Poly(2-oxazoline)s as Smart Bioinspired Polymers

Poly(2‐alkyl‐2‐oxazoline)s can be regarded as pseudo‐peptides or bioinspired polymers, which are available through living/controlled cationic polymerization and polymer (“click”) modification procedures. Materials and solution properties may be adjusted via the nature of the side chain (hydrophilic‐...

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Veröffentlicht in:Macromolecular rapid communications. 2010-03, Vol.31 (6), p.511-525
Hauptverfasser: Schlaad, Helmut, Diehl, Christina, Gress, Anja, Meyer, Matthias, Demirel, A. Levent, Nur, Yusuf, Bertin, Annabelle
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container_end_page 525
container_issue 6
container_start_page 511
container_title Macromolecular rapid communications.
container_volume 31
creator Schlaad, Helmut
Diehl, Christina
Gress, Anja
Meyer, Matthias
Demirel, A. Levent
Nur, Yusuf
Bertin, Annabelle
description Poly(2‐alkyl‐2‐oxazoline)s can be regarded as pseudo‐peptides or bioinspired polymers, which are available through living/controlled cationic polymerization and polymer (“click”) modification procedures. Materials and solution properties may be adjusted via the nature of the side chain (hydrophilic‐hydrophobic, chiral, bio‐functional, etc.), opening the way to stimulus‐responsive materials and complex colloidal structures in aqueous environments. Herein, we give an overview over the macromolecular engineering of polyoxazolines, including the synthesis of biohybrids, and the “smart”/bioinspired aggregation behavior in solution. Synthetic poly(2‐oxazoline)s are considered as pseudo‐peptides exhibiting interesting materials and solution properties including stimuli‐sensitivity and complex/hierarchical self‐assembly. The advanced macromolecular engineering of polyoxazolines, including the synthesis of biohybrids, and the “smart”/bioinspired aggregation behavior in solution are discussed.
doi_str_mv 10.1002/marc.200900683
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Synthetic poly(2‐oxazoline)s are considered as pseudo‐peptides exhibiting interesting materials and solution properties including stimuli‐sensitivity and complex/hierarchical self‐assembly. 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source Wiley Online Library Journals Frontfile Complete
subjects Adjustment
Agglomeration
Applied sciences
Aqueous environments
biohybrids
Cationic polymerization
Chains (polymeric)
Exact sciences and technology
macromolecular engineering
Organic polymers
Physicochemistry of polymers
Polymerization
Polymers
polyoxazoline
Polyoxazolines
Preparation, kinetics, thermodynamics, mechanism and catalysts
self-assembly
stimuli-sensitive polymers
Synthesis
title Poly(2-oxazoline)s as Smart Bioinspired Polymers
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