Distinguishing Homogeneous from Heterogeneous Catalysis in Electrode-Driven Water Oxidation with Molecular Iridium Complexes

Molecular water-oxidation catalysts can deactivate by side reactions or decompose to secondary materials over time due to the harsh, oxidizing conditions required to drive oxygen evolution. Distinguishing electrode surface-bound heterogeneous catalysts (such as iridium oxide) from homogeneous molecu...

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Veröffentlicht in:	Journal of the American Chemical Society 2011-07, Vol.133 (27), p.10473-10481
Hauptverfasser:	Schley, Nathan D, Blakemore, James D, Subbaiyan, Navaneetha K, Incarvito, Christopher D, D’Souza, Francis, Crabtree, Robert H, Brudvig, Gary W
Format:	Artikel
Sprache:	eng
Schlagworte:	catalysis (homogeneous), catalysis (heterogeneous), solar (photovoltaic), solar (fuels), photosynthesis (natural and artificial), bio-inspired, hydrogen and fuel cells, electrodes - solar, defects, charge transport, spin dynamics, membrane, materials and chemistry by design, optics, synthesis (novel materials), synthesis (self-assembly)
Online-Zugang:	Volltext
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