One-Step Inversion Process to a Janus Emulsion with Two Mutually Insoluble Oils
High internal phase ratio (HIPR) aqueous Janus emulsions of two immiscible oils, silicone oil (SO) and a vegetable oil (VO), were prepared using a vibration mixer. The simple HIPR Janus emulsions, (VO + SO)/W, were found at weight fractions of the aqueous phase in excess of 0.3, while at a correspon...
Gespeichert in:
| Veröffentlicht in: | Langmuir 2011-06, Vol.27 (11), p.6584-6588 |
|---|---|
| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 6588 |
|---|---|
| container_issue | 11 |
| container_start_page | 6584 |
| container_title | Langmuir |
| container_volume | 27 |
| creator | Hasinovic, Hida Friberg, Stig E |
| description | High internal phase ratio (HIPR) aqueous Janus emulsions of two immiscible oils, silicone oil (SO) and a vegetable oil (VO), were prepared using a vibration mixer. The simple HIPR Janus emulsions, (VO + SO)/W, were found at weight fractions of the aqueous phase in excess of 0.3, while at a corresponding fraction of 0.1, a triple emulsion was obtained with the Janus emulsion forming a drop inside the vegetable oil to give a double Janus emulsion, (VO + SO)/W/VO, which in turn formed drops in the silicone oil resulting in a triple Janus emulsion (VO + SO)/W/VO/SO. Increasing the aqueous-phase fraction from 0.1 to 0.3 consequently meant an inversion, of which one intermediate stage was observed: a more complex configuration, e.g., one in which large SO drops with highly distorted VO drops attached were dispersed in a regular aqueous emulsion with spherical Janus (VO + SO) drops. A preliminary investigation was made into the destabilization process of the triple emulsions. |
| doi_str_mv | 10.1021/la105118h |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_869574512</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>869574512</sourcerecordid><originalsourceid>FETCH-LOGICAL-a344t-caad7476c7f5ddc95d71b3339c4fe6dc2ed88528a70cf8212f2c93a0d81845cc3</originalsourceid><addsrcrecordid>eNpt0LtOwzAUBmALgWgpDLwA8oIQQ8DX2hlRVW4qKhIwR67jqKncuPjEVLw9AUphYDrD-c5FP0LHlFxQwuilN5RISvV8B_WpZCSTmqld1CdK8EyJIe-hA4AFISTnIt9HPUYlF1LoPppOG5c9tW6F75o3F6EODX6MwToA3AZs8L1pEuDxMvmv3rpu5_h5HfBDapPx_r2bg-DTzDs8rT0cor3KeHBHmzpAL9fj59FtNpne3I2uJpnhQrSZNaZUQg2tqmRZ2lyWis4457kVlRuWlrlSa8m0UcRWmlFWMZtzQ0pNtZDW8gE6-967iuE1OWiLZQ3WeW8aFxIUephLJSRlnTz_ljYGgOiqYhXrpYnvBSXFZ3zFNr7Onmy2ptnSlVv5k1cHTjfAgDW-iqaxNfw60b2q6B9nLBSLkGLThfHPwQ83y4L9</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>869574512</pqid></control><display><type>article</type><title>One-Step Inversion Process to a Janus Emulsion with Two Mutually Insoluble Oils</title><source>MEDLINE</source><source>American Chemical Society Journals</source><creator>Hasinovic, Hida ; Friberg, Stig E</creator><creatorcontrib>Hasinovic, Hida ; Friberg, Stig E</creatorcontrib><description>High internal phase ratio (HIPR) aqueous Janus emulsions of two immiscible oils, silicone oil (SO) and a vegetable oil (VO), were prepared using a vibration mixer. The simple HIPR Janus emulsions, (VO + SO)/W, were found at weight fractions of the aqueous phase in excess of 0.3, while at a corresponding fraction of 0.1, a triple emulsion was obtained with the Janus emulsion forming a drop inside the vegetable oil to give a double Janus emulsion, (VO + SO)/W/VO, which in turn formed drops in the silicone oil resulting in a triple Janus emulsion (VO + SO)/W/VO/SO. Increasing the aqueous-phase fraction from 0.1 to 0.3 consequently meant an inversion, of which one intermediate stage was observed: a more complex configuration, e.g., one in which large SO drops with highly distorted VO drops attached were dispersed in a regular aqueous emulsion with spherical Janus (VO + SO) drops. A preliminary investigation was made into the destabilization process of the triple emulsions.</description><identifier>ISSN: 0743-7463</identifier><identifier>EISSN: 1520-5827</identifier><identifier>DOI: 10.1021/la105118h</identifier><identifier>PMID: 21534548</identifier><identifier>CODEN: LANGD5</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Chemistry ; Colloidal state and disperse state ; Colloids: Surfactants and Self-Assembly, Dispersions, Emulsions, Foams ; Emulsions ; Emulsions. Microemulsions. Foams ; Exact sciences and technology ; General and physical chemistry ; Plant Oils - chemistry ; Silicone Oils - chemistry ; Solubility ; Time Factors ; Water - chemistry</subject><ispartof>Langmuir, 2011-06, Vol.27 (11), p.6584-6588</ispartof><rights>Copyright © 2011 American Chemical Society</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a344t-caad7476c7f5ddc95d71b3339c4fe6dc2ed88528a70cf8212f2c93a0d81845cc3</citedby><cites>FETCH-LOGICAL-a344t-caad7476c7f5ddc95d71b3339c4fe6dc2ed88528a70cf8212f2c93a0d81845cc3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/la105118h$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/la105118h$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,2752,27053,27901,27902,56713,56763</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=24212718$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/21534548$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Hasinovic, Hida</creatorcontrib><creatorcontrib>Friberg, Stig E</creatorcontrib><title>One-Step Inversion Process to a Janus Emulsion with Two Mutually Insoluble Oils</title><title>Langmuir</title><addtitle>Langmuir</addtitle><description>High internal phase ratio (HIPR) aqueous Janus emulsions of two immiscible oils, silicone oil (SO) and a vegetable oil (VO), were prepared using a vibration mixer. The simple HIPR Janus emulsions, (VO + SO)/W, were found at weight fractions of the aqueous phase in excess of 0.3, while at a corresponding fraction of 0.1, a triple emulsion was obtained with the Janus emulsion forming a drop inside the vegetable oil to give a double Janus emulsion, (VO + SO)/W/VO, which in turn formed drops in the silicone oil resulting in a triple Janus emulsion (VO + SO)/W/VO/SO. Increasing the aqueous-phase fraction from 0.1 to 0.3 consequently meant an inversion, of which one intermediate stage was observed: a more complex configuration, e.g., one in which large SO drops with highly distorted VO drops attached were dispersed in a regular aqueous emulsion with spherical Janus (VO + SO) drops. A preliminary investigation was made into the destabilization process of the triple emulsions.</description><subject>Chemistry</subject><subject>Colloidal state and disperse state</subject><subject>Colloids: Surfactants and Self-Assembly, Dispersions, Emulsions, Foams</subject><subject>Emulsions</subject><subject>Emulsions. Microemulsions. Foams</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Plant Oils - chemistry</subject><subject>Silicone Oils - chemistry</subject><subject>Solubility</subject><subject>Time Factors</subject><subject>Water - chemistry</subject><issn>0743-7463</issn><issn>1520-5827</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNpt0LtOwzAUBmALgWgpDLwA8oIQQ8DX2hlRVW4qKhIwR67jqKncuPjEVLw9AUphYDrD-c5FP0LHlFxQwuilN5RISvV8B_WpZCSTmqld1CdK8EyJIe-hA4AFISTnIt9HPUYlF1LoPppOG5c9tW6F75o3F6EODX6MwToA3AZs8L1pEuDxMvmv3rpu5_h5HfBDapPx_r2bg-DTzDs8rT0cor3KeHBHmzpAL9fj59FtNpne3I2uJpnhQrSZNaZUQg2tqmRZ2lyWis4457kVlRuWlrlSa8m0UcRWmlFWMZtzQ0pNtZDW8gE6-967iuE1OWiLZQ3WeW8aFxIUephLJSRlnTz_ljYGgOiqYhXrpYnvBSXFZ3zFNr7Onmy2ptnSlVv5k1cHTjfAgDW-iqaxNfw60b2q6B9nLBSLkGLThfHPwQ83y4L9</recordid><startdate>20110607</startdate><enddate>20110607</enddate><creator>Hasinovic, Hida</creator><creator>Friberg, Stig E</creator><general>American Chemical Society</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20110607</creationdate><title>One-Step Inversion Process to a Janus Emulsion with Two Mutually Insoluble Oils</title><author>Hasinovic, Hida ; Friberg, Stig E</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a344t-caad7476c7f5ddc95d71b3339c4fe6dc2ed88528a70cf8212f2c93a0d81845cc3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Chemistry</topic><topic>Colloidal state and disperse state</topic><topic>Colloids: Surfactants and Self-Assembly, Dispersions, Emulsions, Foams</topic><topic>Emulsions</topic><topic>Emulsions. Microemulsions. Foams</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Plant Oils - chemistry</topic><topic>Silicone Oils - chemistry</topic><topic>Solubility</topic><topic>Time Factors</topic><topic>Water - chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hasinovic, Hida</creatorcontrib><creatorcontrib>Friberg, Stig E</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Langmuir</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hasinovic, Hida</au><au>Friberg, Stig E</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>One-Step Inversion Process to a Janus Emulsion with Two Mutually Insoluble Oils</atitle><jtitle>Langmuir</jtitle><addtitle>Langmuir</addtitle><date>2011-06-07</date><risdate>2011</risdate><volume>27</volume><issue>11</issue><spage>6584</spage><epage>6588</epage><pages>6584-6588</pages><issn>0743-7463</issn><eissn>1520-5827</eissn><coden>LANGD5</coden><abstract>High internal phase ratio (HIPR) aqueous Janus emulsions of two immiscible oils, silicone oil (SO) and a vegetable oil (VO), were prepared using a vibration mixer. The simple HIPR Janus emulsions, (VO + SO)/W, were found at weight fractions of the aqueous phase in excess of 0.3, while at a corresponding fraction of 0.1, a triple emulsion was obtained with the Janus emulsion forming a drop inside the vegetable oil to give a double Janus emulsion, (VO + SO)/W/VO, which in turn formed drops in the silicone oil resulting in a triple Janus emulsion (VO + SO)/W/VO/SO. Increasing the aqueous-phase fraction from 0.1 to 0.3 consequently meant an inversion, of which one intermediate stage was observed: a more complex configuration, e.g., one in which large SO drops with highly distorted VO drops attached were dispersed in a regular aqueous emulsion with spherical Janus (VO + SO) drops. A preliminary investigation was made into the destabilization process of the triple emulsions.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><pmid>21534548</pmid><doi>10.1021/la105118h</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0743-7463 |
| ispartof | Langmuir, 2011-06, Vol.27 (11), p.6584-6588 |
| issn | 0743-7463 1520-5827 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_869574512 |
| source | MEDLINE; American Chemical Society Journals |
| subjects | Chemistry Colloidal state and disperse state Colloids: Surfactants and Self-Assembly, Dispersions, Emulsions, Foams Emulsions Emulsions. Microemulsions. Foams Exact sciences and technology General and physical chemistry Plant Oils - chemistry Silicone Oils - chemistry Solubility Time Factors Water - chemistry |
| title | One-Step Inversion Process to a Janus Emulsion with Two Mutually Insoluble Oils |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-07T16%3A51%3A08IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=One-Step%20Inversion%20Process%20to%20a%20Janus%20Emulsion%20with%20Two%20Mutually%20Insoluble%20Oils&rft.jtitle=Langmuir&rft.au=Hasinovic,%20Hida&rft.date=2011-06-07&rft.volume=27&rft.issue=11&rft.spage=6584&rft.epage=6588&rft.pages=6584-6588&rft.issn=0743-7463&rft.eissn=1520-5827&rft.coden=LANGD5&rft_id=info:doi/10.1021/la105118h&rft_dat=%3Cproquest_cross%3E869574512%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=869574512&rft_id=info:pmid/21534548&rfr_iscdi=true |