Construction of Two 3D Homochiral Frameworks with 1D Chiral Pores via Chiral Recognition

Construction of Two 3D Homochiral Frameworks with 1D Chiral Pores via Chiral Recognition

The reactions of a pair of enantiomers of macrocyclic nickel(II) complexes with racemic penicillamine generated two 3D hydrogen-bonded homochiral frameworks of {[Ni(f-(SS)-L)]2(l-pends)(ClO4)2} n (Λ-1) and {[Ni(f-(RR)-L)]2(d-pends) (ClO4)2} n (Δ-1). The frameworks possess 1D tubular pores and opposi...

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Veröffentlicht in:Inorganic chemistry 2011-04, Vol.50 (8), p.3177-3179
Hauptverfasser: Li, Huan-Yong, Jiang, Long, Xiang, Hua, Makal, Tegan A., Zhou, Hong-Cai, Lu, Tong-Bu
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container_end_page 3179
container_issue 8
container_start_page 3177
container_title Inorganic chemistry
container_volume 50
creator Li, Huan-Yong
Jiang, Long
Xiang, Hua
Makal, Tegan A.
Zhou, Hong-Cai
Lu, Tong-Bu
description The reactions of a pair of enantiomers of macrocyclic nickel(II) complexes with racemic penicillamine generated two 3D hydrogen-bonded homochiral frameworks of {[Ni(f-(SS)-L)]2(l-pends)(ClO4)2} n (Λ-1) and {[Ni(f-(RR)-L)]2(d-pends) (ClO4)2} n (Δ-1). The frameworks possess 1D tubular pores and opposite right/left-handed helical porous surfaces (L = 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane; pends2− = penicillaminedisulfide anion).
doi_str_mv 10.1021/ic200264s
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title Construction of Two 3D Homochiral Frameworks with 1D Chiral Pores via Chiral Recognition
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