Rational Catalysis Design on the Basis of Mechanistic Understanding: Highly Efficient Pd-Catalyzed Cyanation of Aryl Bromides with NaCN in Recyclable Solvents

Rational catalysis design on the basis of a detailed mechanistic understanding has been used to successfully develop the first efficient general Pd-catalyzed aromatic cyanation reaction under the highly sought after practicable conditions: (i) MCN (M = Na or K) as a cyanide source; (ii) low-boiling...

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Veröffentlicht in:	Journal of the American Chemical Society 2011-07, Vol.133 (28), p.10999-11005
Hauptverfasser:	Ushkov, Alexander V, Grushin, Vladimir V
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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