Design and synthesis of new chiral phosphorus-olefin bidentate ligands and their use in the rhodium-catalyzed asymmetric addition of organoboroxines to N-sulfonyl imines

Design and synthesis of new chiral phosphorus-olefin bidentate ligands and their use in the rhodium-catalyzed asymmetric addition of organoboroxines to N-sulfonyl imines

Novel chiral phosphorus-olefin bidentate ligands have been synthesized in a few steps from a readily available enantiopure compound. These ligands have been applied to a rhodium-catalyzed asymmetric addition of organoboroxines to N-sulfonyl aldimines, achieving high yield and enantioselectivity.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2011-06, Vol.47 (21), p.6123-6125
Hauptverfasser: Shintani, Ryo, Narui, Rintaro, Tsutsumi, Yosuke, Hayashi, Sayuri, Hayashi, Tamio
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container_issue 21
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container_title Chemical communications (Cambridge, England)
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creator Shintani, Ryo
Narui, Rintaro
Tsutsumi, Yosuke
Hayashi, Sayuri
Hayashi, Tamio
description Novel chiral phosphorus-olefin bidentate ligands have been synthesized in a few steps from a readily available enantiopure compound. These ligands have been applied to a rhodium-catalyzed asymmetric addition of organoboroxines to N-sulfonyl aldimines, achieving high yield and enantioselectivity.
doi_str_mv 10.1039/c1cc11823d
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
title Design and synthesis of new chiral phosphorus-olefin bidentate ligands and their use in the rhodium-catalyzed asymmetric addition of organoboroxines to N-sulfonyl imines
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