Spin Canting and Metamagnetism in the First Hybrid Cobalt-Hypoxanthine Open Framework with umr Topology

Hydrothermal reactions generated a cobalt–hypoxanthine framework [Co3(OH)4(Hpxt)2]⋅2 H2O (H2pxt=6‐hydroxypurine, 1⋅2 H2O), which became a microporous framework [Co3(OH)4(Hpxt)2] (1) through a single‐crystal‐to‐single‐crystal transformation. Compound 1⋅2 H2O shows a three‐dimensional umr topological...

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Veröffentlicht in:	Chemistry : a European journal 2011-05, Vol.17 (20), p.5588-5594
Hauptverfasser:	Zhang, Xu-Hui, Hao, Zheng-Ming, Zhang, Xian-Ming
Format:	Artikel
Sprache:	eng
Schlagworte:	Antiferromagnetism Channels Chemistry cobalt Construction Ferromagnetism Filing hypoxanthine Joining magnetic properties metal-organic frameworks Spirals Three dimensional X-ray diffraction
Online-Zugang:	Volltext
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