A Simple, Iron-Catalyzed, Pyridine-Assisted Hydrogen Peroxide Epoxidation System
A simple and inexpensive system comprised of H2O2-pyridine-FeCl3·6H2O for the catalysis of olefin epoxidation was established. Intriguingly, the reactivity of this system greatly depends on the amounts of pyridine. Various substrates, including aromatic and aliphatic olefins, were epoxidized by this...
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| Veröffentlicht in: | Chemical & pharmaceutical bulletin 2011/06/01, Vol.59(6), pp.799-801 |
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| container_title | Chemical & pharmaceutical bulletin |
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| creator | Jiao, Mingyu Matsunaga, Hirofumi Ishizuka, Tadao |
| description | A simple and inexpensive system comprised of H2O2-pyridine-FeCl3·6H2O for the catalysis of olefin epoxidation was established. Intriguingly, the reactivity of this system greatly depends on the amounts of pyridine. Various substrates, including aromatic and aliphatic olefins, were epoxidized by this simple system in moderate to excellent yields. |
| doi_str_mv | 10.1248/cpb.59.799 |
| format | Article |
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Intriguingly, the reactivity of this system greatly depends on the amounts of pyridine. Various substrates, including aromatic and aliphatic olefins, were epoxidized by this simple system in moderate to excellent yields.</description><identifier>ISSN: 0009-2363</identifier><identifier>EISSN: 1347-5223</identifier><identifier>DOI: 10.1248/cpb.59.799</identifier><identifier>PMID: 21628924</identifier><language>eng</language><publisher>Japan: The Pharmaceutical Society of Japan</publisher><subject>acceleration ; Alkenes - chemistry ; Catalysis ; Chlorides - chemistry ; Epoxy Compounds - chemistry ; Ferric Compounds - chemistry ; hydrogen peroxide ; Hydrogen Peroxide - chemistry ; iron(III) chloride ; olefin epoxidation ; pyridine ; Pyridines - chemistry</subject><ispartof>Chemical and Pharmaceutical Bulletin, 2011/06/01, Vol.59(6), pp.799-801</ispartof><rights>2011 The Pharmaceutical Society of Japan</rights><rights>Copyright Japan Science and Technology Agency 2011</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c507t-e731925b392131f7690c9b9866a07fc3541a92af97be887801c3630604fe7df73</citedby><cites>FETCH-LOGICAL-c507t-e731925b392131f7690c9b9866a07fc3541a92af97be887801c3630604fe7df73</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,1877,4010,27900,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/21628924$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Jiao, Mingyu</creatorcontrib><creatorcontrib>Matsunaga, Hirofumi</creatorcontrib><creatorcontrib>Ishizuka, Tadao</creatorcontrib><title>A Simple, Iron-Catalyzed, Pyridine-Assisted Hydrogen Peroxide Epoxidation System</title><title>Chemical & pharmaceutical bulletin</title><addtitle>Chem. 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Various substrates, including aromatic and aliphatic olefins, were epoxidized by this simple system in moderate to excellent yields.</description><subject>acceleration</subject><subject>Alkenes - chemistry</subject><subject>Catalysis</subject><subject>Chlorides - chemistry</subject><subject>Epoxy Compounds - chemistry</subject><subject>Ferric Compounds - chemistry</subject><subject>hydrogen peroxide</subject><subject>Hydrogen Peroxide - chemistry</subject><subject>iron(III) chloride</subject><subject>olefin epoxidation</subject><subject>pyridine</subject><subject>Pyridines - chemistry</subject><issn>0009-2363</issn><issn>1347-5223</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNpd0MtKw0AUBuBBFK2XjQ8gAReCmDqXZC4rKaVaQbCgrodJclKn5OZMCsand6Stgps5i_n4OedH6JzgMaGJvM27bJyqsVBqD40IS0ScUsr20QhjrGLKODtCx96vMKYpFuwQHVHCqVQ0GaHFJHqxdVfBTfTo2iaemt5UwxcUN9FicLawDcQT763voYjmQ-HaJTTRAlz7aQuIZt3PNL1tm-hlCKg-RQelqTycbecJerufvU7n8dPzw-N08hTnYYc-BsGIomnGFCWMlIIrnKtMSc4NFmXO0oQYRU2pRAZSColJHu7AHCcliKIU7ARdbXI7136swfe6tj6HqjINtGuvJVdCUU5YkJf_5KpduyYsp0kSAplUXAZ1vVG5a713UOrO2dq4QROsf2rWoWadKh1qDvhiG7nOaih-6a7XAO42YOV7s4RfYFxv8wp2WXzzhMi_n3fjNDTsG09ujTE</recordid><startdate>2011</startdate><enddate>2011</enddate><creator>Jiao, Mingyu</creator><creator>Matsunaga, Hirofumi</creator><creator>Ishizuka, Tadao</creator><general>The Pharmaceutical Society of Japan</general><general>Japan Science and Technology Agency</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7TK</scope><scope>7TM</scope><scope>7U9</scope><scope>H94</scope><scope>7X8</scope></search><sort><creationdate>2011</creationdate><title>A Simple, Iron-Catalyzed, Pyridine-Assisted Hydrogen Peroxide Epoxidation System</title><author>Jiao, Mingyu ; Matsunaga, Hirofumi ; Ishizuka, Tadao</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c507t-e731925b392131f7690c9b9866a07fc3541a92af97be887801c3630604fe7df73</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>acceleration</topic><topic>Alkenes - chemistry</topic><topic>Catalysis</topic><topic>Chlorides - chemistry</topic><topic>Epoxy Compounds - chemistry</topic><topic>Ferric Compounds - chemistry</topic><topic>hydrogen peroxide</topic><topic>Hydrogen Peroxide - chemistry</topic><topic>iron(III) chloride</topic><topic>olefin epoxidation</topic><topic>pyridine</topic><topic>Pyridines - chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Jiao, Mingyu</creatorcontrib><creatorcontrib>Matsunaga, Hirofumi</creatorcontrib><creatorcontrib>Ishizuka, Tadao</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Neurosciences Abstracts</collection><collection>Nucleic Acids Abstracts</collection><collection>Virology and AIDS Abstracts</collection><collection>AIDS and Cancer Research Abstracts</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical & pharmaceutical bulletin</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jiao, Mingyu</au><au>Matsunaga, Hirofumi</au><au>Ishizuka, Tadao</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A Simple, Iron-Catalyzed, Pyridine-Assisted Hydrogen Peroxide Epoxidation System</atitle><jtitle>Chemical & pharmaceutical bulletin</jtitle><addtitle>Chem. 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| ispartof | Chemical and Pharmaceutical Bulletin, 2011/06/01, Vol.59(6), pp.799-801 |
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| language | eng |
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| source | J-STAGE Free; MEDLINE; EZB-FREE-00999 freely available EZB journals; Free Full-Text Journals in Chemistry |
| subjects | acceleration Alkenes - chemistry Catalysis Chlorides - chemistry Epoxy Compounds - chemistry Ferric Compounds - chemistry hydrogen peroxide Hydrogen Peroxide - chemistry iron(III) chloride olefin epoxidation pyridine Pyridines - chemistry |
| title | A Simple, Iron-Catalyzed, Pyridine-Assisted Hydrogen Peroxide Epoxidation System |
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