Ferrocene-Based Trimethylsilyl Chalcogenide Reagents for the Assembly of Functionalized Metal-Chalcogen Architectures
The ferrocene‐based trimethylsilyl chalcogenide reagents [FcC(O)OCH2CH2ESiMe3] (2, E=S, 3 E=Se, Fc=[Fe(η5‐C5H5)(η5‐C5H4)]) and [FcC(O)NHCH2CH2SSiMe3] (8b) have been synthesized. The reagents were reacted with solubilized transition‐metal acetates to yield functionalized complexes and clusters, inclu...
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| Veröffentlicht in: | Chemistry : a European journal 2011-05, Vol.17 (21), p.5890-5902 |
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| creator | MacDonald, Daniel G. Eichhöfer, Andreas Campana, Charles F. Corrigan, John F. |
| description | The ferrocene‐based trimethylsilyl chalcogenide reagents [FcC(O)OCH2CH2ESiMe3] (2, E=S, 3 E=Se, Fc=[Fe(η5‐C5H5)(η5‐C5H4)]) and [FcC(O)NHCH2CH2SSiMe3] (8b) have been synthesized. The reagents were reacted with solubilized transition‐metal acetates to yield functionalized complexes and clusters, including the spherical nanocluster [Ag14S{SCH2CH2O(O)CFc)}12(PPh3)6] (11, PPh3=triphenylphosphine). The complexes were characterized by NMR spectroscopy and X‐ray crystallography. The electrochemical behavior of the complexes was explored by cyclic voltammetry and each displayed a single quasi‐reversible redox wave with some adsorption to the electrode surface.
The more, the merrier: New ferrocene‐based trimethylsilyl chalcogenide reagents have been prepared and used for the assembly of polyferrocenyl metal–chalcogen complexes and cluster frameworks, including the spherical nanocluster [Ag14S{SCH2CH2O(O)CFc}12(PPh3)6] (Fc=[Fe(η5‐C5H5)(η5‐C5H4)], PPh3=triphenylphosphine, see graphic). |
| doi_str_mv | 10.1002/chem.201003756 |
| format | Article |
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The more, the merrier: New ferrocene‐based trimethylsilyl chalcogenide reagents have been prepared and used for the assembly of polyferrocenyl metal–chalcogen complexes and cluster frameworks, including the spherical nanocluster [Ag14S{SCH2CH2O(O)CFc}12(PPh3)6] (Fc=[Fe(η5‐C5H5)(η5‐C5H4)], PPh3=triphenylphosphine, see graphic).</description><identifier>ISSN: 0947-6539</identifier><identifier>EISSN: 1521-3765</identifier><identifier>DOI: 10.1002/chem.201003756</identifier><identifier>PMID: 21506183</identifier><identifier>CODEN: CEUJED</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Assembly ; Chalcogenides ; chalcogens ; Chemistry ; cluster compounds ; Clusters ; cyclic voltammetry ; Electrodes ; ferrocene ; multiple ferrocenyl assembly ; NMR spectroscopy ; Surface chemistry ; Voltammetry ; X-rays</subject><ispartof>Chemistry : a European journal, 2011-05, Vol.17 (21), p.5890-5902</ispartof><rights>Copyright © 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><rights>Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4436-72257adc57833075e7604cd1fca7ded2494e35eff50b15018bfb9a28637255603</citedby><cites>FETCH-LOGICAL-c4436-72257adc57833075e7604cd1fca7ded2494e35eff50b15018bfb9a28637255603</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fchem.201003756$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fchem.201003756$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27903,27904,45553,45554</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/21506183$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>MacDonald, Daniel G.</creatorcontrib><creatorcontrib>Eichhöfer, Andreas</creatorcontrib><creatorcontrib>Campana, Charles F.</creatorcontrib><creatorcontrib>Corrigan, John F.</creatorcontrib><title>Ferrocene-Based Trimethylsilyl Chalcogenide Reagents for the Assembly of Functionalized Metal-Chalcogen Architectures</title><title>Chemistry : a European journal</title><addtitle>Chem. Eur. J</addtitle><description>The ferrocene‐based trimethylsilyl chalcogenide reagents [FcC(O)OCH2CH2ESiMe3] (2, E=S, 3 E=Se, Fc=[Fe(η5‐C5H5)(η5‐C5H4)]) and [FcC(O)NHCH2CH2SSiMe3] (8b) have been synthesized. The reagents were reacted with solubilized transition‐metal acetates to yield functionalized complexes and clusters, including the spherical nanocluster [Ag14S{SCH2CH2O(O)CFc)}12(PPh3)6] (11, PPh3=triphenylphosphine). The complexes were characterized by NMR spectroscopy and X‐ray crystallography. The electrochemical behavior of the complexes was explored by cyclic voltammetry and each displayed a single quasi‐reversible redox wave with some adsorption to the electrode surface.
The more, the merrier: New ferrocene‐based trimethylsilyl chalcogenide reagents have been prepared and used for the assembly of polyferrocenyl metal–chalcogen complexes and cluster frameworks, including the spherical nanocluster [Ag14S{SCH2CH2O(O)CFc}12(PPh3)6] (Fc=[Fe(η5‐C5H5)(η5‐C5H4)], PPh3=triphenylphosphine, see graphic).</description><subject>Assembly</subject><subject>Chalcogenides</subject><subject>chalcogens</subject><subject>Chemistry</subject><subject>cluster compounds</subject><subject>Clusters</subject><subject>cyclic voltammetry</subject><subject>Electrodes</subject><subject>ferrocene</subject><subject>multiple ferrocenyl assembly</subject><subject>NMR spectroscopy</subject><subject>Surface chemistry</subject><subject>Voltammetry</subject><subject>X-rays</subject><issn>0947-6539</issn><issn>1521-3765</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNqFkU1v1DAQhi0EokvhyhFF4lAu2fojtpPjsu3uIlqQUIGj5TgTkuLExU7Uhl-Pw7YrxAFOM4fnfaSZF6GXBC8JxvTUNNAtKY47k1w8QgvCKUmZFPwxWuAik6ngrDhCz0K4xhgXgrGn6IgSjgXJ2QKNG_DeGeghfasDVMmVbzsYmsmG1k42WTfaGvcN-raC5BPouA0hqZ1PhgaSVQjQlXZKXJ1sxt4Mreu1bX9GzyUM2qaHeLLypmkHMMPoITxHT2ptA7y4n8fo8-b8ar1LLz5u361XF6nJMiZSSSmXujJc5oxhyUEKnJmK1EbLCiqaFRkwDnXNcRkvInlZl4WmuWCSci4wO0Yne--Ndz9GCIPq2mDAWt2DG4PKRRRywvNIvvknSaTMMSl4MaOv_0Kv3ejj3TMlZiP-TS33lPEuBA-1uomf1X5SBKu5OjVXpw7VxcCre-1YdlAd8IeuIlDsgdvWwvQfnVrvzi__lKf7bBsGuDtktf-uhIyE-vphq3bbs83ufZapL-wXA3q0aw</recordid><startdate>20110516</startdate><enddate>20110516</enddate><creator>MacDonald, Daniel G.</creator><creator>Eichhöfer, Andreas</creator><creator>Campana, Charles F.</creator><creator>Corrigan, John F.</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>K9.</scope><scope>7X8</scope></search><sort><creationdate>20110516</creationdate><title>Ferrocene-Based Trimethylsilyl Chalcogenide Reagents for the Assembly of Functionalized Metal-Chalcogen Architectures</title><author>MacDonald, Daniel G. ; Eichhöfer, Andreas ; Campana, Charles F. ; Corrigan, John F.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4436-72257adc57833075e7604cd1fca7ded2494e35eff50b15018bfb9a28637255603</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Assembly</topic><topic>Chalcogenides</topic><topic>chalcogens</topic><topic>Chemistry</topic><topic>cluster compounds</topic><topic>Clusters</topic><topic>cyclic voltammetry</topic><topic>Electrodes</topic><topic>ferrocene</topic><topic>multiple ferrocenyl assembly</topic><topic>NMR spectroscopy</topic><topic>Surface chemistry</topic><topic>Voltammetry</topic><topic>X-rays</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>MacDonald, Daniel G.</creatorcontrib><creatorcontrib>Eichhöfer, Andreas</creatorcontrib><creatorcontrib>Campana, Charles F.</creatorcontrib><creatorcontrib>Corrigan, John F.</creatorcontrib><collection>Istex</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>Chemistry : a European journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>MacDonald, Daniel G.</au><au>Eichhöfer, Andreas</au><au>Campana, Charles F.</au><au>Corrigan, John F.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ferrocene-Based Trimethylsilyl Chalcogenide Reagents for the Assembly of Functionalized Metal-Chalcogen Architectures</atitle><jtitle>Chemistry : a European journal</jtitle><addtitle>Chem. Eur. J</addtitle><date>2011-05-16</date><risdate>2011</risdate><volume>17</volume><issue>21</issue><spage>5890</spage><epage>5902</epage><pages>5890-5902</pages><issn>0947-6539</issn><eissn>1521-3765</eissn><coden>CEUJED</coden><abstract>The ferrocene‐based trimethylsilyl chalcogenide reagents [FcC(O)OCH2CH2ESiMe3] (2, E=S, 3 E=Se, Fc=[Fe(η5‐C5H5)(η5‐C5H4)]) and [FcC(O)NHCH2CH2SSiMe3] (8b) have been synthesized. The reagents were reacted with solubilized transition‐metal acetates to yield functionalized complexes and clusters, including the spherical nanocluster [Ag14S{SCH2CH2O(O)CFc)}12(PPh3)6] (11, PPh3=triphenylphosphine). The complexes were characterized by NMR spectroscopy and X‐ray crystallography. The electrochemical behavior of the complexes was explored by cyclic voltammetry and each displayed a single quasi‐reversible redox wave with some adsorption to the electrode surface.
The more, the merrier: New ferrocene‐based trimethylsilyl chalcogenide reagents have been prepared and used for the assembly of polyferrocenyl metal–chalcogen complexes and cluster frameworks, including the spherical nanocluster [Ag14S{SCH2CH2O(O)CFc}12(PPh3)6] (Fc=[Fe(η5‐C5H5)(η5‐C5H4)], PPh3=triphenylphosphine, see graphic).</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><pmid>21506183</pmid><doi>10.1002/chem.201003756</doi><tpages>13</tpages></addata></record> |
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| subjects | Assembly Chalcogenides chalcogens Chemistry cluster compounds Clusters cyclic voltammetry Electrodes ferrocene multiple ferrocenyl assembly NMR spectroscopy Surface chemistry Voltammetry X-rays |
| title | Ferrocene-Based Trimethylsilyl Chalcogenide Reagents for the Assembly of Functionalized Metal-Chalcogen Architectures |
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