Formation mechanism of carbon-encapsulated iron nanorods in a co-carbonization process
[Display omitted] ► Carbon-encapsulated iron nanostructures were prepared by a co-carbonization process. ► Carbon-encapsulated iron nanorod evolves from carbon-encapsulated iron nanoparticle. ► Cooling process is essential to the formation of carbon-encapsulated iron nanorod. Carbon-encapsulated iro...
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Veröffentlicht in: | Carbon (New York) 2011-03, Vol.49 (3), p.890-894 |
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creator | Wu, Bin Song, Huaihe Zhou, Jisheng Chen, Xiaohong |
description | [Display omitted]
► Carbon-encapsulated iron nanostructures were prepared by a co-carbonization process. ► Carbon-encapsulated iron nanorod evolves from carbon-encapsulated iron nanoparticle. ► Cooling process is essential to the formation of carbon-encapsulated iron nanorod.
Carbon-encapsulated iron nanostructures were prepared by co-carbonization of a mixture of aromatic heavy oil and ferrocene. The morphologies and structural features of the iron/carbon composites were investigated using transmission electron microscopy, high-resolusion transmission electron microscopy and X-ray diffraction measurements. It was found that, by increasing the reaction temperature from 420 to 450
°C the product was changed from nanoparticle to nanorod. The morphologies of the products prepared at 440
°C proved the relationship between nanoparticle and nanorod. Therefore, a model was established to explain the formation mechanism of carbon-encapsulated iron nanorods from the aggregation and self-assembly of partially fused carbon-encapsulated iron nanoparticles. |
doi_str_mv | 10.1016/j.carbon.2010.10.051 |
format | Article |
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► Carbon-encapsulated iron nanostructures were prepared by a co-carbonization process. ► Carbon-encapsulated iron nanorod evolves from carbon-encapsulated iron nanoparticle. ► Cooling process is essential to the formation of carbon-encapsulated iron nanorod.
Carbon-encapsulated iron nanostructures were prepared by co-carbonization of a mixture of aromatic heavy oil and ferrocene. The morphologies and structural features of the iron/carbon composites were investigated using transmission electron microscopy, high-resolusion transmission electron microscopy and X-ray diffraction measurements. It was found that, by increasing the reaction temperature from 420 to 450
°C the product was changed from nanoparticle to nanorod. The morphologies of the products prepared at 440
°C proved the relationship between nanoparticle and nanorod. Therefore, a model was established to explain the formation mechanism of carbon-encapsulated iron nanorods from the aggregation and self-assembly of partially fused carbon-encapsulated iron nanoparticles.</description><identifier>ISSN: 0008-6223</identifier><identifier>EISSN: 1873-3891</identifier><identifier>DOI: 10.1016/j.carbon.2010.10.051</identifier><identifier>CODEN: CRBNAH</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Carbon ; Chemistry ; Colloidal state and disperse state ; Cross-disciplinary physics: materials science; rheology ; Electron microscopy ; Exact sciences and technology ; Fullerenes and related materials; diamonds, graphite ; General and physical chemistry ; Iron ; Materials science ; Morphology ; Nanocomposites ; Nanomaterials ; Nanorods ; Nanostructure ; Physical and chemical studies. Granulometry. Electrokinetic phenomena ; Physics ; Self assembly ; Specific materials</subject><ispartof>Carbon (New York), 2011-03, Vol.49 (3), p.890-894</ispartof><rights>2010 Elsevier Ltd</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c368t-784218a8fb99bbac9cb36aca8ff8981ee3ee68efd7856a3c6b273271bacad45b3</citedby><cites>FETCH-LOGICAL-c368t-784218a8fb99bbac9cb36aca8ff8981ee3ee68efd7856a3c6b273271bacad45b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.carbon.2010.10.051$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,778,782,3539,27907,27908,45978</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=23824370$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Wu, Bin</creatorcontrib><creatorcontrib>Song, Huaihe</creatorcontrib><creatorcontrib>Zhou, Jisheng</creatorcontrib><creatorcontrib>Chen, Xiaohong</creatorcontrib><title>Formation mechanism of carbon-encapsulated iron nanorods in a co-carbonization process</title><title>Carbon (New York)</title><description>[Display omitted]
► Carbon-encapsulated iron nanostructures were prepared by a co-carbonization process. ► Carbon-encapsulated iron nanorod evolves from carbon-encapsulated iron nanoparticle. ► Cooling process is essential to the formation of carbon-encapsulated iron nanorod.
Carbon-encapsulated iron nanostructures were prepared by co-carbonization of a mixture of aromatic heavy oil and ferrocene. The morphologies and structural features of the iron/carbon composites were investigated using transmission electron microscopy, high-resolusion transmission electron microscopy and X-ray diffraction measurements. It was found that, by increasing the reaction temperature from 420 to 450
°C the product was changed from nanoparticle to nanorod. The morphologies of the products prepared at 440
°C proved the relationship between nanoparticle and nanorod. Therefore, a model was established to explain the formation mechanism of carbon-encapsulated iron nanorods from the aggregation and self-assembly of partially fused carbon-encapsulated iron nanoparticles.</description><subject>Carbon</subject><subject>Chemistry</subject><subject>Colloidal state and disperse state</subject><subject>Cross-disciplinary physics: materials science; rheology</subject><subject>Electron microscopy</subject><subject>Exact sciences and technology</subject><subject>Fullerenes and related materials; diamonds, graphite</subject><subject>General and physical chemistry</subject><subject>Iron</subject><subject>Materials science</subject><subject>Morphology</subject><subject>Nanocomposites</subject><subject>Nanomaterials</subject><subject>Nanorods</subject><subject>Nanostructure</subject><subject>Physical and chemical studies. Granulometry. Electrokinetic phenomena</subject><subject>Physics</subject><subject>Self assembly</subject><subject>Specific materials</subject><issn>0008-6223</issn><issn>1873-3891</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNp9kE9LxDAQxYMouK5-Aw-9iKfW_Omm6UWQxVVhwYt6DdN0ilnaZE26gn56s3bx6GmYx2_eYx4hl4wWjDJ5sykMhMa7gtNfqaALdkRmTFUiF6pmx2RGKVW55FyckrMYN2ktFStn5G3lwwCj9S4b0LyDs3HIfJdNhjk6A9u462HENrMhUQ6cD76NmXUZZMbnE2m_J5Nt8AZjPCcnHfQRLw5zTl5X9y_Lx3z9_PC0vFvnRkg15pUqOVOguqaumwZMbRohwSShU7ViiAJRKuzaSi0kCCMbXglesYRCWy4aMSfXk2_K_dhhHPVgo8G-B4d-F7WSdVUrseCJLCfSBB9jwE5vgx0gfGlG9b5FvdHTK3rf4l5NLaazq0MARAN9F8AZG_9uuVC8FBVN3O3EYfr202LQ0djUHrY2oBl16-3_QT_xxowB</recordid><startdate>20110301</startdate><enddate>20110301</enddate><creator>Wu, Bin</creator><creator>Song, Huaihe</creator><creator>Zhou, Jisheng</creator><creator>Chen, Xiaohong</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20110301</creationdate><title>Formation mechanism of carbon-encapsulated iron nanorods in a co-carbonization process</title><author>Wu, Bin ; Song, Huaihe ; Zhou, Jisheng ; Chen, Xiaohong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c368t-784218a8fb99bbac9cb36aca8ff8981ee3ee68efd7856a3c6b273271bacad45b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Carbon</topic><topic>Chemistry</topic><topic>Colloidal state and disperse state</topic><topic>Cross-disciplinary physics: materials science; rheology</topic><topic>Electron microscopy</topic><topic>Exact sciences and technology</topic><topic>Fullerenes and related materials; diamonds, graphite</topic><topic>General and physical chemistry</topic><topic>Iron</topic><topic>Materials science</topic><topic>Morphology</topic><topic>Nanocomposites</topic><topic>Nanomaterials</topic><topic>Nanorods</topic><topic>Nanostructure</topic><topic>Physical and chemical studies. Granulometry. Electrokinetic phenomena</topic><topic>Physics</topic><topic>Self assembly</topic><topic>Specific materials</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wu, Bin</creatorcontrib><creatorcontrib>Song, Huaihe</creatorcontrib><creatorcontrib>Zhou, Jisheng</creatorcontrib><creatorcontrib>Chen, Xiaohong</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Carbon (New York)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wu, Bin</au><au>Song, Huaihe</au><au>Zhou, Jisheng</au><au>Chen, Xiaohong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Formation mechanism of carbon-encapsulated iron nanorods in a co-carbonization process</atitle><jtitle>Carbon (New York)</jtitle><date>2011-03-01</date><risdate>2011</risdate><volume>49</volume><issue>3</issue><spage>890</spage><epage>894</epage><pages>890-894</pages><issn>0008-6223</issn><eissn>1873-3891</eissn><coden>CRBNAH</coden><abstract>[Display omitted]
► Carbon-encapsulated iron nanostructures were prepared by a co-carbonization process. ► Carbon-encapsulated iron nanorod evolves from carbon-encapsulated iron nanoparticle. ► Cooling process is essential to the formation of carbon-encapsulated iron nanorod.
Carbon-encapsulated iron nanostructures were prepared by co-carbonization of a mixture of aromatic heavy oil and ferrocene. The morphologies and structural features of the iron/carbon composites were investigated using transmission electron microscopy, high-resolusion transmission electron microscopy and X-ray diffraction measurements. It was found that, by increasing the reaction temperature from 420 to 450
°C the product was changed from nanoparticle to nanorod. The morphologies of the products prepared at 440
°C proved the relationship between nanoparticle and nanorod. Therefore, a model was established to explain the formation mechanism of carbon-encapsulated iron nanorods from the aggregation and self-assembly of partially fused carbon-encapsulated iron nanoparticles.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.carbon.2010.10.051</doi><tpages>5</tpages></addata></record> |
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subjects | Carbon Chemistry Colloidal state and disperse state Cross-disciplinary physics: materials science rheology Electron microscopy Exact sciences and technology Fullerenes and related materials diamonds, graphite General and physical chemistry Iron Materials science Morphology Nanocomposites Nanomaterials Nanorods Nanostructure Physical and chemical studies. Granulometry. Electrokinetic phenomena Physics Self assembly Specific materials |
title | Formation mechanism of carbon-encapsulated iron nanorods in a co-carbonization process |
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