Mapping the Sequential Self-Assembly of Heterometallic Clusters: From a Helix to a Grid

Two iron/cobalt mixed‐valence clusters were synthesized using multidentate polypyridyl ligands (see picture: FeII orange, FeIII yellow, CoII blue, O red). A heptanuclear helix and a [3×3] grid complex form depending on the metal ion stoichiometry. ESI‐MS measurements suggest that the helical cluster...

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Veröffentlicht in:Angewandte Chemie International Edition 2011-05, Vol.50 (21), p.4844-4848
Hauptverfasser: Newton, Graham N., Onuki, Tatsuya, Shiga, Takuya, Noguchi, Mao, Matsumoto, Takuto, Mathieson, Jennifer S., Nihei, Masayuki, Nakano, Motohiro, Cronin, Leroy, Oshio, Hiroki
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container_issue 21
container_start_page 4844
container_title Angewandte Chemie International Edition
container_volume 50
creator Newton, Graham N.
Onuki, Tatsuya
Shiga, Takuya
Noguchi, Mao
Matsumoto, Takuto
Mathieson, Jennifer S.
Nihei, Masayuki
Nakano, Motohiro
Cronin, Leroy
Oshio, Hiroki
description Two iron/cobalt mixed‐valence clusters were synthesized using multidentate polypyridyl ligands (see picture: FeII orange, FeIII yellow, CoII blue, O red). A heptanuclear helix and a [3×3] grid complex form depending on the metal ion stoichiometry. ESI‐MS measurements suggest that the helical cluster is an intermediate to the grid complex.
doi_str_mv 10.1002/anie.201007388
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subjects cobalt
iron
mass spectrometry
self-assembly
spin states
title Mapping the Sequential Self-Assembly of Heterometallic Clusters: From a Helix to a Grid
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