Transition metal complexes bearing a 2,2-bis(3,5-dimethylpyrazol-1-yl)propionate ligand: one methyl more matters
The new N,N,O ligand 2,2-bis(3,5-dimethylpyrazol-1-yl)propionic acid (2,2-Hbdmpzp) (2) and its transition metal complexes [Mn(2,2-bdmpzp)(CO)(3)] (3), [Re(2,2-bdmpzp)(CO)(3)] (4), [Cu(2,2-bdmpzp)(2)] (5), and [Ru(2,2-bdmpzp)Cl(L)(PPh(3))] [L = PPh(3) (6), N(2) (7), CO (8a/b), SO(2) (9a/b)] have been...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2011-05, Vol.40 (17), p.4678-4686 |
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| container_end_page | 4686 |
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| container_issue | 17 |
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| container_title | Dalton transactions : an international journal of inorganic chemistry |
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| creator | Türkoglu, Gazi Heinemann, Frank W Burzlaff, Nicolai |
| description | The new N,N,O ligand 2,2-bis(3,5-dimethylpyrazol-1-yl)propionic acid (2,2-Hbdmpzp) (2) and its transition metal complexes [Mn(2,2-bdmpzp)(CO)(3)] (3), [Re(2,2-bdmpzp)(CO)(3)] (4), [Cu(2,2-bdmpzp)(2)] (5), and [Ru(2,2-bdmpzp)Cl(L)(PPh(3))] [L = PPh(3) (6), N(2) (7), CO (8a/b), SO(2) (9a/b)] have been synthesized, characterized and compared to analogous complexes bearing a bis(3,5-dimethylpyrazol-1-yl)acetic acid. It was found that the additional methyl group has a remarkable influence on the stability and reactivity of transition metal complexes. |
| doi_str_mv | 10.1039/c1dt00022e |
| format | Article |
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It was found that the additional methyl group has a remarkable influence on the stability and reactivity of transition metal complexes.</description><subject>Bearing</subject><subject>Carbon monoxide</subject><subject>Coordination Complexes - chemical synthesis</subject><subject>Coordination Complexes - chemistry</subject><subject>Crystallography, X-Ray</subject><subject>Ligands</subject><subject>Molecular Conformation</subject><subject>Prints</subject><subject>Propionates - chemistry</subject><subject>Pyrazoles - chemistry</subject><subject>Stability</subject><subject>Transition Elements - chemistry</subject><subject>Transition metals</subject><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNp90ctOwzAQBVALgWgpbPgA5B0F1eBX4pgdqnhJldiUdeQkkxLkPLBdifD1pGopO1ZzF0dXoxmEzhm9YVTo25wVgVLKORygMZNKEc2FPNxnHo_QifcfG0IjfoxGnEmqOUvGqFs60_gqVG2DawjG4rytOwtf4HEGxlXNChvMZ5xklZ-KWUSKanDvve16Z75bSxjp7VXn2m6oMAGwrVamKe5w2wDeSly3bsgmBHD-FB2Vxno4280Jent8WM6fyeL16WV-vyC5YDqQvNCRFELHOk9UIspEs0yXWcZ1ISgwCjnESutEUcN4EsnMqNIIJTJaSmViLSbocts7rPa5Bh_SuvI5WGsaaNc-TWIhuZaUDnL6r2SxYlJGgxzo9ZbmrvXeQZl2rqqN61NG080v0r9fDPhi17vOaij29Pf44gc4n4QJ</recordid><startdate>20110507</startdate><enddate>20110507</enddate><creator>Türkoglu, Gazi</creator><creator>Heinemann, Frank W</creator><creator>Burzlaff, Nicolai</creator><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope></search><sort><creationdate>20110507</creationdate><title>Transition metal complexes bearing a 2,2-bis(3,5-dimethylpyrazol-1-yl)propionate ligand: one methyl more matters</title><author>Türkoglu, Gazi ; Heinemann, Frank W ; Burzlaff, Nicolai</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-cd95433969c8783f891b9fbb29d30e10ece6799870a12854ba7fa373b0f47a693</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Bearing</topic><topic>Carbon monoxide</topic><topic>Coordination Complexes - chemical synthesis</topic><topic>Coordination Complexes - chemistry</topic><topic>Crystallography, X-Ray</topic><topic>Ligands</topic><topic>Molecular Conformation</topic><topic>Prints</topic><topic>Propionates - chemistry</topic><topic>Pyrazoles - chemistry</topic><topic>Stability</topic><topic>Transition Elements - chemistry</topic><topic>Transition metals</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Türkoglu, Gazi</creatorcontrib><creatorcontrib>Heinemann, Frank W</creatorcontrib><creatorcontrib>Burzlaff, Nicolai</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Türkoglu, Gazi</au><au>Heinemann, Frank W</au><au>Burzlaff, Nicolai</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Transition metal complexes bearing a 2,2-bis(3,5-dimethylpyrazol-1-yl)propionate ligand: one methyl more matters</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><addtitle>Dalton Trans</addtitle><date>2011-05-07</date><risdate>2011</risdate><volume>40</volume><issue>17</issue><spage>4678</spage><epage>4686</epage><pages>4678-4686</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>The new N,N,O ligand 2,2-bis(3,5-dimethylpyrazol-1-yl)propionic acid (2,2-Hbdmpzp) (2) and its transition metal complexes [Mn(2,2-bdmpzp)(CO)(3)] (3), [Re(2,2-bdmpzp)(CO)(3)] (4), [Cu(2,2-bdmpzp)(2)] (5), and [Ru(2,2-bdmpzp)Cl(L)(PPh(3))] [L = PPh(3) (6), N(2) (7), CO (8a/b), SO(2) (9a/b)] have been synthesized, characterized and compared to analogous complexes bearing a bis(3,5-dimethylpyrazol-1-yl)acetic acid. It was found that the additional methyl group has a remarkable influence on the stability and reactivity of transition metal complexes.</abstract><cop>England</cop><pmid>21409218</pmid><doi>10.1039/c1dt00022e</doi><tpages>9</tpages></addata></record> |
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| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2011-05, Vol.40 (17), p.4678-4686 |
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| language | eng |
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| source | MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Bearing Carbon monoxide Coordination Complexes - chemical synthesis Coordination Complexes - chemistry Crystallography, X-Ray Ligands Molecular Conformation Prints Propionates - chemistry Pyrazoles - chemistry Stability Transition Elements - chemistry Transition metals |
| title | Transition metal complexes bearing a 2,2-bis(3,5-dimethylpyrazol-1-yl)propionate ligand: one methyl more matters |
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