A Versatile Fréchet-Dendron Compound Unifies Host-Guest and Templated Heterogeneous Self-Assembly

To date, heterogeneous patterns on surfaces could assemble either in host‐guest or templated structures only. A Fréchet‐type dendron now shows both classes of ordering and thus connects both assembly types. Depending on the type of interaction with the guest molecule, saturated adamantane is include...

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Veröffentlicht in:Advanced materials (Weinheim) 2011-05, Vol.23 (19), p.2195-2198
Hauptverfasser: Gruber, Kathrin, Rohr, Carsten, Scherer, Lukas J., Malarek, Michael S., Constable, Edwin C., Hermann, Bianca A.
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container_end_page 2198
container_issue 19
container_start_page 2195
container_title Advanced materials (Weinheim)
container_volume 23
creator Gruber, Kathrin
Rohr, Carsten
Scherer, Lukas J.
Malarek, Michael S.
Constable, Edwin C.
Hermann, Bianca A.
description To date, heterogeneous patterns on surfaces could assemble either in host‐guest or templated structures only. A Fréchet‐type dendron now shows both classes of ordering and thus connects both assembly types. Depending on the type of interaction with the guest molecule, saturated adamantane is included in an existing host structure, while aromatic coronene templates a new molecular ordering.
doi_str_mv 10.1002/adma.201100013
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subjects Adamantane - chemistry
Adsorption
Anthracenes - chemistry
Benzoates - chemistry
Graphite - chemistry
heterogeneous molecular monolayers
host-guest assembly
Microscopy, Scanning Tunneling
Polycyclic Compounds - chemistry
supramolecular chemistry
templated patterns
title A Versatile Fréchet-Dendron Compound Unifies Host-Guest and Templated Heterogeneous Self-Assembly
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