Poly(2-oxazoline)s as Smart Bioinspired Polymers
Poly(2‐alkyl‐2‐oxazoline)s can be regarded as pseudo‐peptides or bioinspired polymers, which are available through living/controlled cationic polymerization and polymer (“click”) modification procedures. Materials and solution properties may be adjusted via the nature of the side chain (hydrophilic‐...
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Veröffentlicht in: | Macromolecular rapid communications. 2010-03, Vol.31 (6), p.511-525 |
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creator | Schlaad, Helmut Diehl, Christina Gress, Anja Meyer, Matthias Demirel, A. Levent Nur, Yusuf Bertin, Annabelle |
description | Poly(2‐alkyl‐2‐oxazoline)s can be regarded as pseudo‐peptides or bioinspired polymers, which are available through living/controlled cationic polymerization and polymer (“click”) modification procedures. Materials and solution properties may be adjusted via the nature of the side chain (hydrophilic‐hydrophobic, chiral, bio‐functional, etc.), opening the way to stimulus‐responsive materials and complex colloidal structures in aqueous environments. Herein, we give an overview over the macromolecular engineering of polyoxazolines, including the synthesis of biohybrids, and the “smart”/bioinspired aggregation behavior in solution.
Synthetic poly(2‐oxazoline)s are considered as pseudo‐peptides exhibiting interesting materials and solution properties including stimuli‐sensitivity and complex/hierarchical self‐assembly. The advanced macromolecular engineering of polyoxazolines, including the synthesis of biohybrids, and the “smart”/bioinspired aggregation behavior in solution are discussed. |
doi_str_mv | 10.1002/marc.200900683 |
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Synthetic poly(2‐oxazoline)s are considered as pseudo‐peptides exhibiting interesting materials and solution properties including stimuli‐sensitivity and complex/hierarchical self‐assembly. The advanced macromolecular engineering of polyoxazolines, including the synthesis of biohybrids, and the “smart”/bioinspired aggregation behavior in solution are discussed.</description><identifier>ISSN: 1022-1336</identifier><identifier>EISSN: 1521-3927</identifier><identifier>DOI: 10.1002/marc.200900683</identifier><identifier>PMID: 21590935</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Adjustment ; Agglomeration ; Applied sciences ; Aqueous environments ; biohybrids ; Cationic polymerization ; Chains (polymeric) ; Exact sciences and technology ; macromolecular engineering ; Organic polymers ; Physicochemistry of polymers ; Polymerization ; Polymers ; polyoxazoline ; Polyoxazolines ; Preparation, kinetics, thermodynamics, mechanism and catalysts ; self-assembly ; stimuli-sensitive polymers ; Synthesis</subject><ispartof>Macromolecular rapid communications., 2010-03, Vol.31 (6), p.511-525</ispartof><rights>Copyright © 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2015 INIST-CNRS</rights><rights>Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4443-caa0f8768b305abc63fdd042390a80e396747c6d27223b4218bb60d15da4c2b33</citedby><cites>FETCH-LOGICAL-c4443-caa0f8768b305abc63fdd042390a80e396747c6d27223b4218bb60d15da4c2b33</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fmarc.200900683$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fmarc.200900683$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=22530131$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/21590935$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Schlaad, Helmut</creatorcontrib><creatorcontrib>Diehl, Christina</creatorcontrib><creatorcontrib>Gress, Anja</creatorcontrib><creatorcontrib>Meyer, Matthias</creatorcontrib><creatorcontrib>Demirel, A. Levent</creatorcontrib><creatorcontrib>Nur, Yusuf</creatorcontrib><creatorcontrib>Bertin, Annabelle</creatorcontrib><title>Poly(2-oxazoline)s as Smart Bioinspired Polymers</title><title>Macromolecular rapid communications.</title><addtitle>Macromol. Rapid Commun</addtitle><description>Poly(2‐alkyl‐2‐oxazoline)s can be regarded as pseudo‐peptides or bioinspired polymers, which are available through living/controlled cationic polymerization and polymer (“click”) modification procedures. Materials and solution properties may be adjusted via the nature of the side chain (hydrophilic‐hydrophobic, chiral, bio‐functional, etc.), opening the way to stimulus‐responsive materials and complex colloidal structures in aqueous environments. Herein, we give an overview over the macromolecular engineering of polyoxazolines, including the synthesis of biohybrids, and the “smart”/bioinspired aggregation behavior in solution.
Synthetic poly(2‐oxazoline)s are considered as pseudo‐peptides exhibiting interesting materials and solution properties including stimuli‐sensitivity and complex/hierarchical self‐assembly. The advanced macromolecular engineering of polyoxazolines, including the synthesis of biohybrids, and the “smart”/bioinspired aggregation behavior in solution are discussed.</description><subject>Adjustment</subject><subject>Agglomeration</subject><subject>Applied sciences</subject><subject>Aqueous environments</subject><subject>biohybrids</subject><subject>Cationic polymerization</subject><subject>Chains (polymeric)</subject><subject>Exact sciences and technology</subject><subject>macromolecular engineering</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polymerization</subject><subject>Polymers</subject><subject>polyoxazoline</subject><subject>Polyoxazolines</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>self-assembly</subject><subject>stimuli-sensitive polymers</subject><subject>Synthesis</subject><issn>1022-1336</issn><issn>1521-3927</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNqFkE1PGzEQhi1U1FDg2mOVS9Vy2DCe8drrI43aBJUv8SGOltfrlQybbLATlfTXs1HSlFtOnsPzvuN5GPvMYcAB8HRioxsggAaQBe2xA54jz0ij-tDNgJhxItljn1J6AoBCAH5kPeS5Bk35AYObtll-x6x9tX_bJkz9Serb1L_reuf9H6EN0zQL0Vf9FTfxMR2x_do2yR9v3kP28Ovn_XCcXVyPzodnF5kTQlDmrIW6ULIoCXJbOkl1VYFA0mAL8KSlEsrJChUilQJ5UZYSKp5XVjgsiQ7Zt3XvLLYvC5_mZhKS801jp75dJFNIpbhGLXaSqlCdCMGxIwdr0sU2pehrM4uhu3RpOJiVTrPSabY6u8CXTfWinPhqi__z1wFfN4BNzjZ1tFMX0n8OcwJOvOP0mvsTGr_csdZcnt0O338iW2dDmvvXbdbGZyMVqdw8Xo3MI_89vr2_UQbpDYRMmvQ</recordid><startdate>20100316</startdate><enddate>20100316</enddate><creator>Schlaad, Helmut</creator><creator>Diehl, Christina</creator><creator>Gress, Anja</creator><creator>Meyer, Matthias</creator><creator>Demirel, A. Levent</creator><creator>Nur, Yusuf</creator><creator>Bertin, Annabelle</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8FD</scope><scope>FR3</scope><scope>JG9</scope><scope>KR7</scope><scope>L7M</scope><scope>7X8</scope></search><sort><creationdate>20100316</creationdate><title>Poly(2-oxazoline)s as Smart Bioinspired Polymers</title><author>Schlaad, Helmut ; Diehl, Christina ; Gress, Anja ; Meyer, Matthias ; Demirel, A. Levent ; Nur, Yusuf ; Bertin, Annabelle</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4443-caa0f8768b305abc63fdd042390a80e396747c6d27223b4218bb60d15da4c2b33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Adjustment</topic><topic>Agglomeration</topic><topic>Applied sciences</topic><topic>Aqueous environments</topic><topic>biohybrids</topic><topic>Cationic polymerization</topic><topic>Chains (polymeric)</topic><topic>Exact sciences and technology</topic><topic>macromolecular engineering</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Polymerization</topic><topic>Polymers</topic><topic>polyoxazoline</topic><topic>Polyoxazolines</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><topic>self-assembly</topic><topic>stimuli-sensitive polymers</topic><topic>Synthesis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Schlaad, Helmut</creatorcontrib><creatorcontrib>Diehl, Christina</creatorcontrib><creatorcontrib>Gress, Anja</creatorcontrib><creatorcontrib>Meyer, Matthias</creatorcontrib><creatorcontrib>Demirel, A. 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Herein, we give an overview over the macromolecular engineering of polyoxazolines, including the synthesis of biohybrids, and the “smart”/bioinspired aggregation behavior in solution.
Synthetic poly(2‐oxazoline)s are considered as pseudo‐peptides exhibiting interesting materials and solution properties including stimuli‐sensitivity and complex/hierarchical self‐assembly. The advanced macromolecular engineering of polyoxazolines, including the synthesis of biohybrids, and the “smart”/bioinspired aggregation behavior in solution are discussed.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><pmid>21590935</pmid><doi>10.1002/marc.200900683</doi><tpages>15</tpages></addata></record> |
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subjects | Adjustment Agglomeration Applied sciences Aqueous environments biohybrids Cationic polymerization Chains (polymeric) Exact sciences and technology macromolecular engineering Organic polymers Physicochemistry of polymers Polymerization Polymers polyoxazoline Polyoxazolines Preparation, kinetics, thermodynamics, mechanism and catalysts self-assembly stimuli-sensitive polymers Synthesis |
title | Poly(2-oxazoline)s as Smart Bioinspired Polymers |
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