Asymmetric hydrogenation of alkenes lacking coordinating groups

Asymmetric hydrogenation of alkenes lacking coordinating groups

Asymmetric hydrogenation of olefins is one of the most important reactions for the synthesis of optically active compounds, especially in industry. Chiral iridium catalysts based on P,N ligands have strongly expanded their application range. In contrast to rhodium and ruthenium diphosphine complexes...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2011-07, Vol.47 (28), p.7912-7916
Hauptverfasser: Woodmansee, David H, Pfaltz, Andreas
Format: Artikel
Sprache:eng
Schlagworte:
Alkenes
Asymmetry
Bonding
Hydrogenation
Ligands
Optical activity
Rhodium
Ruthenium
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container_title Chemical communications (Cambridge, England)
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creator Woodmansee, David H
Pfaltz, Andreas
description Asymmetric hydrogenation of olefins is one of the most important reactions for the synthesis of optically active compounds, especially in industry. Chiral iridium catalysts based on P,N ligands have strongly expanded their application range. In contrast to rhodium and ruthenium diphosphine complexes they do not require the presence of a coordinating group near the C=C bond and, therefore, allow highly enantioselective hydrogenations of largely unfunctionalized alkenes.
doi_str_mv 10.1039/c1cc11430a
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Alkenes
Asymmetry
Bonding
Hydrogenation
Ligands
Optical activity
Rhodium
Ruthenium
title Asymmetric hydrogenation of alkenes lacking coordinating groups
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