Helix-Sense-Selective Polymerization of Achiral Substituted Acetylenes in Chiral Micelles
Hold that shape: An achiral acetylene underwent helix‐sense‐selective polymerization in chiral micelles consisting of [{(nbd)RhCl}2] (nbd=2,5‐norbornadiene) and dodecylphenylalanine as a chiral emulsifier to produce optically active helical polymers and polymeric emulsions.
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| Veröffentlicht in: | Angewandte Chemie International Edition 2011-05, Vol.50 (21), p.4909-4912 |
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| container_issue | 21 |
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| container_title | Angewandte Chemie International Edition |
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| creator | Luo, Xiaofeng Deng, Jianping Yang, Wantai |
| description | Hold that shape: An achiral acetylene underwent helix‐sense‐selective polymerization in chiral micelles consisting of [{(nbd)RhCl}2] (nbd=2,5‐norbornadiene) and dodecylphenylalanine as a chiral emulsifier to produce optically active helical polymers and polymeric emulsions. |
| doi_str_mv | 10.1002/anie.201006658 |
| format | Article |
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| subjects | chirality helical structures micelles polymerization |
| title | Helix-Sense-Selective Polymerization of Achiral Substituted Acetylenes in Chiral Micelles |
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