Metal-Ligand-Containing Polymers: Terpyridine as the Supramolecular Unit

New and interesting properties can be obtained from macromolecular architectures functionalized with supramolecular moieties, particularly metal–ligand complexes. Self‐assembly, based on the selective control of noncovalent interactions, guides the creation of hierarchically ordered materials provid...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Macromolecular rapid communications. 2010-05, Vol.31 (9-10), p.784-793
Hauptverfasser: Shunmugam, Raja, Gabriel, Gregory J., Aamer, Khaled A., Tew, Gregory N.
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 793
container_issue 9-10
container_start_page 784
container_title Macromolecular rapid communications.
container_volume 31
creator Shunmugam, Raja
Gabriel, Gregory J.
Aamer, Khaled A.
Tew, Gregory N.
description New and interesting properties can be obtained from macromolecular architectures functionalized with supramolecular moieties, particularly metal–ligand complexes. Self‐assembly, based on the selective control of noncovalent interactions, guides the creation of hierarchically ordered materials providing access to novel structures and new properties. This field has expanded significantly in the last two decades, and one of the most ubiquitous functionalities is terpyridine. Despite its wide‐spread use, much basic knowledge regarding the binding of terpyridine with metal ions remains unknown. Here, the binding constants of PEG‐substituted terpyridine in relation to other literature reports are studied and a few examples of supramolecular materials from our laboratory are summarized. Terpyridine‐complex containing homopolymers (left) and block copolymers (right) behaved as rigid‐rod‐like molecules due to the increase in persistence length generated by the metal complex. This leads to interesting self‐assembling including hierarchical length scales in the block copolymer.
doi_str_mv 10.1002/marc.200900869
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_867726433</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>867726433</sourcerecordid><originalsourceid>FETCH-LOGICAL-c4809-76ff2c61e1cf734dd19ea98c4fd9770226b348b0dd4f28e23151ed7a69c18e133</originalsourceid><addsrcrecordid>eNqFkElPIzEQRi00iP06x1Hf5tTBS8cLN9QDCRAWsYij5djV4JleMna3IP8eo0DEjVPV4X2fqh5CPwkeEYzpYWOCHVGMFcaSqw20Q8aU5ExR8SPtmNKcMMa30W6Mf3FiCky30DYlY4WVIDtoegm9qfOZfzKty8uu7Y1vffuU3XT1soEQj7J7CItl8M63kJmY9c-Q3Q2LYJquBjvUJmQPre_30WZl6ggHH3MPPZye3JfTfHY9OSuPZ7ktJFa54FVFLSdAbCVY4RxRYJS0ReWUEOlePmeFnGPniopKoIyMCThhuLJEQvplD_1e9S5C93-A2OvGRwt1bVrohqglF4Lygn1PCimSQkJ5Ikcr0oYuxgCVXgSfzC41wfpds37XrNeaU-DXR_Uwb8Ct8U-vCVAr4MXXsPymTl8e35Zfy_NV1sceXtdZE_5pLpgY68eriZ78mUp1Xt7qC_YGtO6YCg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>787100126</pqid></control><display><type>article</type><title>Metal-Ligand-Containing Polymers: Terpyridine as the Supramolecular Unit</title><source>Wiley Online Library Journals Frontfile Complete</source><creator>Shunmugam, Raja ; Gabriel, Gregory J. ; Aamer, Khaled A. ; Tew, Gregory N.</creator><creatorcontrib>Shunmugam, Raja ; Gabriel, Gregory J. ; Aamer, Khaled A. ; Tew, Gregory N.</creatorcontrib><description>New and interesting properties can be obtained from macromolecular architectures functionalized with supramolecular moieties, particularly metal–ligand complexes. Self‐assembly, based on the selective control of noncovalent interactions, guides the creation of hierarchically ordered materials providing access to novel structures and new properties. This field has expanded significantly in the last two decades, and one of the most ubiquitous functionalities is terpyridine. Despite its wide‐spread use, much basic knowledge regarding the binding of terpyridine with metal ions remains unknown. Here, the binding constants of PEG‐substituted terpyridine in relation to other literature reports are studied and a few examples of supramolecular materials from our laboratory are summarized. Terpyridine‐complex containing homopolymers (left) and block copolymers (right) behaved as rigid‐rod‐like molecules due to the increase in persistence length generated by the metal complex. This leads to interesting self‐assembling including hierarchical length scales in the block copolymer.</description><identifier>ISSN: 1022-1336</identifier><identifier>EISSN: 1521-3927</identifier><identifier>DOI: 10.1002/marc.200900869</identifier><identifier>PMID: 21590971</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Access control ; amphiphile ; Architecture ; ATRP ; Binding ; binding constant ; Constants ; Materials selection ; Metal ions ; polymer ; Polymers ; Self assembly ; supramolecular ; terpyridine</subject><ispartof>Macromolecular rapid communications., 2010-05, Vol.31 (9-10), p.784-793</ispartof><rights>Copyright © 2010 WILEY‐VCH Verlag GmbH &amp; Co. KGaA, Weinheim</rights><rights>Copyright © 2010 WILEY-VCH Verlag GmbH &amp; Co. KGaA, Weinheim.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4809-76ff2c61e1cf734dd19ea98c4fd9770226b348b0dd4f28e23151ed7a69c18e133</citedby><cites>FETCH-LOGICAL-c4809-76ff2c61e1cf734dd19ea98c4fd9770226b348b0dd4f28e23151ed7a69c18e133</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fmarc.200900869$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fmarc.200900869$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,778,782,1414,27907,27908,45557,45558</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/21590971$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Shunmugam, Raja</creatorcontrib><creatorcontrib>Gabriel, Gregory J.</creatorcontrib><creatorcontrib>Aamer, Khaled A.</creatorcontrib><creatorcontrib>Tew, Gregory N.</creatorcontrib><title>Metal-Ligand-Containing Polymers: Terpyridine as the Supramolecular Unit</title><title>Macromolecular rapid communications.</title><addtitle>Macromol. Rapid Commun</addtitle><description>New and interesting properties can be obtained from macromolecular architectures functionalized with supramolecular moieties, particularly metal–ligand complexes. Self‐assembly, based on the selective control of noncovalent interactions, guides the creation of hierarchically ordered materials providing access to novel structures and new properties. This field has expanded significantly in the last two decades, and one of the most ubiquitous functionalities is terpyridine. Despite its wide‐spread use, much basic knowledge regarding the binding of terpyridine with metal ions remains unknown. Here, the binding constants of PEG‐substituted terpyridine in relation to other literature reports are studied and a few examples of supramolecular materials from our laboratory are summarized. Terpyridine‐complex containing homopolymers (left) and block copolymers (right) behaved as rigid‐rod‐like molecules due to the increase in persistence length generated by the metal complex. This leads to interesting self‐assembling including hierarchical length scales in the block copolymer.</description><subject>Access control</subject><subject>amphiphile</subject><subject>Architecture</subject><subject>ATRP</subject><subject>Binding</subject><subject>binding constant</subject><subject>Constants</subject><subject>Materials selection</subject><subject>Metal ions</subject><subject>polymer</subject><subject>Polymers</subject><subject>Self assembly</subject><subject>supramolecular</subject><subject>terpyridine</subject><issn>1022-1336</issn><issn>1521-3927</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNqFkElPIzEQRi00iP06x1Hf5tTBS8cLN9QDCRAWsYij5djV4JleMna3IP8eo0DEjVPV4X2fqh5CPwkeEYzpYWOCHVGMFcaSqw20Q8aU5ExR8SPtmNKcMMa30W6Mf3FiCky30DYlY4WVIDtoegm9qfOZfzKty8uu7Y1vffuU3XT1soEQj7J7CItl8M63kJmY9c-Q3Q2LYJquBjvUJmQPre_30WZl6ggHH3MPPZye3JfTfHY9OSuPZ7ktJFa54FVFLSdAbCVY4RxRYJS0ReWUEOlePmeFnGPniopKoIyMCThhuLJEQvplD_1e9S5C93-A2OvGRwt1bVrohqglF4Lygn1PCimSQkJ5Ikcr0oYuxgCVXgSfzC41wfpds37XrNeaU-DXR_Uwb8Ct8U-vCVAr4MXXsPymTl8e35Zfy_NV1sceXtdZE_5pLpgY68eriZ78mUp1Xt7qC_YGtO6YCg</recordid><startdate>20100512</startdate><enddate>20100512</enddate><creator>Shunmugam, Raja</creator><creator>Gabriel, Gregory J.</creator><creator>Aamer, Khaled A.</creator><creator>Tew, Gregory N.</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><scope>BSCLL</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope></search><sort><creationdate>20100512</creationdate><title>Metal-Ligand-Containing Polymers: Terpyridine as the Supramolecular Unit</title><author>Shunmugam, Raja ; Gabriel, Gregory J. ; Aamer, Khaled A. ; Tew, Gregory N.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4809-76ff2c61e1cf734dd19ea98c4fd9770226b348b0dd4f28e23151ed7a69c18e133</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Access control</topic><topic>amphiphile</topic><topic>Architecture</topic><topic>ATRP</topic><topic>Binding</topic><topic>binding constant</topic><topic>Constants</topic><topic>Materials selection</topic><topic>Metal ions</topic><topic>polymer</topic><topic>Polymers</topic><topic>Self assembly</topic><topic>supramolecular</topic><topic>terpyridine</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Shunmugam, Raja</creatorcontrib><creatorcontrib>Gabriel, Gregory J.</creatorcontrib><creatorcontrib>Aamer, Khaled A.</creatorcontrib><creatorcontrib>Tew, Gregory N.</creatorcontrib><collection>Istex</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Macromolecular rapid communications.</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shunmugam, Raja</au><au>Gabriel, Gregory J.</au><au>Aamer, Khaled A.</au><au>Tew, Gregory N.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Metal-Ligand-Containing Polymers: Terpyridine as the Supramolecular Unit</atitle><jtitle>Macromolecular rapid communications.</jtitle><addtitle>Macromol. Rapid Commun</addtitle><date>2010-05-12</date><risdate>2010</risdate><volume>31</volume><issue>9-10</issue><spage>784</spage><epage>793</epage><pages>784-793</pages><issn>1022-1336</issn><eissn>1521-3927</eissn><abstract>New and interesting properties can be obtained from macromolecular architectures functionalized with supramolecular moieties, particularly metal–ligand complexes. Self‐assembly, based on the selective control of noncovalent interactions, guides the creation of hierarchically ordered materials providing access to novel structures and new properties. This field has expanded significantly in the last two decades, and one of the most ubiquitous functionalities is terpyridine. Despite its wide‐spread use, much basic knowledge regarding the binding of terpyridine with metal ions remains unknown. Here, the binding constants of PEG‐substituted terpyridine in relation to other literature reports are studied and a few examples of supramolecular materials from our laboratory are summarized. Terpyridine‐complex containing homopolymers (left) and block copolymers (right) behaved as rigid‐rod‐like molecules due to the increase in persistence length generated by the metal complex. This leads to interesting self‐assembling including hierarchical length scales in the block copolymer.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><pmid>21590971</pmid><doi>10.1002/marc.200900869</doi><tpages>10</tpages></addata></record>
fulltext fulltext
identifier ISSN: 1022-1336
ispartof Macromolecular rapid communications., 2010-05, Vol.31 (9-10), p.784-793
issn 1022-1336
1521-3927
language eng
recordid cdi_proquest_miscellaneous_867726433
source Wiley Online Library Journals Frontfile Complete
subjects Access control
amphiphile
Architecture
ATRP
Binding
binding constant
Constants
Materials selection
Metal ions
polymer
Polymers
Self assembly
supramolecular
terpyridine
title Metal-Ligand-Containing Polymers: Terpyridine as the Supramolecular Unit
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-16T23%3A57%3A56IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Metal-Ligand-Containing%20Polymers:%20Terpyridine%20as%20the%20Supramolecular%20Unit&rft.jtitle=Macromolecular%20rapid%20communications.&rft.au=Shunmugam,%20Raja&rft.date=2010-05-12&rft.volume=31&rft.issue=9-10&rft.spage=784&rft.epage=793&rft.pages=784-793&rft.issn=1022-1336&rft.eissn=1521-3927&rft_id=info:doi/10.1002/marc.200900869&rft_dat=%3Cproquest_cross%3E867726433%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=787100126&rft_id=info:pmid/21590971&rfr_iscdi=true