Classical Retention Mechanism in Ion Exchange Chromatography. Theory and Experiment
The classical model for ion exchange chromatography is characterized by firmly adsorbed driving ions at the surface of the stationary phase in an amount required by electroneutrality and stoichiometric ion exchange between the bulk of the eluent electrolyte and this immobilized Stern layer. Retentio...
Gespeichert in:
| Veröffentlicht in: | Analytical chemistry (Washington) 1996-08, Vol.68 (15), p.2580-2589 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 2589 |
|---|---|
| container_issue | 15 |
| container_start_page | 2580 |
| container_title | Analytical chemistry (Washington) |
| container_volume | 68 |
| creator | Fóti, György Révész, Gabriella Hajós, Péter Pellaton, Gabrielle sz. Kováts, Ervin |
| description | The classical model for ion exchange chromatography is characterized by firmly adsorbed driving ions at the surface of the stationary phase in an amount required by electroneutrality and stoichiometric ion exchange between the bulk of the eluent electrolyte and this immobilized Stern layer. Retention equations have been derived for system peaks, labeled eluent ions, and analytes in a system containing only strong electrolytes by strictly respecting this model. It is shown that the classical model described dependence of retention data on concentration and composition of the binary eluent with excellent precision, but the resulting system parameters were not self-consistent. Inconsistency of the results might be due to contributions from another retention mechanism. |
| doi_str_mv | 10.1021/ac9600159 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_869571569</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>869571569</sourcerecordid><originalsourceid>FETCH-LOGICAL-a406t-eafc48e59cedb45fa9fc386bce9189520f7426c90f1d8c90b5a8b056131766d03</originalsourceid><addsrcrecordid>eNpl0F1rFDEUBuAgit22XvgHZBCLeDH1nMwkk1zKWGthtWJXEG_CmUymO3U-1mQWuv_eLLvdgl4FTh4O530Ze4lwjsDxPVktAVDoJ2yGgkMqleJP2QwAspQXAEfsOIS7SBBQPmdHHCVqDvmM3ZQdhdBa6pLvbnLD1I5D8sXZJQ1t6JN2SK7i4OJ-O7h1Sbn0Y0_TeOtptdycJ4ulG_0moaGOZuV828cVp-xZQ11wL_bvCfvx6WJRfk7n15dX5Yd5SjnIKXXU2Fw5oa2rq1w0pBubKVlZp1HpGKMpci6thgZrFZ9KkKpASMywkLKG7IS93e1d-fHP2oXJ9G2wrutocOM6GCW1KFBIHeXrf-TduPZDPM5wLJQQWmYRvdsh68cQvGvMKuYhvzEIZtuzOfQc7av9wnXVu_ogH4qN4M0eUIjlNp4G24aDy1ByUDyydMfaMLn7wzf530YWWSHM4tuNKfHrx8tfP-dmG_ls58mGxwz_3_cXSqKeLQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>217855963</pqid></control><display><type>article</type><title>Classical Retention Mechanism in Ion Exchange Chromatography. Theory and Experiment</title><source>ACS Publications</source><creator>Fóti, György ; Révész, Gabriella ; Hajós, Péter ; Pellaton, Gabrielle ; sz. Kováts, Ervin</creator><creatorcontrib>Fóti, György ; Révész, Gabriella ; Hajós, Péter ; Pellaton, Gabrielle ; sz. Kováts, Ervin</creatorcontrib><description>The classical model for ion exchange chromatography is characterized by firmly adsorbed driving ions at the surface of the stationary phase in an amount required by electroneutrality and stoichiometric ion exchange between the bulk of the eluent electrolyte and this immobilized Stern layer. Retention equations have been derived for system peaks, labeled eluent ions, and analytes in a system containing only strong electrolytes by strictly respecting this model. It is shown that the classical model described dependence of retention data on concentration and composition of the binary eluent with excellent precision, but the resulting system parameters were not self-consistent. Inconsistency of the results might be due to contributions from another retention mechanism.</description><identifier>ISSN: 0003-2700</identifier><identifier>EISSN: 1520-6882</identifier><identifier>DOI: 10.1021/ac9600159</identifier><identifier>PMID: 21619204</identifier><identifier>CODEN: ANCHAM</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Analytical chemistry ; Chemistry ; Chromatographic methods and physical methods associated with chromatography ; Exact sciences and technology ; Ions ; Other chromatographic methods ; Theory</subject><ispartof>Analytical chemistry (Washington), 1996-08, Vol.68 (15), p.2580-2589</ispartof><rights>Copyright © 1996 American Chemical Society</rights><rights>1996 INIST-CNRS</rights><rights>Copyright American Chemical Society Aug 1, 1996</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a406t-eafc48e59cedb45fa9fc386bce9189520f7426c90f1d8c90b5a8b056131766d03</citedby><cites>FETCH-LOGICAL-a406t-eafc48e59cedb45fa9fc386bce9189520f7426c90f1d8c90b5a8b056131766d03</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/ac9600159$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/ac9600159$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,2765,27076,27924,27925,56738,56788</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=3162082$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/21619204$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Fóti, György</creatorcontrib><creatorcontrib>Révész, Gabriella</creatorcontrib><creatorcontrib>Hajós, Péter</creatorcontrib><creatorcontrib>Pellaton, Gabrielle</creatorcontrib><creatorcontrib>sz. Kováts, Ervin</creatorcontrib><title>Classical Retention Mechanism in Ion Exchange Chromatography. Theory and Experiment</title><title>Analytical chemistry (Washington)</title><addtitle>Anal. Chem</addtitle><description>The classical model for ion exchange chromatography is characterized by firmly adsorbed driving ions at the surface of the stationary phase in an amount required by electroneutrality and stoichiometric ion exchange between the bulk of the eluent electrolyte and this immobilized Stern layer. Retention equations have been derived for system peaks, labeled eluent ions, and analytes in a system containing only strong electrolytes by strictly respecting this model. It is shown that the classical model described dependence of retention data on concentration and composition of the binary eluent with excellent precision, but the resulting system parameters were not self-consistent. Inconsistency of the results might be due to contributions from another retention mechanism.</description><subject>Analytical chemistry</subject><subject>Chemistry</subject><subject>Chromatographic methods and physical methods associated with chromatography</subject><subject>Exact sciences and technology</subject><subject>Ions</subject><subject>Other chromatographic methods</subject><subject>Theory</subject><issn>0003-2700</issn><issn>1520-6882</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1996</creationdate><recordtype>article</recordtype><recordid>eNpl0F1rFDEUBuAgit22XvgHZBCLeDH1nMwkk1zKWGthtWJXEG_CmUymO3U-1mQWuv_eLLvdgl4FTh4O530Ze4lwjsDxPVktAVDoJ2yGgkMqleJP2QwAspQXAEfsOIS7SBBQPmdHHCVqDvmM3ZQdhdBa6pLvbnLD1I5D8sXZJQ1t6JN2SK7i4OJ-O7h1Sbn0Y0_TeOtptdycJ4ulG_0moaGOZuV828cVp-xZQ11wL_bvCfvx6WJRfk7n15dX5Yd5SjnIKXXU2Fw5oa2rq1w0pBubKVlZp1HpGKMpci6thgZrFZ9KkKpASMywkLKG7IS93e1d-fHP2oXJ9G2wrutocOM6GCW1KFBIHeXrf-TduPZDPM5wLJQQWmYRvdsh68cQvGvMKuYhvzEIZtuzOfQc7av9wnXVu_ogH4qN4M0eUIjlNp4G24aDy1ByUDyydMfaMLn7wzf530YWWSHM4tuNKfHrx8tfP-dmG_ls58mGxwz_3_cXSqKeLQ</recordid><startdate>19960801</startdate><enddate>19960801</enddate><creator>Fóti, György</creator><creator>Révész, Gabriella</creator><creator>Hajós, Péter</creator><creator>Pellaton, Gabrielle</creator><creator>sz. Kováts, Ervin</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SC</scope><scope>7SE</scope><scope>7SP</scope><scope>7SR</scope><scope>7TA</scope><scope>7TB</scope><scope>7TM</scope><scope>7U5</scope><scope>7U7</scope><scope>7U9</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>F28</scope><scope>FR3</scope><scope>H8D</scope><scope>H8G</scope><scope>H94</scope><scope>JG9</scope><scope>JQ2</scope><scope>KR7</scope><scope>L7M</scope><scope>L~C</scope><scope>L~D</scope><scope>P64</scope><scope>7X8</scope></search><sort><creationdate>19960801</creationdate><title>Classical Retention Mechanism in Ion Exchange Chromatography. Theory and Experiment</title><author>Fóti, György ; Révész, Gabriella ; Hajós, Péter ; Pellaton, Gabrielle ; sz. Kováts, Ervin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a406t-eafc48e59cedb45fa9fc386bce9189520f7426c90f1d8c90b5a8b056131766d03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1996</creationdate><topic>Analytical chemistry</topic><topic>Chemistry</topic><topic>Chromatographic methods and physical methods associated with chromatography</topic><topic>Exact sciences and technology</topic><topic>Ions</topic><topic>Other chromatographic methods</topic><topic>Theory</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Fóti, György</creatorcontrib><creatorcontrib>Révész, Gabriella</creatorcontrib><creatorcontrib>Hajós, Péter</creatorcontrib><creatorcontrib>Pellaton, Gabrielle</creatorcontrib><creatorcontrib>sz. Kováts, Ervin</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Biotechnology Research Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Computer and Information Systems Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Materials Business File</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Nucleic Acids Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Toxicology Abstracts</collection><collection>Virology and AIDS Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Copper Technical Reference Library</collection><collection>AIDS and Cancer Research Abstracts</collection><collection>Materials Research Database</collection><collection>ProQuest Computer Science Collection</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Computer and Information Systems Abstracts Academic</collection><collection>Computer and Information Systems Abstracts Professional</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>MEDLINE - Academic</collection><jtitle>Analytical chemistry (Washington)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Fóti, György</au><au>Révész, Gabriella</au><au>Hajós, Péter</au><au>Pellaton, Gabrielle</au><au>sz. Kováts, Ervin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Classical Retention Mechanism in Ion Exchange Chromatography. Theory and Experiment</atitle><jtitle>Analytical chemistry (Washington)</jtitle><addtitle>Anal. Chem</addtitle><date>1996-08-01</date><risdate>1996</risdate><volume>68</volume><issue>15</issue><spage>2580</spage><epage>2589</epage><pages>2580-2589</pages><issn>0003-2700</issn><eissn>1520-6882</eissn><coden>ANCHAM</coden><abstract>The classical model for ion exchange chromatography is characterized by firmly adsorbed driving ions at the surface of the stationary phase in an amount required by electroneutrality and stoichiometric ion exchange between the bulk of the eluent electrolyte and this immobilized Stern layer. Retention equations have been derived for system peaks, labeled eluent ions, and analytes in a system containing only strong electrolytes by strictly respecting this model. It is shown that the classical model described dependence of retention data on concentration and composition of the binary eluent with excellent precision, but the resulting system parameters were not self-consistent. Inconsistency of the results might be due to contributions from another retention mechanism.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><pmid>21619204</pmid><doi>10.1021/ac9600159</doi><tpages>10</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0003-2700 |
| ispartof | Analytical chemistry (Washington), 1996-08, Vol.68 (15), p.2580-2589 |
| issn | 0003-2700 1520-6882 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_869571569 |
| source | ACS Publications |
| subjects | Analytical chemistry Chemistry Chromatographic methods and physical methods associated with chromatography Exact sciences and technology Ions Other chromatographic methods Theory |
| title | Classical Retention Mechanism in Ion Exchange Chromatography. Theory and Experiment |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-21T13%3A28%3A57IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Classical%20Retention%20Mechanism%20in%20Ion%20Exchange%20Chromatography.%20Theory%20and%20Experiment&rft.jtitle=Analytical%20chemistry%20(Washington)&rft.au=F%C3%B3ti,%20Gy%C3%B6rgy&rft.date=1996-08-01&rft.volume=68&rft.issue=15&rft.spage=2580&rft.epage=2589&rft.pages=2580-2589&rft.issn=0003-2700&rft.eissn=1520-6882&rft.coden=ANCHAM&rft_id=info:doi/10.1021/ac9600159&rft_dat=%3Cproquest_cross%3E869571569%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=217855963&rft_id=info:pmid/21619204&rfr_iscdi=true |