Multi-residual GC-MS determination of personal care products in waters using solid-phase microextraction
A multi-residual method is described for the simultaneous determination of 23 personal care products (PCPs), which display a wide range of physicochemical properties, present at trace levels in water samples. A one-step procedure was developed based on solid-phase microextraction (SPME) coupled with...
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| Veröffentlicht in: | Analytical and bioanalytical chemistry 2011-02, Vol.399 (6), p.2257-2265 |
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| creator | Basaglia, G Pasti, L Pietrogrande, M. C |
| description | A multi-residual method is described for the simultaneous determination of 23 personal care products (PCPs), which display a wide range of physicochemical properties, present at trace levels in water samples. A one-step procedure was developed based on solid-phase microextraction (SPME) coupled with GC-MS analysis. A chemometric approach consisting of an experimental design (design of experiments) was applied to systematically investigate how four operating parameters--extraction temperature and time and desorption temperature and time--affect extraction recovery of PCPs in water. The optimum SPME procedure operating conditions, those yielding the highest extraction recovery for all the compounds, were determined; they correspond to an extraction time of 90 min and temperature of 80 °C and a desorption time of 11 min and temperature of 260 °C. Under these optimized conditions, the SPME procedure shows good analytical performance characterized by high reproducibility (RSD% intra-day accuracy varying in the 0.01-1.3% range) as well as good linearity and low detection limits (LODs lower than 2 ppb for most of the investigated PCPs). [graphic removed] |
| doi_str_mv | 10.1007/s00216-010-4609-4 |
| format | Article |
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Under these optimized conditions, the SPME procedure shows good analytical performance characterized by high reproducibility (RSD% intra-day accuracy varying in the 0.01-1.3% range) as well as good linearity and low detection limits (LODs lower than 2 ppb for most of the investigated PCPs). 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C</creatorcontrib><title>Multi-residual GC-MS determination of personal care products in waters using solid-phase microextraction</title><title>Analytical and bioanalytical chemistry</title><addtitle>Anal Bioanal Chem</addtitle><addtitle>Anal Bioanal Chem</addtitle><description>A multi-residual method is described for the simultaneous determination of 23 personal care products (PCPs), which display a wide range of physicochemical properties, present at trace levels in water samples. A one-step procedure was developed based on solid-phase microextraction (SPME) coupled with GC-MS analysis. A chemometric approach consisting of an experimental design (design of experiments) was applied to systematically investigate how four operating parameters--extraction temperature and time and desorption temperature and time--affect extraction recovery of PCPs in water. The optimum SPME procedure operating conditions, those yielding the highest extraction recovery for all the compounds, were determined; they correspond to an extraction time of 90 min and temperature of 80 °C and a desorption time of 11 min and temperature of 260 °C. Under these optimized conditions, the SPME procedure shows good analytical performance characterized by high reproducibility (RSD% intra-day accuracy varying in the 0.01-1.3% range) as well as good linearity and low detection limits (LODs lower than 2 ppb for most of the investigated PCPs). [graphic removed]</description><subject>Analysis</subject><subject>Analytical Chemistry</subject><subject>Biochemistry</subject><subject>Causes of</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chromatographic methods and physical methods associated with chromatography</subject><subject>Cosmetics - analysis</subject><subject>Cosmetics - isolation & purification</subject><subject>Design engineering</subject><subject>Design of experiments</subject><subject>Desorption</subject><subject>Environmental aspects</subject><subject>Equipment and supplies</subject><subject>Exact sciences and technology</subject><subject>Extraction</subject><subject>Extraction (Chemistry)</subject><subject>Food Science</subject><subject>Gas chromatographic methods</subject><subject>Gas chromatography</subject><subject>Gas Chromatography-Mass Spectrometry</subject><subject>Health and beauty aids</subject><subject>Hygiene products</subject><subject>Laboratory Medicine</subject><subject>Mass spectrometry</subject><subject>Mathematical analysis</subject><subject>Methods</subject><subject>Monitoring/Environmental Analysis</subject><subject>Multi-residue method</subject><subject>Optimization</subject><subject>Organic water pollutants</subject><subject>Original Paper</subject><subject>personal care products</subject><subject>Recovery</subject><subject>Reproducibility</subject><subject>Response surface model</subject><subject>Solid Phase Microextraction - methods</subject><subject>Solid-phase microextraction</subject><subject>Spectrometric and optical methods</subject><subject>Water Pollutants, Chemical - analysis</subject><subject>Water Pollutants, Chemical - isolation & purification</subject><issn>1618-2642</issn><issn>1618-2650</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkk9vFSEUxSdGY2v1A7hREmN0Q738n1k2L1pN2rioXROGgVeaefCEmVS_vUzmWWNialhA4HcOl8tpmpcETgmA-lAAKJEYCGAuocP8UXNMJGkxlQIe3685PWqelXILQERL5NPmiBJKieDiuLm5nMcp4OxKGGYzovMNvrxCg5tc3oVoppAiSh7tXS4p1nNrskP7nIbZTgWFiO5MRQuaS4hbVNIYBry_McWhXbA5uR9TNnZxed488WYs7sVhPmmuP338tvmML76ef9mcXWAraDdh4gZgjErwVBkDnnfQD13vrfOgRN8OVlrlGW9V3zNphPeUcds7oZSAKmAnzbvVtxb5fXZl0rtQrBtHE12ai26VpJRJzv9PChCiI5RV8v2DJFGcKwK1qoq-WdGtGZ0O0aelAQuuz1inqqEkXaVO_0HVMbjathSdD3X_LwFZBbWnpWTn9T6Hnck_NQG9ZEGvWdA1C3rJgl7e9-pQ9dzv3HCv-P35FXh7AEyxZvTZRBvKH461UkgmK0dXrtSjuHVZ36Y51zSUB29_vYq8SdpsczW-vqJAGJCO16Yq9gvdgtPv</recordid><startdate>20110201</startdate><enddate>20110201</enddate><creator>Basaglia, G</creator><creator>Pasti, L</creator><creator>Pietrogrande, M. 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A chemometric approach consisting of an experimental design (design of experiments) was applied to systematically investigate how four operating parameters--extraction temperature and time and desorption temperature and time--affect extraction recovery of PCPs in water. The optimum SPME procedure operating conditions, those yielding the highest extraction recovery for all the compounds, were determined; they correspond to an extraction time of 90 min and temperature of 80 °C and a desorption time of 11 min and temperature of 260 °C. Under these optimized conditions, the SPME procedure shows good analytical performance characterized by high reproducibility (RSD% intra-day accuracy varying in the 0.01-1.3% range) as well as good linearity and low detection limits (LODs lower than 2 ppb for most of the investigated PCPs). 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| subjects | Analysis Analytical Chemistry Biochemistry Causes of Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Chromatographic methods and physical methods associated with chromatography Cosmetics - analysis Cosmetics - isolation & purification Design engineering Design of experiments Desorption Environmental aspects Equipment and supplies Exact sciences and technology Extraction Extraction (Chemistry) Food Science Gas chromatographic methods Gas chromatography Gas Chromatography-Mass Spectrometry Health and beauty aids Hygiene products Laboratory Medicine Mass spectrometry Mathematical analysis Methods Monitoring/Environmental Analysis Multi-residue method Optimization Organic water pollutants Original Paper personal care products Recovery Reproducibility Response surface model Solid Phase Microextraction - methods Solid-phase microextraction Spectrometric and optical methods Water Pollutants, Chemical - analysis Water Pollutants, Chemical - isolation & purification |
| title | Multi-residual GC-MS determination of personal care products in waters using solid-phase microextraction |
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