Activation parameters derived from a temperature dependent large amplitude ac voltammetric study of the electrode kinetics of the Cp2M(0/+) redox couples (M = Fe, Co) at a glassy carbon electrode

Heterogeneous charge transfer rate constants (k°) for the oxidation of ferrocene, Fc (k° = 0.21 cm s(-1) at 20 °C), and the reduction of the cobaltocenium cation, Cc(+) (k° = 0.12 cm s(-1) at 18 °C), in CH(2)Cl(2) (0.5 M Bu(4)NPF(6)) at a glassy carbon (GC) electrode were determined as a function of...

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Veröffentlicht in:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2011-06, Vol.115 (24), p.6493-6502
Hauptverfasser:	Bullock, John P, Mashkina, Elena, Bond, Alan M
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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