Dirhodium-Catalyzed Phenol and Aniline Oxidations with T-HYDRO. Substrate Scope and Mechanism of Oxidation

Dirhodium caprolactamate, Rh2(cap)4, is a very efficient catalyst for the generation of the tert-butylperoxy radical from tert-butyl hydroperoxide, and the tert-butylperoxy radical is a highly effective oxidant for phenols and anilines. These reactions are performed with 70% aqueous tert-butyl hydro...

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Veröffentlicht in:	Journal of organic chemistry 2011-04, Vol.76 (8), p.2585-2593
Hauptverfasser:	Ratnikov, Maxim O, Farkas, Linda E, McLaughlin, Emily C, Chiou, Grace, Choi, Hojae, El-Khalafy, Sahar H, Doyle, Michael P
Format:	Artikel
Sprache:	eng
Schlagworte:	Amines - chemistry Aniline Compounds - chemistry Catalysis Catalysts: preparations and properties Chemistry Cyclohexenes - chemical synthesis Electrons Estrone - chemistry Exact sciences and technology Free radicals chemistry General and physical chemistry Kinetics and mechanisms Noncondensed benzenic compounds Organic chemistry Oxidants - chemistry Oxidation-Reduction Oxygen Phenols - chemistry Preparations and properties Protons Reactivity and mechanisms Rhodium - chemistry Solvents - chemistry Stereoisomerism Substrate Specificity tert-Butylhydroperoxide - chemistry Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry Water
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