Pressure-induced isostructural phase transition and correlation of FeAs coordination with the superconducting properties of 111-type Na(1-x)FeAs

The effect of pressure on the crystalline structure and superconducting transition temperature (T(c)) of the 111-type Na(1-x)FeAs system using in situ high-pressure synchrotron X-ray powder diffraction and diamond anvil cell techniques is studied. A pressure-induced tetragonal to tetragonal isostruc...

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Veröffentlicht in:Journal of the American Chemical Society 2011-05, Vol.133 (20), p.7892-7896
Hauptverfasser: Liu, Qingqing, Yu, Xiaohui, Wang, Xiancheng, Deng, Zheng, Lv, Yuxi, Zhu, Jinlong, Zhang, Sijia, Liu, Haozhe, Yang, Wenge, Wang, Lin, Mao, Hokwang, Shen, Guoyin, Lu, Zhong-Yi, Ren, Yang, Chen, Zhiqiang, Lin, Zhijun, Zhao, Yusheng, Jin, Changqing
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container_issue 20
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container_title Journal of the American Chemical Society
container_volume 133
creator Liu, Qingqing
Yu, Xiaohui
Wang, Xiancheng
Deng, Zheng
Lv, Yuxi
Zhu, Jinlong
Zhang, Sijia
Liu, Haozhe
Yang, Wenge
Wang, Lin
Mao, Hokwang
Shen, Guoyin
Lu, Zhong-Yi
Ren, Yang
Chen, Zhiqiang
Lin, Zhijun
Zhao, Yusheng
Jin, Changqing
description The effect of pressure on the crystalline structure and superconducting transition temperature (T(c)) of the 111-type Na(1-x)FeAs system using in situ high-pressure synchrotron X-ray powder diffraction and diamond anvil cell techniques is studied. A pressure-induced tetragonal to tetragonal isostructural phase transition was found. The systematic evolution of the FeAs(4) tetrahedron as a function of pressure based on Rietveld refinements on the powder X-ray diffraction patterns was obtained. The nonmonotonic T(c)(P) behavior of Na(1-x)FeAs is found to correlate with the anomalies of the distance between the anion (As) and the iron layer as well as the bond angle of As-Fe-As for the two tetragonal phases. This behavior provides the key structural information in understanding the origin of the pressure dependence of T(c) for 111-type iron pnictide superconductors. A pressure-induced structural phase transition is also observed at 20 GPa.
doi_str_mv 10.1021/ja2009949
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