Corrosion behavior of lanthanum-based conversion coating modified with citric acid on hot dip galvanized steel in aerated 1M NaCl solution

a-[ordm The corrosion behavior of lanthanum conversion coating modified with citric acid on hot dip galvanized (HDG) steel was investigated in aerated 1M NaCl solution. a-[ordm The La salt conversion coatings inhibit both the anodic and cathodic responses of the system and hence prevent the HDG subs...

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Veröffentlicht in:Corrosion science 2011-04, Vol.53 (4), p.1621-1626
Hauptverfasser: Kong, Gang, Lingyan, Liu, Lu, Jintang, Che, Chunshan, Zhong, Zheng
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container_end_page 1626
container_issue 4
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container_title Corrosion science
container_volume 53
creator Kong, Gang
Lingyan, Liu
Lu, Jintang
Che, Chunshan
Zhong, Zheng
description a-[ordm The corrosion behavior of lanthanum conversion coating modified with citric acid on hot dip galvanized (HDG) steel was investigated in aerated 1M NaCl solution. a-[ordm The La salt conversion coatings inhibit both the anodic and cathodic responses of the system and hence prevent the HDG substrate from corrosion. a-[ordm The corrosion process of the coating can be divided into three stages. The outer layer of the coating was destroyed at the initial stage of immersion (144h). Rare earth conversion coating is one of the most promising substitutes to the toxic chromate coating. The corrosion resistance of lanthanum conversion coating modified with citric acid on hot dip galvanized (HDG) steel was investigated in aerated 1M NaCl solution by means of electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization measurements. Equivalent circuits were subsequently developed from the measurements to elucidate the corrosion behavior of the coating. The surface morphology of the lanthanum conversion coating was observed by scanning electron microscopy (SEM), and the chemical composition of the coating was characterized by energy dispersive spectroscopy (EDS). The results showed that the corrosion process of the modified lanthanum conversion coating consisted of three stages. The overall corrosion resistance of the coating was excellent.
doi_str_mv 10.1016/j.corsci.2011.01.038
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subjects Aerated
Citric acid
Coating
Conversion coating
Corrosion
Corrosion inhibitors
Hot dip galvanizing
Lanthanum
Rare earth metals
title Corrosion behavior of lanthanum-based conversion coating modified with citric acid on hot dip galvanized steel in aerated 1M NaCl solution
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