A Ring−Disk Study of the Competition between Anodic Oxygen-Transfer and Dioxygen-Evolution Reactions

Voltammetric data obtained at a rotated ring−disk electrode for oxidation of dimethyl sulfoxide (DMSO) to dimethyl sulfone support the conclusion that anodic O-transfer and O2(aq)-evolution reactions are in competition for a common reaction precursor. That species is concluded to be the adsorbed OH...

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Veröffentlicht in:	Analytical chemistry (Washington) 1998-02, Vol.70 (3), p.468-472
Hauptverfasser:	Popović, Nataša D, Johnson, Dennis C
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Electrochemistry Exact sciences and technology General and physical chemistry Kinetics and mechanism of reactions
Online-Zugang:	Volltext
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