Subbiah</creatorcontrib><creatorcontrib>Chen, Zhongfang</creatorcontrib><creatorcontrib>Kong, Xiangxing</creatorcontrib><creatorcontrib>Li, Chen-Zhong</creatorcontrib><title>Membraneless enzymatic biofuel cells based on graphene nanosheets</title><title>Biosensors & bioelectronics</title><addtitle>Biosens Bioelectron</addtitle><description>The possibility of employing graphene sheets as a potential candidate for the construction of biofuel cells is reported in this paper. Initially, graphene sheets were chemically synthesized and characterized by surface characterization techniques. Following this, graphene was employed to fabricate the anode and cathode in the biofuel cell. The anode of the biofuel cell consists of a gold electrode on which we co-immobilized graphene – glucose oxidase using silica sol–gel matrix. Voltammetric measurements were conducted to quantitatively evaluate the suitability of employing graphene sheets as an electrode dopant and its performance was compared with single walled carbon nanotubes (SWCNTs). The cathode of the biofuel cell was constructed in a similar method except that graphene was co-immobilized with bilirubin oxidase. Finally, two membraneless enzymatic biofuel cells, one using graphene sheets and the other using SWCNTs, were constructed and their performances were compared. Upon comparison, graphene based biofuel cell exhibited a maximum power density of about 24.3±4μW (N=3), which is nearly two times greater than that of the SWCNTs biofuel cell, and the performance of the graphene biofuel cell lasted for 7 days.</description><subject>Bacterial Physiological Phenomena</subject><subject>Bioelectric Energy Sources - microbiology</subject><subject>Biofuel cell</subject><subject>Biological and medical sciences</subject><subject>Biomedical device</subject><subject>Biotechnology</subject><subject>Enzyme</subject><subject>Equipment Design</subject><subject>Equipment Failure Analysis</subject><subject>Fundamental and applied biological sciences. Psychology</subject><subject>Glucose</subject><subject>Glucose - chemistry</subject><subject>Graphene nanosheets</subject><subject>Graphite - chemistry</subject><subject>Membranes, Artificial</subject><subject>Miniaturized power source</subject><subject>Nanostructures - chemistry</subject><subject>Nanostructures - ultrastructure</subject><subject>Nanotubes, Carbon - chemistry</subject><subject>Nanotubes, Carbon - ultrastructure</subject><subject>Sol–gel</subject><issn>0956-5663</issn><issn>1873-4235</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkE1P3DAURS3UCqa0f6ALlE3FKumzHcexxAahUiqBuoG1ZTsvxaN8DH6ZSvDr69FMy46u3ubcq_sOY585VBx483Vd-ThTJQBMxUUFXByxFW-1LGsh1Tu2AqOaUjWNPGEfiNYAoLmBY3aSI6qpQa7Y5R2OPrkJByQqcHp5Ht0SQ5Gb-y0ORcBhoMI7wq6Yp-JXcptHnLCY3DTTI-JCH9n73g2Enw73lD1cf7u_uilvf37_cXV5W4aa66XkRisjhYI8pwteat0JhdqB4k3Td963xns0KtRdDU7URrj8hOqF4NygauUpO9_3btL8tEVa7BhpNy-Pn7dkW62Vlm3N_0tqKZWQrYBMij0Z0kyUsLebFEeXni0Hu3Ns13bn2O4cWy5sdpxDZ4f6rR-x-xf5KzUDXw6Ao-CGPusNkV450UC2YTJ3secwa_sdMVkKEaeAXUwYFtvN8a0dfwDeZZij</recordid><startdate>20100315</startdate><enddate>20100315</enddate><creator>Liu, Chang</creator><creator>Alwarappan, Subbiah</creator><creator>Chen, Zhongfang</creator><creator>Kong, Xiangxing</creator><creator>Li, Chen-Zhong</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7QO</scope><scope>8FD</scope><scope>FR3</scope><scope>P64</scope></search><sort><creationdate>20100315</creationdate><title>Membraneless enzymatic biofuel cells based on graphene nanosheets</title><author>Liu, Chang ; Alwarappan, Subbiah ; Chen, Zhongfang ; Kong, Xiangxing ; Li, Chen-Zhong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c417t-197593250663dcb377d25e7a05166fdbb89bbe95c4d40a2492a2355f22119e583</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Bacterial Physiological Phenomena</topic><topic>Bioelectric Energy Sources - microbiology</topic><topic>Biofuel cell</topic><topic>Biological and medical sciences</topic><topic>Biomedical device</topic><topic>Biotechnology</topic><topic>Enzyme</topic><topic>Equipment Design</topic><topic>Equipment Failure Analysis</topic><topic>Fundamental and applied biological sciences. Psychology</topic><topic>Glucose</topic><topic>Glucose - chemistry</topic><topic>Graphene nanosheets</topic><topic>Graphite - chemistry</topic><topic>Membranes, Artificial</topic><topic>Miniaturized power source</topic><topic>Nanostructures - chemistry</topic><topic>Nanostructures - ultrastructure</topic><topic>Nanotubes, Carbon - chemistry</topic><topic>Nanotubes, Carbon - ultrastructure</topic><topic>Sol–gel</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liu, Chang</creatorcontrib><creatorcontrib>Alwarappan, Subbiah</creatorcontrib><creatorcontrib>Chen, Zhongfang</creatorcontrib><creatorcontrib>Kong, Xiangxing</creatorcontrib><creatorcontrib>Li, Chen-Zhong</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Biotechnology Research Abstracts</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Biotechnology and BioEngineering Abstracts</collection><jtitle>Biosensors & bioelectronics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liu, Chang</au><au>Alwarappan, Subbiah</au><au>Chen, Zhongfang</au><au>Kong, Xiangxing</au><au>Li, Chen-Zhong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Membraneless enzymatic biofuel cells based on graphene nanosheets</atitle><jtitle>Biosensors & bioelectronics</jtitle><addtitle>Biosens Bioelectron</addtitle><date>2010-03-15</date><risdate>2010</risdate><volume>25</volume><issue>7</issue><spage>1829</spage><epage>1833</epage><pages>1829-1833</pages><issn>0956-5663</issn><eissn>1873-4235</eissn><abstract>The possibility of employing graphene sheets as a potential candidate for the construction of biofuel cells is reported in this paper. Initially, graphene sheets were chemically synthesized and characterized by surface characterization techniques. Following this, graphene was employed to fabricate the anode and cathode in the biofuel cell. The anode of the biofuel cell consists of a gold electrode on which we co-immobilized graphene – glucose oxidase using silica sol–gel matrix. Voltammetric measurements were conducted to quantitatively evaluate the suitability of employing graphene sheets as an electrode dopant and its performance was compared with single walled carbon nanotubes (SWCNTs). The cathode of the biofuel cell was constructed in a similar method except that graphene was co-immobilized with bilirubin oxidase. Finally, two membraneless enzymatic biofuel cells, one using graphene sheets and the other using SWCNTs, were constructed and their performances were compared. Upon comparison, graphene based biofuel cell exhibited a maximum power density of about 24.3±4μW (N=3), which is nearly two times greater than that of the SWCNTs biofuel cell, and the performance of the graphene biofuel cell lasted for 7 days.</abstract><cop>Kidlington</cop><pub>Elsevier B.V</pub><pmid>20056403</pmid><doi>10.1016/j.bios.2009.12.012</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0956-5663 |
| ispartof | Biosensors & bioelectronics, 2010-03, Vol.25 (7), p.1829-1833 |
| issn | 0956-5663 1873-4235 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_877573841 |
| source | MEDLINE; Elsevier ScienceDirect Journals |
| subjects | Bacterial Physiological Phenomena Bioelectric Energy Sources - microbiology Biofuel cell Biological and medical sciences Biomedical device Biotechnology Enzyme Equipment Design Equipment Failure Analysis Fundamental and applied biological sciences. Psychology Glucose Glucose - chemistry Graphene nanosheets Graphite - chemistry Membranes, Artificial Miniaturized power source Nanostructures - chemistry Nanostructures - ultrastructure Nanotubes, Carbon - chemistry Nanotubes, Carbon - ultrastructure Sol–gel |
| title | Membraneless enzymatic biofuel cells based on graphene nanosheets |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-08T08%3A20%3A49IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Membraneless%20enzymatic%20biofuel%20cells%20based%20on%20graphene%20nanosheets&rft.jtitle=Biosensors%20&%20bioelectronics&rft.au=Liu,%20Chang&rft.date=2010-03-15&rft.volume=25&rft.issue=7&rft.spage=1829&rft.epage=1833&rft.pages=1829-1833&rft.issn=0956-5663&rft.eissn=1873-4235&rft_id=info:doi/10.1016/j.bios.2009.12.012&rft_dat=%3Cproquest_cross%3E877573841%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=733523820&rft_id=info:pmid/20056403&rft_els_id=S0956566309006630&rfr_iscdi=true |