Copper-Catalyzed Tandem Reaction of Isocyanides with N-(2-Haloaryl)propiolamides for the Synthesis of Pyrrolo[3,2-c]quinolin-4-ones

The copper-catalyzed tandem reaction of isocyanides with N-(2-haloaryl)propiolamides is very efficient for the synthesis of pyrrolo[3, 2-c]quinolin-4-ones. Highly reactive cyclic organocopper intermediates were proposed to be generated in the copper-catalyzed formal [3 + 2] cycloaddition reaction of...

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Veröffentlicht in:	Journal of organic chemistry 2011-07, Vol.76 (13), p.5346-5353
Hauptverfasser:	Zhou, Fengtao, Liu, Jianguang, Ding, Ke, Liu, Jinsong, Cai, Qian
Format:	Artikel
Sprache:	eng
Schlagworte:	4-Quinolones - chemical synthesis 4-Quinolones - chemistry Amides - chemistry Catalysis Chemistry Copper - chemistry Cyanides - chemistry Exact sciences and technology Heterocyclic compounds Heterocyclic compounds with only one n hetero atom and condensed derivatives Heterocyclic compounds with several n hetero atoms in the same ring, in separated rings or in fused rings Molecular Structure Organic chemistry Preparations and properties Stereoisomerism
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