Reversible Tuning of the Wettability of Carbon Nanotube Arrays: The Effect of Ultraviolet/Ozone and Vacuum Pyrolysis Treatments

Among diverse types of synthetic materials, arrays of vertically aligned carbon nanotubes have attracted the most attention, mainly because of their exceptional mechanical, electrical, optical, and thermal properties. However, their wetting properties are yet to be understood. In this present study,...

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Veröffentlicht in:Langmuir 2011-07, Vol.27 (14), p.9005-9011
Hauptverfasser: Aria, Adrianus I, Gharib, Morteza
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Gharib, Morteza
description Among diverse types of synthetic materials, arrays of vertically aligned carbon nanotubes have attracted the most attention, mainly because of their exceptional mechanical, electrical, optical, and thermal properties. However, their wetting properties are yet to be understood. In this present study, oxygenated surface functional groups have been identified as a vital factor in controlling the wetting properties of carbon nanotube arrays. The results presented herein indeed show that a combination of ultraviolet/ozone and vacuum pyrolysis treatments can be used to vary the surface concentration of these functional groups such that the carbon nanotube array can be repeatedly switched between hydrophilic and hydrophobic.
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subjects Chemistry
Exact sciences and technology
General and physical chemistry
Materials: Nano-and Mesostructured Materials, Polymers, Gels, Liquid Crystals, Composites
Models, Molecular
Molecular Conformation
Nanotechnology - instrumentation
Nanotubes, Carbon - chemistry
Oxidation-Reduction
Ozone - chemistry
Solid-liquid interface
Surface physical chemistry
Temperature
Time Factors
Ultraviolet Rays
Wettability
title Reversible Tuning of the Wettability of Carbon Nanotube Arrays: The Effect of Ultraviolet/Ozone and Vacuum Pyrolysis Treatments
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