Post-irradiation relaxation in vitreous arsenic/antimony trisulphides

Instability caused by high-energy γ-irradiation was studied in (As 2S 3) 1−x(Sb 2S 3) x glasses ( x = 0, 0.1, 0.2 and 0.3) using positron annihilation lifetime spectroscopy, the obtained results being treated within a two-state trapping model. The observed decrease in the positron trapping rate of t...

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Veröffentlicht in:Journal of non-crystalline solids 2011-01, Vol.357 (2), p.487-489
Hauptverfasser: Balitska, V., Shpotyuk, Ya, Filipecki, J., Shpotyuk, O., Iovu, M.
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container_end_page 489
container_issue 2
container_start_page 487
container_title Journal of non-crystalline solids
container_volume 357
creator Balitska, V.
Shpotyuk, Ya
Filipecki, J.
Shpotyuk, O.
Iovu, M.
description Instability caused by high-energy γ-irradiation was studied in (As 2S 3) 1−x(Sb 2S 3) x glasses ( x = 0, 0.1, 0.2 and 0.3) using positron annihilation lifetime spectroscopy, the obtained results being treated within a two-state trapping model. The observed decrease in the positron trapping rate of the glasses tested just after irradiation was explained due to renovation of destroyed covalent chemical bonds. This process was governed by monomolecular relaxation kinetics agreed well with corresponding changes in fundamental optical absorption edge.
doi_str_mv 10.1016/j.jnoncrysol.2010.06.052
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source Elsevier ScienceDirect Journals Complete
subjects Antimony
Chalcogenide vitreous semiconductors
Condensed matter: structure, mechanical and thermal properties
Covalence
Cross-disciplinary physics: materials science
rheology
Exact sciences and technology
Glass
Glasses (including metallic glasses)
Instability
Materials science
Physical radiation effects, radiation damage
Physics
Positron annihilation
Positrons
Relaxation
Specific materials
Stability
Structure of liquids
Structure of solids and liquids
crystallography
Time-dependent properties
relaxation
Topological defects
Trapping
γ ray effects
title Post-irradiation relaxation in vitreous arsenic/antimony trisulphides
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