Synthesis of Oxidized Thienopyrroles using HOF·CH3CN
An efficient transformation of the sulfur atoms to the sulfonyl group in a range of thienopyrroles was achieved by using the HOF·CH3CN complex. Mild conditions, high yields, and easy purification are the main features of this novel route. Most new materials exhibit considerable red-shift absorptions...
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Veröffentlicht in: | Journal of organic chemistry 2011-06, Vol.76 (11), p.4611-4616 |
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container_title | Journal of organic chemistry |
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creator | Shefer, Neta Rozen, Shlomo |
description | An efficient transformation of the sulfur atoms to the sulfonyl group in a range of thienopyrroles was achieved by using the HOF·CH3CN complex. Mild conditions, high yields, and easy purification are the main features of this novel route. Most new materials exhibit considerable red-shift absorptions in the UV/visible range relative to the parent compounds. |
doi_str_mv | 10.1021/jo200534p |
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Mild conditions, high yields, and easy purification are the main features of this novel route. Most new materials exhibit considerable red-shift absorptions in the UV/visible range relative to the parent compounds.</description><identifier>ISSN: 0022-3263</identifier><identifier>EISSN: 1520-6904</identifier><identifier>DOI: 10.1021/jo200534p</identifier><identifier>PMID: 21513352</identifier><identifier>CODEN: JOCEAH</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Chemistry ; Exact sciences and technology ; Heterocyclic compounds ; Heterocyclic compounds with n hetero atom and also o and/or s, se, te hetero atoms ; Organic chemistry ; Preparations and properties</subject><ispartof>Journal of organic chemistry, 2011-06, Vol.76 (11), p.4611-4616</ispartof><rights>Copyright © 2011 American Chemical Society</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/jo200534p$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/jo200534p$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,27053,27901,27902,56713,56763</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=24199103$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/21513352$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Shefer, Neta</creatorcontrib><creatorcontrib>Rozen, Shlomo</creatorcontrib><title>Synthesis of Oxidized Thienopyrroles using HOF·CH3CN</title><title>Journal of organic chemistry</title><addtitle>J. Org. Chem</addtitle><description>An efficient transformation of the sulfur atoms to the sulfonyl group in a range of thienopyrroles was achieved by using the HOF·CH3CN complex. Mild conditions, high yields, and easy purification are the main features of this novel route. Most new materials exhibit considerable red-shift absorptions in the UV/visible range relative to the parent compounds.</description><subject>Chemistry</subject><subject>Exact sciences and technology</subject><subject>Heterocyclic compounds</subject><subject>Heterocyclic compounds with n hetero atom and also o and/or s, se, te hetero atoms</subject><subject>Organic chemistry</subject><subject>Preparations and properties</subject><issn>0022-3263</issn><issn>1520-6904</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNpF0LFOwzAQBmALgWgpDLwAyoKYAmf7nMYjilqKVNGBMluOY1NXaRLiRqK8GDtPRhCF3nLLp9N_PyGXFG4pMHq3rhmA4NgckSEVDOJEAh6TIQBjMWcJH5CzENbQjxDilAwYFZRzwYZEPO-q7coGH6LaRYt3X_gPW0TLlbdV3ezati5tiLrgq9dotph-fWYznj2dkxOny2Av9ntEXqaTZTaL54uHx-x-Hmsm6DZGZyWaVDpAicByk8g-b1LQApkAx5ylqA2CSQwg5rkdS8ktOqGRphoTPiI3v3ebtn7rbNiqjQ_GlqWubN0FlSaplGMqeC-v9rLLN7ZQTes3ut2pv097cL0HOhhdulZXxoeDQyr7cPzgtAlqXXdt1T-oKKifptV_0_wbIvtrjw</recordid><startdate>20110603</startdate><enddate>20110603</enddate><creator>Shefer, Neta</creator><creator>Rozen, Shlomo</creator><general>American Chemical Society</general><scope>IQODW</scope><scope>NPM</scope><scope>7X8</scope></search><sort><creationdate>20110603</creationdate><title>Synthesis of Oxidized Thienopyrroles using HOF·CH3CN</title><author>Shefer, Neta ; Rozen, Shlomo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a251t-4fe94c89f049402bc691026d1d4250f2fe14ac40c6c044bbe7993e4f5a418a463</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Chemistry</topic><topic>Exact sciences and technology</topic><topic>Heterocyclic compounds</topic><topic>Heterocyclic compounds with n hetero atom and also o and/or s, se, te hetero atoms</topic><topic>Organic chemistry</topic><topic>Preparations and properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Shefer, Neta</creatorcontrib><creatorcontrib>Rozen, Shlomo</creatorcontrib><collection>Pascal-Francis</collection><collection>PubMed</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of organic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shefer, Neta</au><au>Rozen, Shlomo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of Oxidized Thienopyrroles using HOF·CH3CN</atitle><jtitle>Journal of organic chemistry</jtitle><addtitle>J. Org. Chem</addtitle><date>2011-06-03</date><risdate>2011</risdate><volume>76</volume><issue>11</issue><spage>4611</spage><epage>4616</epage><pages>4611-4616</pages><issn>0022-3263</issn><eissn>1520-6904</eissn><coden>JOCEAH</coden><abstract>An efficient transformation of the sulfur atoms to the sulfonyl group in a range of thienopyrroles was achieved by using the HOF·CH3CN complex. Mild conditions, high yields, and easy purification are the main features of this novel route. Most new materials exhibit considerable red-shift absorptions in the UV/visible range relative to the parent compounds.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><pmid>21513352</pmid><doi>10.1021/jo200534p</doi><tpages>6</tpages></addata></record> |
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subjects | Chemistry Exact sciences and technology Heterocyclic compounds Heterocyclic compounds with n hetero atom and also o and/or s, se, te hetero atoms Organic chemistry Preparations and properties |
title | Synthesis of Oxidized Thienopyrroles using HOF·CH3CN |
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