Ruthenium Catalysts Containing Rigid Chiral Diamines and Achiral Diphosphanes for Highly Enantioselective Hydrogenation of Aromatic Ketones

Ruthenium Catalysts Containing Rigid Chiral Diamines and Achiral Diphosphanes for Highly Enantioselective Hydrogenation of Aromatic Ketones

One chiral element is enough: A new ruthenium catalyst containing a rigid chiral diamine (BIDN) and a commercially available inexpensive achiral phosphane (DPPF) is highly efficient for the enantioselective hydrogenation of ketones (see scheme). High reactivity (S/C up to 100 000) and excellent enan...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemistry : a European journal 2011-07, Vol.17 (28), p.7760-7763
Hauptverfasser: Zhu, Qiming, Shi, Dengjian, Xia, Chungu, Huang, Hanmin
Format: Artikel
Sprache:eng
Schlagworte:
achiral phosphanes
Catalysis
Catalysts
Chemistry
Diamines
enantioselectivity
Hydrogenation
Ketones
Ruthenium
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 7763
container_issue 28
container_start_page 7760
container_title Chemistry : a European journal
container_volume 17
creator Zhu, Qiming
Shi, Dengjian
Xia, Chungu
Huang, Hanmin
description One chiral element is enough: A new ruthenium catalyst containing a rigid chiral diamine (BIDN) and a commercially available inexpensive achiral phosphane (DPPF) is highly efficient for the enantioselective hydrogenation of ketones (see scheme). High reactivity (S/C up to 100 000) and excellent enantioselectivities (up to 99 % ee) were obtained.
doi_str_mv 10.1002/chem.201100820
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_873492627</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1800489020</sourcerecordid><originalsourceid>FETCH-LOGICAL-c4430-a3650b891bc0a7fc505a0edc0fb771ebe1d8cc24f98e3d8678bda33b8250fab13</originalsourceid><addsrcrecordid>eNqFkUGP0zAQhSMEYsvClSOyxAEuKeM4sZ1jN5QtUEBaQBwtx3EaL4ld7ATIb-BP46q7FeIAp9HMfO9JTy9JHmNYYoDsher0sMwAx4VncCdZ4CLDKWG0uJssoMxZSgtSniUPQrgGgJIScj85yzDFnBK6SH5dTWOnrZkGVMlR9nMYA6qcHaWxxu7QldmZBlWd8bJHL40cjNUBSduglbo97jsX9p08PFrn0cbsun5GayvtaFzQvVaj-a7RZm6822kr49Ui16KVd0NcFHqrRxfVD5N7reyDfnQzz5PPr9afqk26_XD5ulptU5XnBFJJaAE1L3GtQLJWFVBI0I2CtmYM61rjhiuV5W3JNWk4ZbxuJCE1zwpoZY3JefLs6Lv37tukwygGE5Tu-xjBTUFwRvIyoxmL5PN_kpgD5LyEDCL69C_02k3exhwCM0opxjmjkVoeKeVdCF63Yu_NIP0sMIhDoeJQqDgVGgVPbmynetDNCb9tMALlEfhhej3_x05Um_W7P83To9aEUf88aaX_KigjrBBf3l-Ki5Llby7wR7ElvwEtrb2L</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1766611476</pqid></control><display><type>article</type><title>Ruthenium Catalysts Containing Rigid Chiral Diamines and Achiral Diphosphanes for Highly Enantioselective Hydrogenation of Aromatic Ketones</title><source>Wiley Online Library Journals Frontfile Complete</source><creator>Zhu, Qiming ; Shi, Dengjian ; Xia, Chungu ; Huang, Hanmin</creator><creatorcontrib>Zhu, Qiming ; Shi, Dengjian ; Xia, Chungu ; Huang, Hanmin</creatorcontrib><description>One chiral element is enough: A new ruthenium catalyst containing a rigid chiral diamine (BIDN) and a commercially available inexpensive achiral phosphane (DPPF) is highly efficient for the enantioselective hydrogenation of ketones (see scheme). High reactivity (S/C up to 100 000) and excellent enantioselectivities (up to 99 % ee) were obtained.</description><identifier>ISSN: 0947-6539</identifier><identifier>EISSN: 1521-3765</identifier><identifier>DOI: 10.1002/chem.201100820</identifier><identifier>PMID: 21618636</identifier><identifier>CODEN: CEUJED</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>achiral phosphanes ; Catalysis ; Catalysts ; Chemistry ; Diamines ; enantioselectivity ; Hydrogenation ; Ketones ; Ruthenium</subject><ispartof>Chemistry : a European journal, 2011-07, Vol.17 (28), p.7760-7763</ispartof><rights>Copyright © 2011 WILEY‐VCH Verlag GmbH &amp; Co. KGaA, Weinheim</rights><rights>Copyright © 2011 WILEY-VCH Verlag GmbH &amp; Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4430-a3650b891bc0a7fc505a0edc0fb771ebe1d8cc24f98e3d8678bda33b8250fab13</citedby><cites>FETCH-LOGICAL-c4430-a3650b891bc0a7fc505a0edc0fb771ebe1d8cc24f98e3d8678bda33b8250fab13</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fchem.201100820$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fchem.201100820$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/21618636$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Zhu, Qiming</creatorcontrib><creatorcontrib>Shi, Dengjian</creatorcontrib><creatorcontrib>Xia, Chungu</creatorcontrib><creatorcontrib>Huang, Hanmin</creatorcontrib><title>Ruthenium Catalysts Containing Rigid Chiral Diamines and Achiral Diphosphanes for Highly Enantioselective Hydrogenation of Aromatic Ketones</title><title>Chemistry : a European journal</title><addtitle>Chem. Eur. J</addtitle><description>One chiral element is enough: A new ruthenium catalyst containing a rigid chiral diamine (BIDN) and a commercially available inexpensive achiral phosphane (DPPF) is highly efficient for the enantioselective hydrogenation of ketones (see scheme). High reactivity (S/C up to 100 000) and excellent enantioselectivities (up to 99 % ee) were obtained.</description><subject>achiral phosphanes</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Chemistry</subject><subject>Diamines</subject><subject>enantioselectivity</subject><subject>Hydrogenation</subject><subject>Ketones</subject><subject>Ruthenium</subject><issn>0947-6539</issn><issn>1521-3765</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNqFkUGP0zAQhSMEYsvClSOyxAEuKeM4sZ1jN5QtUEBaQBwtx3EaL4ld7ATIb-BP46q7FeIAp9HMfO9JTy9JHmNYYoDsher0sMwAx4VncCdZ4CLDKWG0uJssoMxZSgtSniUPQrgGgJIScj85yzDFnBK6SH5dTWOnrZkGVMlR9nMYA6qcHaWxxu7QldmZBlWd8bJHL40cjNUBSduglbo97jsX9p08PFrn0cbsun5GayvtaFzQvVaj-a7RZm6822kr49Ui16KVd0NcFHqrRxfVD5N7reyDfnQzz5PPr9afqk26_XD5ulptU5XnBFJJaAE1L3GtQLJWFVBI0I2CtmYM61rjhiuV5W3JNWk4ZbxuJCE1zwpoZY3JefLs6Lv37tukwygGE5Tu-xjBTUFwRvIyoxmL5PN_kpgD5LyEDCL69C_02k3exhwCM0opxjmjkVoeKeVdCF63Yu_NIP0sMIhDoeJQqDgVGgVPbmynetDNCb9tMALlEfhhej3_x05Um_W7P83To9aEUf88aaX_KigjrBBf3l-Ki5Llby7wR7ElvwEtrb2L</recordid><startdate>20110704</startdate><enddate>20110704</enddate><creator>Zhu, Qiming</creator><creator>Shi, Dengjian</creator><creator>Xia, Chungu</creator><creator>Huang, Hanmin</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>K9.</scope><scope>7X8</scope></search><sort><creationdate>20110704</creationdate><title>Ruthenium Catalysts Containing Rigid Chiral Diamines and Achiral Diphosphanes for Highly Enantioselective Hydrogenation of Aromatic Ketones</title><author>Zhu, Qiming ; Shi, Dengjian ; Xia, Chungu ; Huang, Hanmin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4430-a3650b891bc0a7fc505a0edc0fb771ebe1d8cc24f98e3d8678bda33b8250fab13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>achiral phosphanes</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Chemistry</topic><topic>Diamines</topic><topic>enantioselectivity</topic><topic>Hydrogenation</topic><topic>Ketones</topic><topic>Ruthenium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhu, Qiming</creatorcontrib><creatorcontrib>Shi, Dengjian</creatorcontrib><creatorcontrib>Xia, Chungu</creatorcontrib><creatorcontrib>Huang, Hanmin</creatorcontrib><collection>Istex</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>ProQuest Health &amp; Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>Chemistry : a European journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhu, Qiming</au><au>Shi, Dengjian</au><au>Xia, Chungu</au><au>Huang, Hanmin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ruthenium Catalysts Containing Rigid Chiral Diamines and Achiral Diphosphanes for Highly Enantioselective Hydrogenation of Aromatic Ketones</atitle><jtitle>Chemistry : a European journal</jtitle><addtitle>Chem. Eur. J</addtitle><date>2011-07-04</date><risdate>2011</risdate><volume>17</volume><issue>28</issue><spage>7760</spage><epage>7763</epage><pages>7760-7763</pages><issn>0947-6539</issn><eissn>1521-3765</eissn><coden>CEUJED</coden><abstract>One chiral element is enough: A new ruthenium catalyst containing a rigid chiral diamine (BIDN) and a commercially available inexpensive achiral phosphane (DPPF) is highly efficient for the enantioselective hydrogenation of ketones (see scheme). High reactivity (S/C up to 100 000) and excellent enantioselectivities (up to 99 % ee) were obtained.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><pmid>21618636</pmid><doi>10.1002/chem.201100820</doi><tpages>4</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0947-6539
ispartof Chemistry : a European journal, 2011-07, Vol.17 (28), p.7760-7763
issn 0947-6539
1521-3765
language eng
recordid cdi_proquest_miscellaneous_873492627
source Wiley Online Library Journals Frontfile Complete
subjects achiral phosphanes
Catalysis
Catalysts
Chemistry
Diamines
enantioselectivity
Hydrogenation
Ketones
Ruthenium
title Ruthenium Catalysts Containing Rigid Chiral Diamines and Achiral Diphosphanes for Highly Enantioselective Hydrogenation of Aromatic Ketones
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-02T12%3A24%3A43IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Ruthenium%20Catalysts%20Containing%20Rigid%20Chiral%20Diamines%20and%20Achiral%20Diphosphanes%20for%20Highly%20Enantioselective%20Hydrogenation%20of%20Aromatic%20Ketones&rft.jtitle=Chemistry%20:%20a%20European%20journal&rft.au=Zhu,%20Qiming&rft.date=2011-07-04&rft.volume=17&rft.issue=28&rft.spage=7760&rft.epage=7763&rft.pages=7760-7763&rft.issn=0947-6539&rft.eissn=1521-3765&rft.coden=CEUJED&rft_id=info:doi/10.1002/chem.201100820&rft_dat=%3Cproquest_cross%3E1800489020%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1766611476&rft_id=info:pmid/21618636&rfr_iscdi=true