General and Selective Palladium-Catalyzed Oxidative Esterification of Alcohols

General and Selective Palladium-Catalyzed Oxidative Esterification of Alcohols

Selectively esterified: Primary alcohols react with dioxygen as a benign oxidant in a palladium‐catalyzed oxidative esterification (see scheme). The corresponding aldehydes and esters are formed highly selectively depending on the catalyst system. The reactions take place in the presence of commerci...

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Veröffentlicht in:Angewandte Chemie International Edition 2011-05, Vol.50 (22), p.5139-5143
Hauptverfasser: Gowrisankar, Saravanan, Neumann, Helfried, Beller, Matthias
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Sprache:eng
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alcohols
aldehydes
esters
oxidative esterification
Palladium
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container_title Angewandte Chemie International Edition
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creator Gowrisankar, Saravanan
Neumann, Helfried
Beller, Matthias
description Selectively esterified: Primary alcohols react with dioxygen as a benign oxidant in a palladium‐catalyzed oxidative esterification (see scheme). The corresponding aldehydes and esters are formed highly selectively depending on the catalyst system. The reactions take place in the presence of commercially available ligands without the need for additional organic hydrogen acceptors.
doi_str_mv 10.1002/anie.201008035
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source Wiley Online Library Journals Frontfile Complete
subjects alcohols
aldehydes
esters
oxidative esterification
Palladium
title General and Selective Palladium-Catalyzed Oxidative Esterification of Alcohols
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