Formation mechanism of carbon-encapsulated iron nanorods in a co-carbonization process

[Display omitted] ► Carbon-encapsulated iron nanostructures were prepared by a co-carbonization process. ► Carbon-encapsulated iron nanorod evolves from carbon-encapsulated iron nanoparticle. ► Cooling process is essential to the formation of carbon-encapsulated iron nanorod. Carbon-encapsulated iro...

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Veröffentlicht in:Carbon (New York) 2011-03, Vol.49 (3), p.890-894
Hauptverfasser: Wu, Bin, Song, Huaihe, Zhou, Jisheng, Chen, Xiaohong
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container_title Carbon (New York)
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creator Wu, Bin
Song, Huaihe
Zhou, Jisheng
Chen, Xiaohong
description [Display omitted] ► Carbon-encapsulated iron nanostructures were prepared by a co-carbonization process. ► Carbon-encapsulated iron nanorod evolves from carbon-encapsulated iron nanoparticle. ► Cooling process is essential to the formation of carbon-encapsulated iron nanorod. Carbon-encapsulated iron nanostructures were prepared by co-carbonization of a mixture of aromatic heavy oil and ferrocene. The morphologies and structural features of the iron/carbon composites were investigated using transmission electron microscopy, high-resolusion transmission electron microscopy and X-ray diffraction measurements. It was found that, by increasing the reaction temperature from 420 to 450 °C the product was changed from nanoparticle to nanorod. The morphologies of the products prepared at 440 °C proved the relationship between nanoparticle and nanorod. Therefore, a model was established to explain the formation mechanism of carbon-encapsulated iron nanorods from the aggregation and self-assembly of partially fused carbon-encapsulated iron nanoparticles.
doi_str_mv 10.1016/j.carbon.2010.10.051
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Carbon-encapsulated iron nanostructures were prepared by co-carbonization of a mixture of aromatic heavy oil and ferrocene. The morphologies and structural features of the iron/carbon composites were investigated using transmission electron microscopy, high-resolusion transmission electron microscopy and X-ray diffraction measurements. It was found that, by increasing the reaction temperature from 420 to 450 °C the product was changed from nanoparticle to nanorod. The morphologies of the products prepared at 440 °C proved the relationship between nanoparticle and nanorod. Therefore, a model was established to explain the formation mechanism of carbon-encapsulated iron nanorods from the aggregation and self-assembly of partially fused carbon-encapsulated iron nanoparticles.</description><identifier>ISSN: 0008-6223</identifier><identifier>EISSN: 1873-3891</identifier><identifier>DOI: 10.1016/j.carbon.2010.10.051</identifier><identifier>CODEN: CRBNAH</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Carbon ; Chemistry ; Colloidal state and disperse state ; Cross-disciplinary physics: materials science; rheology ; Electron microscopy ; Exact sciences and technology ; Fullerenes and related materials; diamonds, graphite ; General and physical chemistry ; Iron ; Materials science ; Morphology ; Nanocomposites ; Nanomaterials ; Nanorods ; Nanostructure ; Physical and chemical studies. Granulometry. 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Carbon-encapsulated iron nanostructures were prepared by co-carbonization of a mixture of aromatic heavy oil and ferrocene. The morphologies and structural features of the iron/carbon composites were investigated using transmission electron microscopy, high-resolusion transmission electron microscopy and X-ray diffraction measurements. It was found that, by increasing the reaction temperature from 420 to 450 °C the product was changed from nanoparticle to nanorod. The morphologies of the products prepared at 440 °C proved the relationship between nanoparticle and nanorod. 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Electrokinetic phenomena</topic><topic>Physics</topic><topic>Self assembly</topic><topic>Specific materials</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wu, Bin</creatorcontrib><creatorcontrib>Song, Huaihe</creatorcontrib><creatorcontrib>Zhou, Jisheng</creatorcontrib><creatorcontrib>Chen, Xiaohong</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Carbon (New York)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wu, Bin</au><au>Song, Huaihe</au><au>Zhou, Jisheng</au><au>Chen, Xiaohong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Formation mechanism of carbon-encapsulated iron nanorods in a co-carbonization process</atitle><jtitle>Carbon (New York)</jtitle><date>2011-03-01</date><risdate>2011</risdate><volume>49</volume><issue>3</issue><spage>890</spage><epage>894</epage><pages>890-894</pages><issn>0008-6223</issn><eissn>1873-3891</eissn><coden>CRBNAH</coden><abstract>[Display omitted] ► Carbon-encapsulated iron nanostructures were prepared by a co-carbonization process. ► Carbon-encapsulated iron nanorod evolves from carbon-encapsulated iron nanoparticle. ► Cooling process is essential to the formation of carbon-encapsulated iron nanorod. Carbon-encapsulated iron nanostructures were prepared by co-carbonization of a mixture of aromatic heavy oil and ferrocene. The morphologies and structural features of the iron/carbon composites were investigated using transmission electron microscopy, high-resolusion transmission electron microscopy and X-ray diffraction measurements. It was found that, by increasing the reaction temperature from 420 to 450 °C the product was changed from nanoparticle to nanorod. The morphologies of the products prepared at 440 °C proved the relationship between nanoparticle and nanorod. Therefore, a model was established to explain the formation mechanism of carbon-encapsulated iron nanorods from the aggregation and self-assembly of partially fused carbon-encapsulated iron nanoparticles.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.carbon.2010.10.051</doi><tpages>5</tpages></addata></record>
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subjects Carbon
Chemistry
Colloidal state and disperse state
Cross-disciplinary physics: materials science
rheology
Electron microscopy
Exact sciences and technology
Fullerenes and related materials
diamonds, graphite
General and physical chemistry
Iron
Materials science
Morphology
Nanocomposites
Nanomaterials
Nanorods
Nanostructure
Physical and chemical studies. Granulometry. Electrokinetic phenomena
Physics
Self assembly
Specific materials
title Formation mechanism of carbon-encapsulated iron nanorods in a co-carbonization process
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