Fast Gas Chromatographic Separation of Biodiesel
A high-speed gas chromatographic method has been developed to determine the FAME distribution of B100 biodiesel. The capillary column used in this work has dimensions of 20 m × 0.100 mm and is coated with a polyethylene glycol film. Analysis times are typically on the order of 4-5 min depending upon...
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| Veröffentlicht in: | J. Chromatogr. Sci 2011-05, Vol.49 (5), p.370-374 |
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| container_title | J. Chromatogr. Sci |
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| creator | Pauls, R. E. |
| description | A high-speed gas chromatographic method has been developed to determine the FAME distribution of B100 biodiesel. The capillary column used in this work has dimensions of 20 m × 0.100 mm and is coated with a polyethylene glycol film. Analysis times are typically on the order of 4-5 min depending upon the composition of the B100. The application of this method to a variety of vegetable and animal derived B100 is demonstrated. Quantitative results obtained with this method were in close agreement with those obtained by a more conventional approach on a 100 m column. The method, coupled with solid-phase extraction, was also found suitable to determine the B100 content of biodiesel-diesel blends. |
| doi_str_mv | 10.1093/chromsci/49.5.370 |
| format | Article |
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E.</creator><creatorcontrib>Pauls, R. E. ; Argonne National Lab. (ANL), Argonne, IL (United States)</creatorcontrib><description>A high-speed gas chromatographic method has been developed to determine the FAME distribution of B100 biodiesel. The capillary column used in this work has dimensions of 20 m × 0.100 mm and is coated with a polyethylene glycol film. Analysis times are typically on the order of 4-5 min depending upon the composition of the B100. The application of this method to a variety of vegetable and animal derived B100 is demonstrated. Quantitative results obtained with this method were in close agreement with those obtained by a more conventional approach on a 100 m column. The method, coupled with solid-phase extraction, was also found suitable to determine the B100 content of biodiesel-diesel blends.</description><identifier>ISSN: 0021-9665</identifier><identifier>EISSN: 1945-239X</identifier><identifier>DOI: 10.1093/chromsci/49.5.370</identifier><identifier>PMID: 21549028</identifier><identifier>CODEN: JCHSBZ</identifier><language>eng</language><publisher>Niles, IL: Oxford University Press</publisher><subject>ADVANCED PROPULSION SYSTEMS ; Analytical chemistry ; ANIMALS ; Applied sciences ; Biofuel production ; BIOFUELS ; Biofuels - analysis ; Biological and medical sciences ; Biotechnology ; Chemistry ; Chromatographic methods and physical methods associated with chromatography ; Chromatography, Gas - methods ; Crude oil, natural gas and petroleum products ; DIESEL FUELS ; DIMENSIONS ; DISTRIBUTION ; Energy ; Exact sciences and technology ; Fatty Acids - analysis ; Fatty Acids - isolation & purification ; Fuels ; Fundamental and applied biological sciences. Psychology ; Gas chromatographic methods ; Industrial applications and implications. Economical aspects ; POLYETHYLENE GLYCOLS ; Prospecting and production of crude oil, natural gas, oil shales and tar sands ; Reproducibility of Results ; Solid Phase Extraction ; VEGETABLES</subject><ispartof>J. Chromatogr. 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E.</creatorcontrib><creatorcontrib>Argonne National Lab. (ANL), Argonne, IL (United States)</creatorcontrib><title>Fast Gas Chromatographic Separation of Biodiesel</title><title>J. Chromatogr. Sci</title><addtitle>Journal of Chromatographic Science</addtitle><addtitle>J Chromatogr Sci</addtitle><description>A high-speed gas chromatographic method has been developed to determine the FAME distribution of B100 biodiesel. The capillary column used in this work has dimensions of 20 m × 0.100 mm and is coated with a polyethylene glycol film. Analysis times are typically on the order of 4-5 min depending upon the composition of the B100. The application of this method to a variety of vegetable and animal derived B100 is demonstrated. Quantitative results obtained with this method were in close agreement with those obtained by a more conventional approach on a 100 m column. The method, coupled with solid-phase extraction, was also found suitable to determine the B100 content of biodiesel-diesel blends.</description><subject>ADVANCED PROPULSION SYSTEMS</subject><subject>Analytical chemistry</subject><subject>ANIMALS</subject><subject>Applied sciences</subject><subject>Biofuel production</subject><subject>BIOFUELS</subject><subject>Biofuels - analysis</subject><subject>Biological and medical sciences</subject><subject>Biotechnology</subject><subject>Chemistry</subject><subject>Chromatographic methods and physical methods associated with chromatography</subject><subject>Chromatography, Gas - methods</subject><subject>Crude oil, natural gas and petroleum products</subject><subject>DIESEL FUELS</subject><subject>DIMENSIONS</subject><subject>DISTRIBUTION</subject><subject>Energy</subject><subject>Exact sciences and technology</subject><subject>Fatty Acids - analysis</subject><subject>Fatty Acids - isolation & purification</subject><subject>Fuels</subject><subject>Fundamental and applied biological sciences. Psychology</subject><subject>Gas chromatographic methods</subject><subject>Industrial applications and implications. Economical aspects</subject><subject>POLYETHYLENE GLYCOLS</subject><subject>Prospecting and production of crude oil, natural gas, oil shales and tar sands</subject><subject>Reproducibility of Results</subject><subject>Solid Phase Extraction</subject><subject>VEGETABLES</subject><issn>0021-9665</issn><issn>1945-239X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqNkMFLwzAYxYMobk7_AC9SBPFityRN0uaow01h4EEFbyH9mrpI19SkPfjfm7GpV08fH_zee7yH0DnBU4JlNoO1d5sAdsbklE-zHB-gMZGMpzSTb4dojDElqRSCj9BJCB_blxT8GI0o4UxiWowRXujQJ0sdkvnWTPfu3etubSF5Np32ureuTVyd3FlXWRNMc4qOat0Ec7a_E_S6uH-ZP6Srp-Xj_HaVAsvyPi1ZTiWvSF1q4AIoaAK00JjK2gCO8UKWkJOCESJLmYkaqjyCFS4ky42Q2QRd7nxd6K2KJXsDa3Bta6BXBFMsOInQ9Q7qvPscTOjVxgYwTaNb44agCsGFZEVOI0l2JHgXgje16rzdaP8VvdR2TPUzpmJScRXHjJqLvftQbkz1q_hZLwJXe0AH0E3tdQs2_HGM0EywbZebfZeh-0fuN9R5i_E</recordid><startdate>20110501</startdate><enddate>20110501</enddate><creator>Pauls, R. E.</creator><general>Oxford University Press</general><general>Preston Publications</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>OTOTI</scope></search><sort><creationdate>20110501</creationdate><title>Fast Gas Chromatographic Separation of Biodiesel</title><author>Pauls, R. E.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c437t-b47295d1fbac56c2ca1c28a029fec015469bc7184119b936fcd7c56d08947e693</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>ADVANCED PROPULSION SYSTEMS</topic><topic>Analytical chemistry</topic><topic>ANIMALS</topic><topic>Applied sciences</topic><topic>Biofuel production</topic><topic>BIOFUELS</topic><topic>Biofuels - analysis</topic><topic>Biological and medical sciences</topic><topic>Biotechnology</topic><topic>Chemistry</topic><topic>Chromatographic methods and physical methods associated with chromatography</topic><topic>Chromatography, Gas - methods</topic><topic>Crude oil, natural gas and petroleum products</topic><topic>DIESEL FUELS</topic><topic>DIMENSIONS</topic><topic>DISTRIBUTION</topic><topic>Energy</topic><topic>Exact sciences and technology</topic><topic>Fatty Acids - analysis</topic><topic>Fatty Acids - isolation & purification</topic><topic>Fuels</topic><topic>Fundamental and applied biological sciences. Psychology</topic><topic>Gas chromatographic methods</topic><topic>Industrial applications and implications. Economical aspects</topic><topic>POLYETHYLENE GLYCOLS</topic><topic>Prospecting and production of crude oil, natural gas, oil shales and tar sands</topic><topic>Reproducibility of Results</topic><topic>Solid Phase Extraction</topic><topic>VEGETABLES</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Pauls, R. E.</creatorcontrib><creatorcontrib>Argonne National Lab. (ANL), Argonne, IL (United States)</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>OSTI.GOV</collection><jtitle>J. Chromatogr. Sci</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Pauls, R. E.</au><aucorp>Argonne National Lab. (ANL), Argonne, IL (United States)</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Fast Gas Chromatographic Separation of Biodiesel</atitle><jtitle>J. Chromatogr. Sci</jtitle><stitle>Journal of Chromatographic Science</stitle><addtitle>J Chromatogr Sci</addtitle><date>2011-05-01</date><risdate>2011</risdate><volume>49</volume><issue>5</issue><spage>370</spage><epage>374</epage><pages>370-374</pages><issn>0021-9665</issn><eissn>1945-239X</eissn><coden>JCHSBZ</coden><abstract>A high-speed gas chromatographic method has been developed to determine the FAME distribution of B100 biodiesel. The capillary column used in this work has dimensions of 20 m × 0.100 mm and is coated with a polyethylene glycol film. Analysis times are typically on the order of 4-5 min depending upon the composition of the B100. The application of this method to a variety of vegetable and animal derived B100 is demonstrated. Quantitative results obtained with this method were in close agreement with those obtained by a more conventional approach on a 100 m column. The method, coupled with solid-phase extraction, was also found suitable to determine the B100 content of biodiesel-diesel blends.</abstract><cop>Niles, IL</cop><pub>Oxford University Press</pub><pmid>21549028</pmid><doi>10.1093/chromsci/49.5.370</doi><tpages>5</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
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| ispartof | J. Chromatogr. Sci, 2011-05, Vol.49 (5), p.370-374 |
| issn | 0021-9665 1945-239X |
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| source | MEDLINE; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; Oxford University Press Journals All Titles (1996-Current); Free Full-Text Journals in Chemistry |
| subjects | ADVANCED PROPULSION SYSTEMS Analytical chemistry ANIMALS Applied sciences Biofuel production BIOFUELS Biofuels - analysis Biological and medical sciences Biotechnology Chemistry Chromatographic methods and physical methods associated with chromatography Chromatography, Gas - methods Crude oil, natural gas and petroleum products DIESEL FUELS DIMENSIONS DISTRIBUTION Energy Exact sciences and technology Fatty Acids - analysis Fatty Acids - isolation & purification Fuels Fundamental and applied biological sciences. Psychology Gas chromatographic methods Industrial applications and implications. Economical aspects POLYETHYLENE GLYCOLS Prospecting and production of crude oil, natural gas, oil shales and tar sands Reproducibility of Results Solid Phase Extraction VEGETABLES |
| title | Fast Gas Chromatographic Separation of Biodiesel |
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