An empirical consistency test using thermodynamic consistency lines for the VLE data of 7262 constant-temperature and 5167 constant-pressure binaries

It has already been shown that the deviation in the binary VLE data from the Gibbs–Duhem equation, D, is formulated as D = 2( B − A)Δ x 1 2 using Margules binary parameters, A and B, representing the VLE data, and an experimental error involved in the liquid phase composition, Δ x 1. In the present...

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