Analysis of hydrogen peroxide field samples by HPLC/FD and HPLC/ED in DC mode
Abstract The goal of this paper is to describe applications of two recently developed HPLC methods for the analysis and confirmation of the presence of hydrogen peroxide residues in field studies. The procedure utilizes two different HPLC systems, one with post-column derivatization followed by fluo...
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| Veröffentlicht in: | Forensic science international 2011-06, Vol.209 (1), p.166-172 |
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| creator | Tarvin, Megan McCord, Bruce Mount, Kelly Miller, Mark L |
| description | Abstract The goal of this paper is to describe applications of two recently developed HPLC methods for the analysis and confirmation of the presence of hydrogen peroxide residues in field studies. The procedure utilizes two different HPLC systems, one with post-column derivatization followed by fluorescence detection (HPLC/FD), and the other with electrochemical detection (HPLC/ED). The two systems were utilized to detect hydrogen peroxide in a variety of typical forensic samples including pre- and post-blast samples, as well as a series of environmental control samples. Peroxide-based organic explosives were also examined due to their propensity to produce peroxide residues following detonation. Because samples collected from post-blast scenes are frequently shipped or stored prior to analysis, the effects of storage time, temperature and type of substrate material on the recovery of hydrogen peroxide residues were also investigated. The combined results of the study demonstrate the capability of two HPLC approaches with selective detection in the analysis and investigation of suspected incidents involving peroxide based explosives. |
| doi_str_mv | 10.1016/j.forsciint.2011.01.024 |
| format | Article |
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The procedure utilizes two different HPLC systems, one with post-column derivatization followed by fluorescence detection (HPLC/FD), and the other with electrochemical detection (HPLC/ED). The two systems were utilized to detect hydrogen peroxide in a variety of typical forensic samples including pre- and post-blast samples, as well as a series of environmental control samples. Peroxide-based organic explosives were also examined due to their propensity to produce peroxide residues following detonation. Because samples collected from post-blast scenes are frequently shipped or stored prior to analysis, the effects of storage time, temperature and type of substrate material on the recovery of hydrogen peroxide residues were also investigated. The combined results of the study demonstrate the capability of two HPLC approaches with selective detection in the analysis and investigation of suspected incidents involving peroxide based explosives.</description><subject>Alliances</subject><subject>Biological and medical sciences</subject><subject>Chromatography</subject><subject>Detonation</subject><subject>Electrochemical detection</subject><subject>Electrodes</subject><subject>Environmental control</subject><subject>Explosives</subject><subject>Fluorescence</subject><subject>Fluorescence detection</subject><subject>Forensic chemistry</subject><subject>Forensic medicine</subject><subject>Forensic science</subject><subject>Forensic sciences</subject><subject>General aspects</subject><subject>HPLC</subject><subject>Hydrogen peroxide</subject><subject>Investigative techniques, diagnostic techniques (general aspects)</subject><subject>Medical sciences</subject><subject>Pathology</subject><subject>Peroxides</subject><subject>Public health. 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| identifier | ISSN: 0379-0738 |
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| source | Elsevier ScienceDirect Journals |
| subjects | Alliances Biological and medical sciences Chromatography Detonation Electrochemical detection Electrodes Environmental control Explosives Fluorescence Fluorescence detection Forensic chemistry Forensic medicine Forensic science Forensic sciences General aspects HPLC Hydrogen peroxide Investigative techniques, diagnostic techniques (general aspects) Medical sciences Pathology Peroxides Public health. Hygiene Public health. Hygiene-occupational medicine Residues Studies |
| title | Analysis of hydrogen peroxide field samples by HPLC/FD and HPLC/ED in DC mode |
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