On the dependence of the properties of glasses on cooling and heating rates
The glass transition is theoretically described in terms of a generic non-equilibrium thermodynamics approach employing De Donder's structural order parameter method, appropriate expressions for the relaxation behavior of glass-forming systems and a simplified but qualitative correct model of g...
Gespeichert in:
| Veröffentlicht in: | Journal of non-crystalline solids 2011-02, Vol.357 (4), p.1291-1302 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1302 |
|---|---|
| container_issue | 4 |
| container_start_page | 1291 |
| container_title | Journal of non-crystalline solids |
| container_volume | 357 |
| creator | Tropin, Timur V. Schmelzer, Jürn W.P. Schick, Christoph |
| description | The glass transition is theoretically described in terms of a generic non-equilibrium thermodynamics approach employing De Donder's structural order parameter method, appropriate expressions for the relaxation behavior of glass-forming systems and a simplified but qualitative correct model of glass-forming melts with one order parameter related to the free volume of the system. Employing this approach the behavior of a variety of thermodynamic quantities describing glass-forming systems in vitrification and devitrification processes is interpreted theoretically. The present paper is devoted to the computation of the entropy, the entropy production and the glass transition temperature in dependence on the cooling and heating rates, varying latter parameter in a broad interval. A comparison with experimental results is given and some further consequences and possible extensions are discussed briefly.
► The dependence of vitrification processes on cooling and heating rates is studied. ► Cooling and heating rates are varied hereby in broad intervals. ► The conventional definition of the glass transition temperature is analyzed. ► Limits of validity and an extension of the Bartenev-Ritland equation are discussed. ► The behaviour of the entropy and entropy production in vitrification is investigated. |
| doi_str_mv | 10.1016/j.jnoncrysol.2010.11.111 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_864413091</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S002230931000966X</els_id><sourcerecordid>864413091</sourcerecordid><originalsourceid>FETCH-LOGICAL-c1951-96ceb83fa16c8c8def981eacf4d2503b007ffa039bea44bfeaed9d7d5deac1a73</originalsourceid><addsrcrecordid>eNqFUMtOwzAQtBBIlMI_5MYpxRuniXOEipeo1AucLcdet45SO9gpUv8ehyJxZLXSjkazq50hJAO6AArVXbfonHcqHKPvFwWdaEgNZ2QGvGZ5yaE4JzNKiyJntGGX5CrGjqaqGZ-Rt43Lxh1mGgd0Gp3CzJsfZgh-wDBajBOz7WWME3SZ8r63bptJp7MdynHCQY4Yr8mFkX3Em985Jx9Pj--rl3y9eX5d3a9zBc0S8qZS2HJmJFSKK67RNBxQKlPqYklZmz4zRlLWtCjLsjUoUTe61kudRCBrNie3p7vpxc8DxlHsbVTY99KhP0TBq7KE5BWSkp-UKvgYAxoxBLuX4SiAiik-0Ym_-MQUnwBIPa0-nFYxOfmyGERUdspH24BqFNrb_498AzcNgEo</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>864413091</pqid></control><display><type>article</type><title>On the dependence of the properties of glasses on cooling and heating rates</title><source>Elsevier ScienceDirect Journals</source><creator>Tropin, Timur V. ; Schmelzer, Jürn W.P. ; Schick, Christoph</creator><creatorcontrib>Tropin, Timur V. ; Schmelzer, Jürn W.P. ; Schick, Christoph</creatorcontrib><description>The glass transition is theoretically described in terms of a generic non-equilibrium thermodynamics approach employing De Donder's structural order parameter method, appropriate expressions for the relaxation behavior of glass-forming systems and a simplified but qualitative correct model of glass-forming melts with one order parameter related to the free volume of the system. Employing this approach the behavior of a variety of thermodynamic quantities describing glass-forming systems in vitrification and devitrification processes is interpreted theoretically. The present paper is devoted to the computation of the entropy, the entropy production and the glass transition temperature in dependence on the cooling and heating rates, varying latter parameter in a broad interval. A comparison with experimental results is given and some further consequences and possible extensions are discussed briefly.
► The dependence of vitrification processes on cooling and heating rates is studied. ► Cooling and heating rates are varied hereby in broad intervals. ► The conventional definition of the glass transition temperature is analyzed. ► Limits of validity and an extension of the Bartenev-Ritland equation are discussed. ► The behaviour of the entropy and entropy production in vitrification is investigated.</description><identifier>ISSN: 0022-3093</identifier><identifier>EISSN: 1873-4812</identifier><identifier>DOI: 10.1016/j.jnoncrysol.2010.11.111</identifier><language>eng</language><publisher>Elsevier B.V</publisher><subject>Bartenev-Ritland equation ; Cooling rate ; Entropy ; Entropy and entropy production ; Glass transition temperature ; Heating rate ; Intervals ; Mathematical models ; Order parameters ; Vitrification</subject><ispartof>Journal of non-crystalline solids, 2011-02, Vol.357 (4), p.1291-1302</ispartof><rights>2011 Elsevier B.V.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c1951-96ceb83fa16c8c8def981eacf4d2503b007ffa039bea44bfeaed9d7d5deac1a73</citedby><cites>FETCH-LOGICAL-c1951-96ceb83fa16c8c8def981eacf4d2503b007ffa039bea44bfeaed9d7d5deac1a73</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S002230931000966X$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3536,27903,27904,65309</link.rule.ids></links><search><creatorcontrib>Tropin, Timur V.</creatorcontrib><creatorcontrib>Schmelzer, Jürn W.P.</creatorcontrib><creatorcontrib>Schick, Christoph</creatorcontrib><title>On the dependence of the properties of glasses on cooling and heating rates</title><title>Journal of non-crystalline solids</title><description>The glass transition is theoretically described in terms of a generic non-equilibrium thermodynamics approach employing De Donder's structural order parameter method, appropriate expressions for the relaxation behavior of glass-forming systems and a simplified but qualitative correct model of glass-forming melts with one order parameter related to the free volume of the system. Employing this approach the behavior of a variety of thermodynamic quantities describing glass-forming systems in vitrification and devitrification processes is interpreted theoretically. The present paper is devoted to the computation of the entropy, the entropy production and the glass transition temperature in dependence on the cooling and heating rates, varying latter parameter in a broad interval. A comparison with experimental results is given and some further consequences and possible extensions are discussed briefly.
► The dependence of vitrification processes on cooling and heating rates is studied. ► Cooling and heating rates are varied hereby in broad intervals. ► The conventional definition of the glass transition temperature is analyzed. ► Limits of validity and an extension of the Bartenev-Ritland equation are discussed. ► The behaviour of the entropy and entropy production in vitrification is investigated.</description><subject>Bartenev-Ritland equation</subject><subject>Cooling rate</subject><subject>Entropy</subject><subject>Entropy and entropy production</subject><subject>Glass transition temperature</subject><subject>Heating rate</subject><subject>Intervals</subject><subject>Mathematical models</subject><subject>Order parameters</subject><subject>Vitrification</subject><issn>0022-3093</issn><issn>1873-4812</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNqFUMtOwzAQtBBIlMI_5MYpxRuniXOEipeo1AucLcdet45SO9gpUv8ehyJxZLXSjkazq50hJAO6AArVXbfonHcqHKPvFwWdaEgNZ2QGvGZ5yaE4JzNKiyJntGGX5CrGjqaqGZ-Rt43Lxh1mGgd0Gp3CzJsfZgh-wDBajBOz7WWME3SZ8r63bptJp7MdynHCQY4Yr8mFkX3Em985Jx9Pj--rl3y9eX5d3a9zBc0S8qZS2HJmJFSKK67RNBxQKlPqYklZmz4zRlLWtCjLsjUoUTe61kudRCBrNie3p7vpxc8DxlHsbVTY99KhP0TBq7KE5BWSkp-UKvgYAxoxBLuX4SiAiik-0Ym_-MQUnwBIPa0-nFYxOfmyGERUdspH24BqFNrb_498AzcNgEo</recordid><startdate>20110215</startdate><enddate>20110215</enddate><creator>Tropin, Timur V.</creator><creator>Schmelzer, Jürn W.P.</creator><creator>Schick, Christoph</creator><general>Elsevier B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QQ</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20110215</creationdate><title>On the dependence of the properties of glasses on cooling and heating rates</title><author>Tropin, Timur V. ; Schmelzer, Jürn W.P. ; Schick, Christoph</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1951-96ceb83fa16c8c8def981eacf4d2503b007ffa039bea44bfeaed9d7d5deac1a73</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Bartenev-Ritland equation</topic><topic>Cooling rate</topic><topic>Entropy</topic><topic>Entropy and entropy production</topic><topic>Glass transition temperature</topic><topic>Heating rate</topic><topic>Intervals</topic><topic>Mathematical models</topic><topic>Order parameters</topic><topic>Vitrification</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Tropin, Timur V.</creatorcontrib><creatorcontrib>Schmelzer, Jürn W.P.</creatorcontrib><creatorcontrib>Schick, Christoph</creatorcontrib><collection>CrossRef</collection><collection>Ceramic Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of non-crystalline solids</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Tropin, Timur V.</au><au>Schmelzer, Jürn W.P.</au><au>Schick, Christoph</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>On the dependence of the properties of glasses on cooling and heating rates</atitle><jtitle>Journal of non-crystalline solids</jtitle><date>2011-02-15</date><risdate>2011</risdate><volume>357</volume><issue>4</issue><spage>1291</spage><epage>1302</epage><pages>1291-1302</pages><issn>0022-3093</issn><eissn>1873-4812</eissn><abstract>The glass transition is theoretically described in terms of a generic non-equilibrium thermodynamics approach employing De Donder's structural order parameter method, appropriate expressions for the relaxation behavior of glass-forming systems and a simplified but qualitative correct model of glass-forming melts with one order parameter related to the free volume of the system. Employing this approach the behavior of a variety of thermodynamic quantities describing glass-forming systems in vitrification and devitrification processes is interpreted theoretically. The present paper is devoted to the computation of the entropy, the entropy production and the glass transition temperature in dependence on the cooling and heating rates, varying latter parameter in a broad interval. A comparison with experimental results is given and some further consequences and possible extensions are discussed briefly.
► The dependence of vitrification processes on cooling and heating rates is studied. ► Cooling and heating rates are varied hereby in broad intervals. ► The conventional definition of the glass transition temperature is analyzed. ► Limits of validity and an extension of the Bartenev-Ritland equation are discussed. ► The behaviour of the entropy and entropy production in vitrification is investigated.</abstract><pub>Elsevier B.V</pub><doi>10.1016/j.jnoncrysol.2010.11.111</doi><tpages>12</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0022-3093 |
| ispartof | Journal of non-crystalline solids, 2011-02, Vol.357 (4), p.1291-1302 |
| issn | 0022-3093 1873-4812 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_864413091 |
| source | Elsevier ScienceDirect Journals |
| subjects | Bartenev-Ritland equation Cooling rate Entropy Entropy and entropy production Glass transition temperature Heating rate Intervals Mathematical models Order parameters Vitrification |
| title | On the dependence of the properties of glasses on cooling and heating rates |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-25T04%3A38%3A19IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=On%20the%20dependence%20of%20the%20properties%20of%20glasses%20on%20cooling%20and%20heating%20rates&rft.jtitle=Journal%20of%20non-crystalline%20solids&rft.au=Tropin,%20Timur%20V.&rft.date=2011-02-15&rft.volume=357&rft.issue=4&rft.spage=1291&rft.epage=1302&rft.pages=1291-1302&rft.issn=0022-3093&rft.eissn=1873-4812&rft_id=info:doi/10.1016/j.jnoncrysol.2010.11.111&rft_dat=%3Cproquest_cross%3E864413091%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=864413091&rft_id=info:pmid/&rft_els_id=S002230931000966X&rfr_iscdi=true |