Triiodide PVC Membrane Electrode Based on a Charge-Transfer Complex of Iodine with 2,4,6,8- Tetraphenyl-2,4,6,8-tetraazabicyclo[3.3.0]octane
A novel triiodide ion-selective electrode based on a charge-transfer complex of iodine with 2,4,6,8-tetraphenyl-2,4,6,8-tetraazabicyclo[3.3.0]octane as membrane carrier was prepared. The electrode has a linear dynamic range between 5.0 × 10-2 and 3.5 × 10-6 M, with a near-Nernstian slope of 54.7 ± 0...
Gespeichert in:
| Veröffentlicht in: | Analytical chemistry (Washington) 1999-04, Vol.71 (7), p.1350-1353 |
|---|---|
| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1353 |
|---|---|
| container_issue | 7 |
| container_start_page | 1350 |
| container_title | Analytical chemistry (Washington) |
| container_volume | 71 |
| creator | Rouhollahi, Ahmad Shamsipur, Mojtaba |
| description | A novel triiodide ion-selective electrode based on a charge-transfer complex of iodine with 2,4,6,8-tetraphenyl-2,4,6,8-tetraazabicyclo[3.3.0]octane as membrane carrier was prepared. The electrode has a linear dynamic range between 5.0 × 10-2 and 3.5 × 10-6 M, with a near-Nernstian slope of 54.7 ± 0.8 mV decade-1 and a detection limit of 2.0 × 10-6 M. The potentiometric response is independent of the pH of the solution in the pH range 4.0−10.5. The electrode possesses the advantages of low resistance, short conditioning time, fast response, and, especially, very good selectivities over a wide variety of other anions. The electrode can be used for at least 10 months without any considerable divergence in potentials. It was used as an indicator electrode in potentiometric titration of triiodide ions. |
| doi_str_mv | 10.1021/ac981077x |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_872526574</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>41286202</sourcerecordid><originalsourceid>FETCH-LOGICAL-a406t-914537e4fcb74297ec49334a38f29ea92f826f6d864fce529538094c9cbe15e03</originalsourceid><addsrcrecordid>eNpl0VuLEzEUB_AgiltXH_wCEkQRoVNzm1weddjVhRUXHC8gEjLpGTu7M01Nptj6GfzQZmm3C_oUOPnln5MchB5TMqOE0VfOG02JUps7aEJLRgqpNbuLJoQQXjBFyBF6kNIlIZQSKu-jI0alZKZUE_Snjl0X5t0c8MXnCr-HoYluCfikBz_GkMtvXII5DkvscLVw8QcUdRaphYirMKx62ODQ4rOckY_96sYFZlMxlVNd4BrG6FYLWG774qY4Xtfcb9d0fuv78I3P-Ix8D37Mtz5E91rXJ3i0X4_Rp9OTunpXnH94e1a9Pi-cIHIsDBUlVyBa3yjBjAIvDOfCcd0yA86wVjPZyrmWmUCZH8o1McIb3wAtgfBj9GKXu4rh5xrSaIcueej73ENYJ6sVK5kslcjy6T_yMqzjMjdnGVWGEEVNRi93yMeQUoTWrmI3uLi1lNjrAdnDgLJ9sg9cNwPMD_JmIhk82wOXvOvb_Ne-S7eJimspy8yKHevSCJvDtotXViquSltffLT8KxXqi2L2NPvnO-98un3D__39Bfjrryo</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>217900719</pqid></control><display><type>article</type><title>Triiodide PVC Membrane Electrode Based on a Charge-Transfer Complex of Iodine with 2,4,6,8- Tetraphenyl-2,4,6,8-tetraazabicyclo[3.3.0]octane</title><source>American Chemical Society Journals</source><creator>Rouhollahi, Ahmad ; Shamsipur, Mojtaba</creator><creatorcontrib>Rouhollahi, Ahmad ; Shamsipur, Mojtaba</creatorcontrib><description>A novel triiodide ion-selective electrode based on a charge-transfer complex of iodine with 2,4,6,8-tetraphenyl-2,4,6,8-tetraazabicyclo[3.3.0]octane as membrane carrier was prepared. The electrode has a linear dynamic range between 5.0 × 10-2 and 3.5 × 10-6 M, with a near-Nernstian slope of 54.7 ± 0.8 mV decade-1 and a detection limit of 2.0 × 10-6 M. The potentiometric response is independent of the pH of the solution in the pH range 4.0−10.5. The electrode possesses the advantages of low resistance, short conditioning time, fast response, and, especially, very good selectivities over a wide variety of other anions. The electrode can be used for at least 10 months without any considerable divergence in potentials. It was used as an indicator electrode in potentiometric titration of triiodide ions.</description><identifier>ISSN: 0003-2700</identifier><identifier>EISSN: 1520-6882</identifier><identifier>DOI: 10.1021/ac981077x</identifier><identifier>PMID: 21662957</identifier><identifier>CODEN: ANCHAM</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Analytical chemistry ; Chemistry ; Electrochemistry ; Electrodes: preparations and properties ; Exact sciences and technology ; General and physical chemistry ; General, instrumentation ; Ion selective electrodes ; Ions ; Membranes</subject><ispartof>Analytical chemistry (Washington), 1999-04, Vol.71 (7), p.1350-1353</ispartof><rights>Copyright © 1999 American Chemical Society</rights><rights>1999 INIST-CNRS</rights><rights>Copyright American Chemical Society Apr 1, 1999</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a406t-914537e4fcb74297ec49334a38f29ea92f826f6d864fce529538094c9cbe15e03</citedby><cites>FETCH-LOGICAL-a406t-914537e4fcb74297ec49334a38f29ea92f826f6d864fce529538094c9cbe15e03</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/ac981077x$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/ac981077x$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,2765,27076,27924,27925,56738,56788</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=1738665$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/21662957$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Rouhollahi, Ahmad</creatorcontrib><creatorcontrib>Shamsipur, Mojtaba</creatorcontrib><title>Triiodide PVC Membrane Electrode Based on a Charge-Transfer Complex of Iodine with 2,4,6,8- Tetraphenyl-2,4,6,8-tetraazabicyclo[3.3.0]octane</title><title>Analytical chemistry (Washington)</title><addtitle>Anal. Chem</addtitle><description>A novel triiodide ion-selective electrode based on a charge-transfer complex of iodine with 2,4,6,8-tetraphenyl-2,4,6,8-tetraazabicyclo[3.3.0]octane as membrane carrier was prepared. The electrode has a linear dynamic range between 5.0 × 10-2 and 3.5 × 10-6 M, with a near-Nernstian slope of 54.7 ± 0.8 mV decade-1 and a detection limit of 2.0 × 10-6 M. The potentiometric response is independent of the pH of the solution in the pH range 4.0−10.5. The electrode possesses the advantages of low resistance, short conditioning time, fast response, and, especially, very good selectivities over a wide variety of other anions. The electrode can be used for at least 10 months without any considerable divergence in potentials. It was used as an indicator electrode in potentiometric titration of triiodide ions.</description><subject>Analytical chemistry</subject><subject>Chemistry</subject><subject>Electrochemistry</subject><subject>Electrodes: preparations and properties</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>General, instrumentation</subject><subject>Ion selective electrodes</subject><subject>Ions</subject><subject>Membranes</subject><issn>0003-2700</issn><issn>1520-6882</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1999</creationdate><recordtype>article</recordtype><recordid>eNpl0VuLEzEUB_AgiltXH_wCEkQRoVNzm1weddjVhRUXHC8gEjLpGTu7M01Nptj6GfzQZmm3C_oUOPnln5MchB5TMqOE0VfOG02JUps7aEJLRgqpNbuLJoQQXjBFyBF6kNIlIZQSKu-jI0alZKZUE_Snjl0X5t0c8MXnCr-HoYluCfikBz_GkMtvXII5DkvscLVw8QcUdRaphYirMKx62ODQ4rOckY_96sYFZlMxlVNd4BrG6FYLWG774qY4Xtfcb9d0fuv78I3P-Ix8D37Mtz5E91rXJ3i0X4_Rp9OTunpXnH94e1a9Pi-cIHIsDBUlVyBa3yjBjAIvDOfCcd0yA86wVjPZyrmWmUCZH8o1McIb3wAtgfBj9GKXu4rh5xrSaIcueej73ENYJ6sVK5kslcjy6T_yMqzjMjdnGVWGEEVNRi93yMeQUoTWrmI3uLi1lNjrAdnDgLJ9sg9cNwPMD_JmIhk82wOXvOvb_Ne-S7eJimspy8yKHevSCJvDtotXViquSltffLT8KxXqi2L2NPvnO-98un3D__39Bfjrryo</recordid><startdate>19990401</startdate><enddate>19990401</enddate><creator>Rouhollahi, Ahmad</creator><creator>Shamsipur, Mojtaba</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SC</scope><scope>7SE</scope><scope>7SP</scope><scope>7SR</scope><scope>7TA</scope><scope>7TB</scope><scope>7TM</scope><scope>7U5</scope><scope>7U7</scope><scope>7U9</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>F28</scope><scope>FR3</scope><scope>H8D</scope><scope>H8G</scope><scope>H94</scope><scope>JG9</scope><scope>JQ2</scope><scope>KR7</scope><scope>L7M</scope><scope>L~C</scope><scope>L~D</scope><scope>P64</scope><scope>7X8</scope></search><sort><creationdate>19990401</creationdate><title>Triiodide PVC Membrane Electrode Based on a Charge-Transfer Complex of Iodine with 2,4,6,8- Tetraphenyl-2,4,6,8-tetraazabicyclo[3.3.0]octane</title><author>Rouhollahi, Ahmad ; Shamsipur, Mojtaba</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a406t-914537e4fcb74297ec49334a38f29ea92f826f6d864fce529538094c9cbe15e03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1999</creationdate><topic>Analytical chemistry</topic><topic>Chemistry</topic><topic>Electrochemistry</topic><topic>Electrodes: preparations and properties</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>General, instrumentation</topic><topic>Ion selective electrodes</topic><topic>Ions</topic><topic>Membranes</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Rouhollahi, Ahmad</creatorcontrib><creatorcontrib>Shamsipur, Mojtaba</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Biotechnology Research Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Computer and Information Systems Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Materials Business File</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Nucleic Acids Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Toxicology Abstracts</collection><collection>Virology and AIDS Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Copper Technical Reference Library</collection><collection>AIDS and Cancer Research Abstracts</collection><collection>Materials Research Database</collection><collection>ProQuest Computer Science Collection</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Computer and Information Systems Abstracts Academic</collection><collection>Computer and Information Systems Abstracts Professional</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>MEDLINE - Academic</collection><jtitle>Analytical chemistry (Washington)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Rouhollahi, Ahmad</au><au>Shamsipur, Mojtaba</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Triiodide PVC Membrane Electrode Based on a Charge-Transfer Complex of Iodine with 2,4,6,8- Tetraphenyl-2,4,6,8-tetraazabicyclo[3.3.0]octane</atitle><jtitle>Analytical chemistry (Washington)</jtitle><addtitle>Anal. Chem</addtitle><date>1999-04-01</date><risdate>1999</risdate><volume>71</volume><issue>7</issue><spage>1350</spage><epage>1353</epage><pages>1350-1353</pages><issn>0003-2700</issn><eissn>1520-6882</eissn><coden>ANCHAM</coden><abstract>A novel triiodide ion-selective electrode based on a charge-transfer complex of iodine with 2,4,6,8-tetraphenyl-2,4,6,8-tetraazabicyclo[3.3.0]octane as membrane carrier was prepared. The electrode has a linear dynamic range between 5.0 × 10-2 and 3.5 × 10-6 M, with a near-Nernstian slope of 54.7 ± 0.8 mV decade-1 and a detection limit of 2.0 × 10-6 M. The potentiometric response is independent of the pH of the solution in the pH range 4.0−10.5. The electrode possesses the advantages of low resistance, short conditioning time, fast response, and, especially, very good selectivities over a wide variety of other anions. The electrode can be used for at least 10 months without any considerable divergence in potentials. It was used as an indicator electrode in potentiometric titration of triiodide ions.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><pmid>21662957</pmid><doi>10.1021/ac981077x</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0003-2700 |
| ispartof | Analytical chemistry (Washington), 1999-04, Vol.71 (7), p.1350-1353 |
| issn | 0003-2700 1520-6882 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_872526574 |
| source | American Chemical Society Journals |
| subjects | Analytical chemistry Chemistry Electrochemistry Electrodes: preparations and properties Exact sciences and technology General and physical chemistry General, instrumentation Ion selective electrodes Ions Membranes |
| title | Triiodide PVC Membrane Electrode Based on a Charge-Transfer Complex of Iodine with 2,4,6,8- Tetraphenyl-2,4,6,8-tetraazabicyclo[3.3.0]octane |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-27T06%3A36%3A11IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Triiodide%20PVC%20Membrane%20Electrode%20Based%20on%20a%20Charge-Transfer%20Complex%20of%20Iodine%20with%202,4,6,8-%20Tetraphenyl-2,4,6,8-tetraazabicyclo%5B3.3.0%5Doctane&rft.jtitle=Analytical%20chemistry%20(Washington)&rft.au=Rouhollahi,%20Ahmad&rft.date=1999-04-01&rft.volume=71&rft.issue=7&rft.spage=1350&rft.epage=1353&rft.pages=1350-1353&rft.issn=0003-2700&rft.eissn=1520-6882&rft.coden=ANCHAM&rft_id=info:doi/10.1021/ac981077x&rft_dat=%3Cproquest_cross%3E41286202%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=217900719&rft_id=info:pmid/21662957&rfr_iscdi=true |