Effects of a perfluorinated compound as an additive on the power conversion efficiencies of polymer solar cells
A perfluorinated compound, 4-amino-2-(trifluoromethyl)benzonitrile ( ATMB), was applied as an additive to polymer solar cells (PSCs) with P3HT [poly(3-hexylthiophene)]:PCBM [[6,6]-phenyl-C sub(61-butyric acid methyl ester] blend films. The addition of 6 wt% ATMB to a P3HT:PCBM layer led to an increa...
Gespeichert in:
| Veröffentlicht in: | Solar energy materials and solar cells 2011-07, Vol.95 (7), p.1908-1914 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1914 |
|---|---|
| container_issue | 7 |
| container_start_page | 1908 |
| container_title | Solar energy materials and solar cells |
| container_volume | 95 |
| creator | JEONG, Seonju WOO, Sung-Ho LYU, Hong-Kun YOON SOO HAN |
| description | A perfluorinated compound, 4-amino-2-(trifluoromethyl)benzonitrile ( ATMB), was applied as an additive to polymer solar cells (PSCs) with P3HT [poly(3-hexylthiophene)]:PCBM [[6,6]-phenyl-C sub(61-butyric acid methyl ester] blend films. The addition of 6 wt% ATMB to a P3HT:PCBM layer led to an increased power conversion efficiency of 5.03% due to the enhanced short circuit current and fill factor when compared with that of the reference cell without an additive. On the other hand, the devices with 4-aminobenzonitrile as an additive, not containing fluorine atoms in the molecule, displayed lower PCEs than that of the reference cell. The UV-visible absorption spectra, X-ray measurements and carrier mobility studies revealed that ATMB facilitated ordering of the P3HT chains, resulting in higher absorbance, larger crystal size of P3HT and enhanced hole mobility. XPS depth profiling measurements also showed that the additive molecules were predominantly positioned in the range of 25 nm under the surface of the P3HT:PCBM film, leading to improved fill factor.) |
| doi_str_mv | 10.1016/j.solmat.2011.02.019 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_869586046</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>869586046</sourcerecordid><originalsourceid>FETCH-LOGICAL-c346t-cee8f7f2b6e239d532526151d66106994c2f0865668759cdd927c497df8383003</originalsourceid><addsrcrecordid>eNp9kU1P5DAMhiO0KzHL7j_gkAuCS4uTtPk4IgS7SEhc4BxlE0d01DYl6bDi32-GQRw5WJasx_Zrv4ScMmgZMHm5bUsaJ7e2HBhrgbfAzBHZMK1MI4TR38gGDFcN8E4fkx-lbAGAS9FtSLqJEf1aaIrU0QVzHHcpD7NbMVCfpiXt5kBdoW6mLoRhHV6Rppmuz0iX9A9zheZXzGWoRYxx8APONd4HLml8mypS1bkK4jiWn-R7dGPBXx_5hDzd3jxe_2nuH37fXV_dN150cm08oo4q8r8SuTChF7znkvUsSMlAGtN5HkHLXkqteuNDqOf5zqgQtdACQJyQ88PcJaeXHZbVTkPZK3Azpl2xWppeS-hkJS--JJlSirFegahod0B9TqVkjHbJw-Tym2Vg907YrT04YfdOWOC2OlHbzj42uOLdGLOrHyqfvbxjinGlxX-PYouZ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1777115703</pqid></control><display><type>article</type><title>Effects of a perfluorinated compound as an additive on the power conversion efficiencies of polymer solar cells</title><source>Elsevier ScienceDirect Journals</source><creator>JEONG, Seonju ; WOO, Sung-Ho ; LYU, Hong-Kun ; YOON SOO HAN</creator><creatorcontrib>JEONG, Seonju ; WOO, Sung-Ho ; LYU, Hong-Kun ; YOON SOO HAN</creatorcontrib><description>A perfluorinated compound, 4-amino-2-(trifluoromethyl)benzonitrile ( ATMB), was applied as an additive to polymer solar cells (PSCs) with P3HT [poly(3-hexylthiophene)]:PCBM [[6,6]-phenyl-C sub(61-butyric acid methyl ester] blend films. The addition of 6 wt% ATMB to a P3HT:PCBM layer led to an increased power conversion efficiency of 5.03% due to the enhanced short circuit current and fill factor when compared with that of the reference cell without an additive. On the other hand, the devices with 4-aminobenzonitrile as an additive, not containing fluorine atoms in the molecule, displayed lower PCEs than that of the reference cell. The UV-visible absorption spectra, X-ray measurements and carrier mobility studies revealed that ATMB facilitated ordering of the P3HT chains, resulting in higher absorbance, larger crystal size of P3HT and enhanced hole mobility. XPS depth profiling measurements also showed that the additive molecules were predominantly positioned in the range of 25 nm under the surface of the P3HT:PCBM film, leading to improved fill factor.)</description><identifier>ISSN: 0927-0248</identifier><identifier>EISSN: 1879-3398</identifier><identifier>DOI: 10.1016/j.solmat.2011.02.019</identifier><language>eng</language><publisher>Amsterdam: Elsevier</publisher><subject>Additives ; Applied sciences ; Conversion ; Devices ; Energy ; Exact sciences and technology ; Natural energy ; Order disorder ; Photovoltaic cells ; Photovoltaic conversion ; Solar cells ; Solar cells. Photoelectrochemical cells ; Solar energy ; Solar power generation ; X-ray photoelectron spectroscopy</subject><ispartof>Solar energy materials and solar cells, 2011-07, Vol.95 (7), p.1908-1914</ispartof><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c346t-cee8f7f2b6e239d532526151d66106994c2f0865668759cdd927c497df8383003</citedby><cites>FETCH-LOGICAL-c346t-cee8f7f2b6e239d532526151d66106994c2f0865668759cdd927c497df8383003</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=24171278$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>JEONG, Seonju</creatorcontrib><creatorcontrib>WOO, Sung-Ho</creatorcontrib><creatorcontrib>LYU, Hong-Kun</creatorcontrib><creatorcontrib>YOON SOO HAN</creatorcontrib><title>Effects of a perfluorinated compound as an additive on the power conversion efficiencies of polymer solar cells</title><title>Solar energy materials and solar cells</title><description>A perfluorinated compound, 4-amino-2-(trifluoromethyl)benzonitrile ( ATMB), was applied as an additive to polymer solar cells (PSCs) with P3HT [poly(3-hexylthiophene)]:PCBM [[6,6]-phenyl-C sub(61-butyric acid methyl ester] blend films. The addition of 6 wt% ATMB to a P3HT:PCBM layer led to an increased power conversion efficiency of 5.03% due to the enhanced short circuit current and fill factor when compared with that of the reference cell without an additive. On the other hand, the devices with 4-aminobenzonitrile as an additive, not containing fluorine atoms in the molecule, displayed lower PCEs than that of the reference cell. The UV-visible absorption spectra, X-ray measurements and carrier mobility studies revealed that ATMB facilitated ordering of the P3HT chains, resulting in higher absorbance, larger crystal size of P3HT and enhanced hole mobility. XPS depth profiling measurements also showed that the additive molecules were predominantly positioned in the range of 25 nm under the surface of the P3HT:PCBM film, leading to improved fill factor.)</description><subject>Additives</subject><subject>Applied sciences</subject><subject>Conversion</subject><subject>Devices</subject><subject>Energy</subject><subject>Exact sciences and technology</subject><subject>Natural energy</subject><subject>Order disorder</subject><subject>Photovoltaic cells</subject><subject>Photovoltaic conversion</subject><subject>Solar cells</subject><subject>Solar cells. Photoelectrochemical cells</subject><subject>Solar energy</subject><subject>Solar power generation</subject><subject>X-ray photoelectron spectroscopy</subject><issn>0927-0248</issn><issn>1879-3398</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNp9kU1P5DAMhiO0KzHL7j_gkAuCS4uTtPk4IgS7SEhc4BxlE0d01DYl6bDi32-GQRw5WJasx_Zrv4ScMmgZMHm5bUsaJ7e2HBhrgbfAzBHZMK1MI4TR38gGDFcN8E4fkx-lbAGAS9FtSLqJEf1aaIrU0QVzHHcpD7NbMVCfpiXt5kBdoW6mLoRhHV6Rppmuz0iX9A9zheZXzGWoRYxx8APONd4HLml8mypS1bkK4jiWn-R7dGPBXx_5hDzd3jxe_2nuH37fXV_dN150cm08oo4q8r8SuTChF7znkvUsSMlAGtN5HkHLXkqteuNDqOf5zqgQtdACQJyQ88PcJaeXHZbVTkPZK3Azpl2xWppeS-hkJS--JJlSirFegahod0B9TqVkjHbJw-Tym2Vg907YrT04YfdOWOC2OlHbzj42uOLdGLOrHyqfvbxjinGlxX-PYouZ</recordid><startdate>20110701</startdate><enddate>20110701</enddate><creator>JEONG, Seonju</creator><creator>WOO, Sung-Ho</creator><creator>LYU, Hong-Kun</creator><creator>YOON SOO HAN</creator><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SU</scope><scope>7TB</scope><scope>7U5</scope><scope>8FD</scope><scope>C1K</scope><scope>FR3</scope><scope>L7M</scope><scope>7TG</scope><scope>KL.</scope></search><sort><creationdate>20110701</creationdate><title>Effects of a perfluorinated compound as an additive on the power conversion efficiencies of polymer solar cells</title><author>JEONG, Seonju ; WOO, Sung-Ho ; LYU, Hong-Kun ; YOON SOO HAN</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c346t-cee8f7f2b6e239d532526151d66106994c2f0865668759cdd927c497df8383003</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Additives</topic><topic>Applied sciences</topic><topic>Conversion</topic><topic>Devices</topic><topic>Energy</topic><topic>Exact sciences and technology</topic><topic>Natural energy</topic><topic>Order disorder</topic><topic>Photovoltaic cells</topic><topic>Photovoltaic conversion</topic><topic>Solar cells</topic><topic>Solar cells. Photoelectrochemical cells</topic><topic>Solar energy</topic><topic>Solar power generation</topic><topic>X-ray photoelectron spectroscopy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>JEONG, Seonju</creatorcontrib><creatorcontrib>WOO, Sung-Ho</creatorcontrib><creatorcontrib>LYU, Hong-Kun</creatorcontrib><creatorcontrib>YOON SOO HAN</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Environmental Engineering Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Engineering Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Meteorological & Geoastrophysical Abstracts</collection><collection>Meteorological & Geoastrophysical Abstracts - Academic</collection><jtitle>Solar energy materials and solar cells</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>JEONG, Seonju</au><au>WOO, Sung-Ho</au><au>LYU, Hong-Kun</au><au>YOON SOO HAN</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effects of a perfluorinated compound as an additive on the power conversion efficiencies of polymer solar cells</atitle><jtitle>Solar energy materials and solar cells</jtitle><date>2011-07-01</date><risdate>2011</risdate><volume>95</volume><issue>7</issue><spage>1908</spage><epage>1914</epage><pages>1908-1914</pages><issn>0927-0248</issn><eissn>1879-3398</eissn><abstract>A perfluorinated compound, 4-amino-2-(trifluoromethyl)benzonitrile ( ATMB), was applied as an additive to polymer solar cells (PSCs) with P3HT [poly(3-hexylthiophene)]:PCBM [[6,6]-phenyl-C sub(61-butyric acid methyl ester] blend films. The addition of 6 wt% ATMB to a P3HT:PCBM layer led to an increased power conversion efficiency of 5.03% due to the enhanced short circuit current and fill factor when compared with that of the reference cell without an additive. On the other hand, the devices with 4-aminobenzonitrile as an additive, not containing fluorine atoms in the molecule, displayed lower PCEs than that of the reference cell. The UV-visible absorption spectra, X-ray measurements and carrier mobility studies revealed that ATMB facilitated ordering of the P3HT chains, resulting in higher absorbance, larger crystal size of P3HT and enhanced hole mobility. XPS depth profiling measurements also showed that the additive molecules were predominantly positioned in the range of 25 nm under the surface of the P3HT:PCBM film, leading to improved fill factor.)</abstract><cop>Amsterdam</cop><pub>Elsevier</pub><doi>10.1016/j.solmat.2011.02.019</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0927-0248 |
| ispartof | Solar energy materials and solar cells, 2011-07, Vol.95 (7), p.1908-1914 |
| issn | 0927-0248 1879-3398 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_869586046 |
| source | Elsevier ScienceDirect Journals |
| subjects | Additives Applied sciences Conversion Devices Energy Exact sciences and technology Natural energy Order disorder Photovoltaic cells Photovoltaic conversion Solar cells Solar cells. Photoelectrochemical cells Solar energy Solar power generation X-ray photoelectron spectroscopy |
| title | Effects of a perfluorinated compound as an additive on the power conversion efficiencies of polymer solar cells |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-31T17%3A57%3A28IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Effects%20of%20a%20perfluorinated%20compound%20as%20an%20additive%20on%20the%20power%20conversion%20efficiencies%20of%20polymer%20solar%20cells&rft.jtitle=Solar%20energy%20materials%20and%20solar%20cells&rft.au=JEONG,%20Seonju&rft.date=2011-07-01&rft.volume=95&rft.issue=7&rft.spage=1908&rft.epage=1914&rft.pages=1908-1914&rft.issn=0927-0248&rft.eissn=1879-3398&rft_id=info:doi/10.1016/j.solmat.2011.02.019&rft_dat=%3Cproquest_cross%3E869586046%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1777115703&rft_id=info:pmid/&rfr_iscdi=true |