The free volume in acrylic resin/laponite nanocomposite coatings
[Display omitted] The morphological features and the free volume properties of an acrylic resin/laponite nanocomposite are investigated using X-ray diffraction and Positron Annihilation Lifetime Spectroscopy. The effects of particle loading on the degree of exfoliation is examined. The measured life...
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| Veröffentlicht in: | European polymer journal 2011-03, Vol.47 (3), p.264-272 |
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| container_issue | 3 |
| container_start_page | 264 |
| container_title | European polymer journal |
| container_volume | 47 |
| creator | Choudalakis, G. Gotsis, A.D. Schut, H. Picken, S.J. |
| description | [Display omitted]
The morphological features and the free volume properties of an acrylic resin/laponite nanocomposite are investigated using X-ray diffraction and Positron Annihilation Lifetime Spectroscopy. The effects of particle loading on the degree of exfoliation is examined. The measured lifetime spectra and the relative intensities of samples with different particle loading, as well as the shape parameters of the Doppler line broadening are correlated to the free volume in the nanocomposite and the measured CO2 gas solubility. The effect of the exfoliated nanoclay on the free volume of the composite is found to be very small for clay volume fraction up to 0.2%. |
| doi_str_mv | 10.1016/j.eurpolymj.2010.12.008 |
| format | Article |
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The morphological features and the free volume properties of an acrylic resin/laponite nanocomposite are investigated using X-ray diffraction and Positron Annihilation Lifetime Spectroscopy. The effects of particle loading on the degree of exfoliation is examined. The measured lifetime spectra and the relative intensities of samples with different particle loading, as well as the shape parameters of the Doppler line broadening are correlated to the free volume in the nanocomposite and the measured CO2 gas solubility. The effect of the exfoliated nanoclay on the free volume of the composite is found to be very small for clay volume fraction up to 0.2%.</description><identifier>ISSN: 0014-3057</identifier><identifier>EISSN: 1873-1945</identifier><identifier>DOI: 10.1016/j.eurpolymj.2010.12.008</identifier><identifier>CODEN: EUPJAG</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Acrylic resins ; Applied sciences ; Coating ; Composites ; Doppler effect ; Exact sciences and technology ; Exfoliation ; Forms of application and semi-finished materials ; Free volume ; Gas permeability ; Gas solubility ; Nanocomposite ; Nanocomposites ; Nanomaterials ; Nanostructure ; Particulate composites ; Polymer industry, paints, wood ; Positron annihilation ; Positron Annihilation Lifetime Spectroscopy ; Technology of polymers</subject><ispartof>European polymer journal, 2011-03, Vol.47 (3), p.264-272</ispartof><rights>2010 Elsevier Ltd</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c377t-b4f23a072b30da1a76db3e816f1ec9ef3ef8e494b5bc1ce7e41ff8b5d89b95ee3</citedby><cites>FETCH-LOGICAL-c377t-b4f23a072b30da1a76db3e816f1ec9ef3ef8e494b5bc1ce7e41ff8b5d89b95ee3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0014305710004738$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=23904518$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Choudalakis, G.</creatorcontrib><creatorcontrib>Gotsis, A.D.</creatorcontrib><creatorcontrib>Schut, H.</creatorcontrib><creatorcontrib>Picken, S.J.</creatorcontrib><title>The free volume in acrylic resin/laponite nanocomposite coatings</title><title>European polymer journal</title><description>[Display omitted]
The morphological features and the free volume properties of an acrylic resin/laponite nanocomposite are investigated using X-ray diffraction and Positron Annihilation Lifetime Spectroscopy. The effects of particle loading on the degree of exfoliation is examined. The measured lifetime spectra and the relative intensities of samples with different particle loading, as well as the shape parameters of the Doppler line broadening are correlated to the free volume in the nanocomposite and the measured CO2 gas solubility. The effect of the exfoliated nanoclay on the free volume of the composite is found to be very small for clay volume fraction up to 0.2%.</description><subject>Acrylic resins</subject><subject>Applied sciences</subject><subject>Coating</subject><subject>Composites</subject><subject>Doppler effect</subject><subject>Exact sciences and technology</subject><subject>Exfoliation</subject><subject>Forms of application and semi-finished materials</subject><subject>Free volume</subject><subject>Gas permeability</subject><subject>Gas solubility</subject><subject>Nanocomposite</subject><subject>Nanocomposites</subject><subject>Nanomaterials</subject><subject>Nanostructure</subject><subject>Particulate composites</subject><subject>Polymer industry, paints, wood</subject><subject>Positron annihilation</subject><subject>Positron Annihilation Lifetime Spectroscopy</subject><subject>Technology of polymers</subject><issn>0014-3057</issn><issn>1873-1945</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNqFkMtqwzAQRUVpoenjG-pN6cqOZMmWvWsIfUGgm3QtZHnUKsiSK9mB_H1tErLtapjh3BnmIPRAcEYwKZe7DMbQe3vodlmO52meYVxdoAWpOE1JzYpLtMCYsJTigl-jmxh3GGNOS7pAz9sfSHQASPbejh0kxiVShYM1KgkQjVta2XtnBkicdF75rvdx7pSXg3Hf8Q5daWkj3J_qLfp6fdmu39PN59vHerVJFeV8SBumcyoxzxuKW0kkL9uGQkVKTUDVoCnoCljNmqJRRAEHRrSumqKt6qYuAOgtejru7YP_HSEOojNRgbXSgR-jqMq6IoyVxUTyI6mCjzGAFn0wnQwHQbCYlYmdOCsTszJBcjEpm5KPpxsyKml1kE6ZeI7ntMasIDO3OnIwPbw3EERUBpyC1gRQg2i9-ffWH06KiDk</recordid><startdate>20110301</startdate><enddate>20110301</enddate><creator>Choudalakis, G.</creator><creator>Gotsis, A.D.</creator><creator>Schut, H.</creator><creator>Picken, S.J.</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20110301</creationdate><title>The free volume in acrylic resin/laponite nanocomposite coatings</title><author>Choudalakis, G. ; Gotsis, A.D. ; Schut, H. ; Picken, S.J.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c377t-b4f23a072b30da1a76db3e816f1ec9ef3ef8e494b5bc1ce7e41ff8b5d89b95ee3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Acrylic resins</topic><topic>Applied sciences</topic><topic>Coating</topic><topic>Composites</topic><topic>Doppler effect</topic><topic>Exact sciences and technology</topic><topic>Exfoliation</topic><topic>Forms of application and semi-finished materials</topic><topic>Free volume</topic><topic>Gas permeability</topic><topic>Gas solubility</topic><topic>Nanocomposite</topic><topic>Nanocomposites</topic><topic>Nanomaterials</topic><topic>Nanostructure</topic><topic>Particulate composites</topic><topic>Polymer industry, paints, wood</topic><topic>Positron annihilation</topic><topic>Positron Annihilation Lifetime Spectroscopy</topic><topic>Technology of polymers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Choudalakis, G.</creatorcontrib><creatorcontrib>Gotsis, A.D.</creatorcontrib><creatorcontrib>Schut, H.</creatorcontrib><creatorcontrib>Picken, S.J.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>European polymer journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Choudalakis, G.</au><au>Gotsis, A.D.</au><au>Schut, H.</au><au>Picken, S.J.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The free volume in acrylic resin/laponite nanocomposite coatings</atitle><jtitle>European polymer journal</jtitle><date>2011-03-01</date><risdate>2011</risdate><volume>47</volume><issue>3</issue><spage>264</spage><epage>272</epage><pages>264-272</pages><issn>0014-3057</issn><eissn>1873-1945</eissn><coden>EUPJAG</coden><abstract>[Display omitted]
The morphological features and the free volume properties of an acrylic resin/laponite nanocomposite are investigated using X-ray diffraction and Positron Annihilation Lifetime Spectroscopy. The effects of particle loading on the degree of exfoliation is examined. The measured lifetime spectra and the relative intensities of samples with different particle loading, as well as the shape parameters of the Doppler line broadening are correlated to the free volume in the nanocomposite and the measured CO2 gas solubility. The effect of the exfoliated nanoclay on the free volume of the composite is found to be very small for clay volume fraction up to 0.2%.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.eurpolymj.2010.12.008</doi><tpages>9</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0014-3057 |
| ispartof | European polymer journal, 2011-03, Vol.47 (3), p.264-272 |
| issn | 0014-3057 1873-1945 |
| language | eng |
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| source | Elsevier ScienceDirect Journals |
| subjects | Acrylic resins Applied sciences Coating Composites Doppler effect Exact sciences and technology Exfoliation Forms of application and semi-finished materials Free volume Gas permeability Gas solubility Nanocomposite Nanocomposites Nanomaterials Nanostructure Particulate composites Polymer industry, paints, wood Positron annihilation Positron Annihilation Lifetime Spectroscopy Technology of polymers |
| title | The free volume in acrylic resin/laponite nanocomposite coatings |
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