Structure of a W-enriched phase in Fe–Co–Cr–W–Ga alloys

▶ A new phase is discovered in the system of commonly employed alloys Fe–Co–Cr with small additions of W and Ga. ▶ Its structure is identified and ascribed to the specification clause. ▶ Its role in the formation of magnetic and mechanical properties in the alloys after special treatment is suggeste...

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Veröffentlicht in:Journal of alloys and compounds 2011-02, Vol.509 (5), p.1809-1814
Hauptverfasser: Ivanova, G.V., Shchegoleva, N.N., Serikov, V.V., Kleinerman, N.M., Belozerov, E.V.
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container_end_page 1814
container_issue 5
container_start_page 1809
container_title Journal of alloys and compounds
container_volume 509
creator Ivanova, G.V.
Shchegoleva, N.N.
Serikov, V.V.
Kleinerman, N.M.
Belozerov, E.V.
description ▶ A new phase is discovered in the system of commonly employed alloys Fe–Co–Cr with small additions of W and Ga. ▶ Its structure is identified and ascribed to the specification clause. ▶ Its role in the formation of magnetic and mechanical properties in the alloys after special treatment is suggested. Structure of a metastable W-enriched nanophase that is formed in Fe–Co–Cr–W–Ga alloys has been studied using X ray, electron microscopy, and Mossbauer spectroscopy methods. The phase is established to possess a body-centered-tetragonal crystal lattice with the lattice parameters а ≈ 2.96 Å, с ≈ 3.17 Å. The orientational relationships between its lattice and that of the matrix α-Fe based solid solution are determined. It is shown that the phase contains iron, tungsten, and plausibly chromium, being quite inhomogeneous in composition. Moreover, it is likely to be of a variable composition. At room temperature the phase is paramagnetic.
doi_str_mv 10.1016/j.jallcom.2010.10.046
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Structure of a metastable W-enriched nanophase that is formed in Fe–Co–Cr–W–Ga alloys has been studied using X ray, electron microscopy, and Mossbauer spectroscopy methods. The phase is established to possess a body-centered-tetragonal crystal lattice with the lattice parameters а ≈ 2.96 Å, с ≈ 3.17 Å. The orientational relationships between its lattice and that of the matrix α-Fe based solid solution are determined. It is shown that the phase contains iron, tungsten, and plausibly chromium, being quite inhomogeneous in composition. Moreover, it is likely to be of a variable composition. 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subjects Alloys
Asymptotic properties
Ferrous alloys
Lattice parameters
Mechanical properties
Metals and alloys
Mossbauer spectroscopy
Nanocomposites
Nanomaterials
Nanostructure
Precipitation
Solid solutions
Transmission electron microscopy
X ray diffraction
title Structure of a W-enriched phase in Fe–Co–Cr–W–Ga alloys
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