Hydrophobic Surface Construction by Phase-Separation of Fluorinated Block Copolymer for Immersion Lithography

Newly designed topcoat-less resist for immersion lithography is described. Hydrophobic resist surface layer was constructed successfully in order to solve problems regarding immersion resist and improve lithographic performance. Fluorinated diblock copolymer synthesized via atom transfer radical pol...

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Veröffentlicht in:Journal of Photopolymer Science and Technology 2008/06/24, Vol.21(5), pp.679-684
Hauptverfasser: Otake, Atsushi, Miura, Masashi, Tsuchiya, Kousuke, Ogino, Kenji
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container_title Journal of Photopolymer Science and Technology
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creator Otake, Atsushi
Miura, Masashi
Tsuchiya, Kousuke
Ogino, Kenji
description Newly designed topcoat-less resist for immersion lithography is described. Hydrophobic resist surface layer was constructed successfully in order to solve problems regarding immersion resist and improve lithographic performance. Fluorinated diblock copolymer synthesized via atom transfer radical polymerization (ATRP) showed self-assembly surface segregation in resist films. In spite of low fluorine composition, hydrophobicity of the resist surface was remarkably enhanced. Newly designed topcoat-less resist is expected to be utilized in immersion lithography.
doi_str_mv 10.2494/photopolymer.21.679
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source J-STAGE (Japan Science & Technology Information Aggregator, Electronic) Freely Available Titles - Japanese; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; Free Full-Text Journals in Chemistry
subjects Block Copolymer
Construction
Copolymers
Fluorination
Hydrophobicity
Immersion
immersion lithography
Lithography
Phase-Separation
Resists
Self assembly
topcoat-less resist
title Hydrophobic Surface Construction by Phase-Separation of Fluorinated Block Copolymer for Immersion Lithography
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