Synthesis of high molecular weight polystyrene using AGET ATRP under high pressure

High molecular weight polystyrene (PS) was synthesized by ATRP. Under atmospheric pressure (1bar), PS with Mn up to 200,000 was prepared using either ARGET or ICAR ATRP. Under high pressure (6kbar), higher molecular weight PS could be obtained due to accelerated radical propagation and diminished ra...

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Veröffentlicht in:	European polymer journal 2011-04, Vol.47 (4), p.730-734
Hauptverfasser:	Mueller, Laura, Jakubowski, Wojciech, Matyjaszewski, Krzysztof, Pietrasik, Joanna, Kwiatkowski, Piotr, Chaladaj, Wojciech, Jurczak, Janusz
Format:	Artikel
Sprache:	eng
Schlagworte:	Atmospheric pressure Atom transfer radical polymerization (ATRP) Barometric pressure High molecular weight High pressure Manganese Molecular weight Polymerization Polystyrene (PS) Polystyrene resins Radicals Styrenes Termination (polymerization)
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