On Intermolecular Dipolar Coupling in Two Strongly Polar Liquids: Dimethyl Sulfoxide and Acetonitrile

The paper presents the results of studies of the electric and dielectric properties of dimethyl sulfoxide (DMSO) and acetonitrile (ACN), two strongly polar liquids composed of the molecules of the same dipole moment value (μ ≈ 4 D) but of a quite different static dielectric permittivity (εS DMSO ≫ ε...

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Veröffentlicht in:	The journal of physical chemistry. B 2011-05, Vol.115 (20), p.6623-6628
Hauptverfasser:	Jadzyn, Jan, Swiergiel, Jolanta
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetonitriles - chemistry B: Statistical Mechanics, Thermodynamics, Medium Effects Dimethyl Sulfoxide - chemistry Electric Capacitance Models, Chemical Models, Molecular Temperature
Online-Zugang:	Volltext
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