Construction of Two 3D Homochiral Frameworks with 1D Chiral Pores via Chiral Recognition

Construction of Two 3D Homochiral Frameworks with 1D Chiral Pores via Chiral Recognition

The reactions of a pair of enantiomers of macrocyclic nickel(II) complexes with racemic penicillamine generated two 3D hydrogen-bonded homochiral frameworks of {[Ni(f-(SS)-L)]2(l-pends)(ClO4)2} n (Λ-1) and {[Ni(f-(RR)-L)]2(d-pends) (ClO4)2} n (Δ-1). The frameworks possess 1D tubular pores and opposi...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Inorganic chemistry 2011-04, Vol.50 (8), p.3177-3179
Hauptverfasser: Li, Huan-Yong, Jiang, Long, Xiang, Hua, Makal, Tegan A., Zhou, Hong-Cai, Lu, Tong-Bu
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The reactions of a pair of enantiomers of macrocyclic nickel(II) complexes with racemic penicillamine generated two 3D hydrogen-bonded homochiral frameworks of {[Ni(f-(SS)-L)]2(l-pends)(ClO4)2} n (Λ-1) and {[Ni(f-(RR)-L)]2(d-pends) (ClO4)2} n (Δ-1). The frameworks possess 1D tubular pores and opposite right/left-handed helical porous surfaces (L = 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane; pends2− = penicillaminedisulfide anion).
ISSN:0020-1669
1520-510X
1520-510X
DOI:10.1021/ic200264s