Characterization of a zinc–cerium flow battery
► The performance of a cerium–zinc redox flow battery in methanesulfonic acid was evaluated under: ► different electrode materials, electrolyte compositions and life-cycle testing. ► Carbon felt electrodes show the highest coulombic and voltage efficiencies. ► The performance improved at high operat...
Gespeichert in:
| Veröffentlicht in: | Journal of power sources 2011-06, Vol.196 (11), p.5174-5185 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 5185 |
|---|---|
| container_issue | 11 |
| container_start_page | 5174 |
| container_title | Journal of power sources |
| container_volume | 196 |
| creator | Leung, P.K. Ponce-de-León, C. Low, C.T.J. Shah, A.A. Walsh, F.C. |
| description | ► The performance of a cerium–zinc redox flow battery in methanesulfonic acid was evaluated under: ► different electrode materials, electrolyte compositions and life-cycle testing. ► Carbon felt electrodes show the highest coulombic and voltage efficiencies. ► The performance improved at high operating temperatures and a faster electrolyte flow velocities.
The performance of a divided, parallel-plate zinc–cerium redox flow battery using methanesulfonic acid electrolytes was studied. Eight two and three-dimensional electrodes were tested under both constant current density and constant cell voltage discharge. Carbon felt and the three-dimensional platinised titanium mesh electrodes exhibited superior performance over the 2-dimensional electrodes. The charge and discharge characteristics of the redox flow battery were studied under different operating conditions and Zn/Ce reactant, as well as methansulfonic acid concentration. The cell performance improved at higher operating temperatures and faster electrolyte flow velocities. The number of possible cycles increased at reduced states of charge. During 15
min charge/discharge per cycle experiment, 57 cycles were obtained and the zinc reaction was found to be the limiting process during long term operation. |
| doi_str_mv | 10.1016/j.jpowsour.2011.01.095 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_869843014</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0378775311002230</els_id><sourcerecordid>1777108821</sourcerecordid><originalsourceid>FETCH-LOGICAL-c407t-e1220359997c55a2fd7f94ba98e6ee83c1b37161597f037275595300809f86f33</originalsourceid><addsrcrecordid>eNqFkM1KAzEUhYMoWKuvILMR3cx4M5lMkp1S_IOCG12HNE0ww3RSkxlLu_IdfEOfxJSqS4UDFy7fvedwEDrFUGDA9WVTNEu_in4IRQkYF5Ak6B4aYc5IXjJK99EICOM5Y5QcoqMYG4BEMhghmLyooHRvgtuo3vku8zZT2cZ1-vP9Q6f1sMhs61fZTPWJWh-jA6vaaE6-5xg93948Te7z6ePdw-R6musKWJ8bXJZAqBCCaUpVaefMimqmBDe1MZxoPCMM15gKZlO2bUpBCQAHYXltCRmj893fZfCvg4m9XLioTduqzvghSl4LXhHAVSIv_iQxYwwD5yVOaL1DdfAxBmPlMriFCmuJQW7LlI38KVNuy5SQlIKN0dm3h4patTaoTrv4e11WQDhUZeKudpxJ1bw5E2TUznTazF0wupdz7_6z-gILOIzb</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1777108821</pqid></control><display><type>article</type><title>Characterization of a zinc–cerium flow battery</title><source>Elsevier ScienceDirect Journals</source><creator>Leung, P.K. ; Ponce-de-León, C. ; Low, C.T.J. ; Shah, A.A. ; Walsh, F.C.</creator><creatorcontrib>Leung, P.K. ; Ponce-de-León, C. ; Low, C.T.J. ; Shah, A.A. ; Walsh, F.C.</creatorcontrib><description>► The performance of a cerium–zinc redox flow battery in methanesulfonic acid was evaluated under: ► different electrode materials, electrolyte compositions and life-cycle testing. ► Carbon felt electrodes show the highest coulombic and voltage efficiencies. ► The performance improved at high operating temperatures and a faster electrolyte flow velocities.
The performance of a divided, parallel-plate zinc–cerium redox flow battery using methanesulfonic acid electrolytes was studied. Eight two and three-dimensional electrodes were tested under both constant current density and constant cell voltage discharge. Carbon felt and the three-dimensional platinised titanium mesh electrodes exhibited superior performance over the 2-dimensional electrodes. The charge and discharge characteristics of the redox flow battery were studied under different operating conditions and Zn/Ce reactant, as well as methansulfonic acid concentration. The cell performance improved at higher operating temperatures and faster electrolyte flow velocities. The number of possible cycles increased at reduced states of charge. During 15
min charge/discharge per cycle experiment, 57 cycles were obtained and the zinc reaction was found to be the limiting process during long term operation.</description><identifier>ISSN: 0378-7753</identifier><identifier>EISSN: 1873-2755</identifier><identifier>DOI: 10.1016/j.jpowsour.2011.01.095</identifier><identifier>CODEN: JPSODZ</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Applied sciences ; Battery ; Cerium ; Charge ; Current density ; Direct energy conversion and energy accumulation ; Discharge ; Electric batteries ; Electrical engineering. Electrical power engineering ; Electrical power engineering ; Electrochemical conversion: primary and secondary batteries, fuel cells ; Electrodes ; Electrolytes ; Electrolytic cells ; Energy ; Energy storage ; Energy. Thermal use of fuels ; Exact sciences and technology ; Methanesulfonic acid ; Redox flow battery ; Transport and storage of energy ; Zinc</subject><ispartof>Journal of power sources, 2011-06, Vol.196 (11), p.5174-5185</ispartof><rights>2011 Elsevier B.V.</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c407t-e1220359997c55a2fd7f94ba98e6ee83c1b37161597f037275595300809f86f33</citedby><cites>FETCH-LOGICAL-c407t-e1220359997c55a2fd7f94ba98e6ee83c1b37161597f037275595300809f86f33</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0378775311002230$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=24038042$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Leung, P.K.</creatorcontrib><creatorcontrib>Ponce-de-León, C.</creatorcontrib><creatorcontrib>Low, C.T.J.</creatorcontrib><creatorcontrib>Shah, A.A.</creatorcontrib><creatorcontrib>Walsh, F.C.</creatorcontrib><title>Characterization of a zinc–cerium flow battery</title><title>Journal of power sources</title><description>► The performance of a cerium–zinc redox flow battery in methanesulfonic acid was evaluated under: ► different electrode materials, electrolyte compositions and life-cycle testing. ► Carbon felt electrodes show the highest coulombic and voltage efficiencies. ► The performance improved at high operating temperatures and a faster electrolyte flow velocities.
The performance of a divided, parallel-plate zinc–cerium redox flow battery using methanesulfonic acid electrolytes was studied. Eight two and three-dimensional electrodes were tested under both constant current density and constant cell voltage discharge. Carbon felt and the three-dimensional platinised titanium mesh electrodes exhibited superior performance over the 2-dimensional electrodes. The charge and discharge characteristics of the redox flow battery were studied under different operating conditions and Zn/Ce reactant, as well as methansulfonic acid concentration. The cell performance improved at higher operating temperatures and faster electrolyte flow velocities. The number of possible cycles increased at reduced states of charge. During 15
min charge/discharge per cycle experiment, 57 cycles were obtained and the zinc reaction was found to be the limiting process during long term operation.</description><subject>Applied sciences</subject><subject>Battery</subject><subject>Cerium</subject><subject>Charge</subject><subject>Current density</subject><subject>Direct energy conversion and energy accumulation</subject><subject>Discharge</subject><subject>Electric batteries</subject><subject>Electrical engineering. Electrical power engineering</subject><subject>Electrical power engineering</subject><subject>Electrochemical conversion: primary and secondary batteries, fuel cells</subject><subject>Electrodes</subject><subject>Electrolytes</subject><subject>Electrolytic cells</subject><subject>Energy</subject><subject>Energy storage</subject><subject>Energy. Thermal use of fuels</subject><subject>Exact sciences and technology</subject><subject>Methanesulfonic acid</subject><subject>Redox flow battery</subject><subject>Transport and storage of energy</subject><subject>Zinc</subject><issn>0378-7753</issn><issn>1873-2755</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNqFkM1KAzEUhYMoWKuvILMR3cx4M5lMkp1S_IOCG12HNE0ww3RSkxlLu_IdfEOfxJSqS4UDFy7fvedwEDrFUGDA9WVTNEu_in4IRQkYF5Ak6B4aYc5IXjJK99EICOM5Y5QcoqMYG4BEMhghmLyooHRvgtuo3vku8zZT2cZ1-vP9Q6f1sMhs61fZTPWJWh-jA6vaaE6-5xg93948Te7z6ePdw-R6musKWJ8bXJZAqBCCaUpVaefMimqmBDe1MZxoPCMM15gKZlO2bUpBCQAHYXltCRmj893fZfCvg4m9XLioTduqzvghSl4LXhHAVSIv_iQxYwwD5yVOaL1DdfAxBmPlMriFCmuJQW7LlI38KVNuy5SQlIKN0dm3h4patTaoTrv4e11WQDhUZeKudpxJ1bw5E2TUznTazF0wupdz7_6z-gILOIzb</recordid><startdate>20110601</startdate><enddate>20110601</enddate><creator>Leung, P.K.</creator><creator>Ponce-de-León, C.</creator><creator>Low, C.T.J.</creator><creator>Shah, A.A.</creator><creator>Walsh, F.C.</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SU</scope><scope>7TB</scope><scope>8FD</scope><scope>C1K</scope><scope>FR3</scope><scope>KR7</scope><scope>L7M</scope><scope>7ST</scope><scope>SOI</scope></search><sort><creationdate>20110601</creationdate><title>Characterization of a zinc–cerium flow battery</title><author>Leung, P.K. ; Ponce-de-León, C. ; Low, C.T.J. ; Shah, A.A. ; Walsh, F.C.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c407t-e1220359997c55a2fd7f94ba98e6ee83c1b37161597f037275595300809f86f33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Applied sciences</topic><topic>Battery</topic><topic>Cerium</topic><topic>Charge</topic><topic>Current density</topic><topic>Direct energy conversion and energy accumulation</topic><topic>Discharge</topic><topic>Electric batteries</topic><topic>Electrical engineering. Electrical power engineering</topic><topic>Electrical power engineering</topic><topic>Electrochemical conversion: primary and secondary batteries, fuel cells</topic><topic>Electrodes</topic><topic>Electrolytes</topic><topic>Electrolytic cells</topic><topic>Energy</topic><topic>Energy storage</topic><topic>Energy. Thermal use of fuels</topic><topic>Exact sciences and technology</topic><topic>Methanesulfonic acid</topic><topic>Redox flow battery</topic><topic>Transport and storage of energy</topic><topic>Zinc</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Leung, P.K.</creatorcontrib><creatorcontrib>Ponce-de-León, C.</creatorcontrib><creatorcontrib>Low, C.T.J.</creatorcontrib><creatorcontrib>Shah, A.A.</creatorcontrib><creatorcontrib>Walsh, F.C.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Environmental Engineering Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Engineering Research Database</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Environment Abstracts</collection><collection>Environment Abstracts</collection><jtitle>Journal of power sources</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Leung, P.K.</au><au>Ponce-de-León, C.</au><au>Low, C.T.J.</au><au>Shah, A.A.</au><au>Walsh, F.C.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Characterization of a zinc–cerium flow battery</atitle><jtitle>Journal of power sources</jtitle><date>2011-06-01</date><risdate>2011</risdate><volume>196</volume><issue>11</issue><spage>5174</spage><epage>5185</epage><pages>5174-5185</pages><issn>0378-7753</issn><eissn>1873-2755</eissn><coden>JPSODZ</coden><abstract>► The performance of a cerium–zinc redox flow battery in methanesulfonic acid was evaluated under: ► different electrode materials, electrolyte compositions and life-cycle testing. ► Carbon felt electrodes show the highest coulombic and voltage efficiencies. ► The performance improved at high operating temperatures and a faster electrolyte flow velocities.
The performance of a divided, parallel-plate zinc–cerium redox flow battery using methanesulfonic acid electrolytes was studied. Eight two and three-dimensional electrodes were tested under both constant current density and constant cell voltage discharge. Carbon felt and the three-dimensional platinised titanium mesh electrodes exhibited superior performance over the 2-dimensional electrodes. The charge and discharge characteristics of the redox flow battery were studied under different operating conditions and Zn/Ce reactant, as well as methansulfonic acid concentration. The cell performance improved at higher operating temperatures and faster electrolyte flow velocities. The number of possible cycles increased at reduced states of charge. During 15
min charge/discharge per cycle experiment, 57 cycles were obtained and the zinc reaction was found to be the limiting process during long term operation.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.jpowsour.2011.01.095</doi><tpages>12</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0378-7753 |
| ispartof | Journal of power sources, 2011-06, Vol.196 (11), p.5174-5185 |
| issn | 0378-7753 1873-2755 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_869843014 |
| source | Elsevier ScienceDirect Journals |
| subjects | Applied sciences Battery Cerium Charge Current density Direct energy conversion and energy accumulation Discharge Electric batteries Electrical engineering. Electrical power engineering Electrical power engineering Electrochemical conversion: primary and secondary batteries, fuel cells Electrodes Electrolytes Electrolytic cells Energy Energy storage Energy. Thermal use of fuels Exact sciences and technology Methanesulfonic acid Redox flow battery Transport and storage of energy Zinc |
| title | Characterization of a zinc–cerium flow battery |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-10T00%3A11%3A16IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Characterization%20of%20a%20zinc%E2%80%93cerium%20flow%20battery&rft.jtitle=Journal%20of%20power%20sources&rft.au=Leung,%20P.K.&rft.date=2011-06-01&rft.volume=196&rft.issue=11&rft.spage=5174&rft.epage=5185&rft.pages=5174-5185&rft.issn=0378-7753&rft.eissn=1873-2755&rft.coden=JPSODZ&rft_id=info:doi/10.1016/j.jpowsour.2011.01.095&rft_dat=%3Cproquest_cross%3E1777108821%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1777108821&rft_id=info:pmid/&rft_els_id=S0378775311002230&rfr_iscdi=true |