High-density plasma nitriding of AISI 316L for bipolar plate in proton exchange membrane fuel cell

Austenitic stainless steel (AISI 316L) is nitrided by inductively coupled plasma using a gas mixture of N2 and H2 at temperatures between 530 K and 650 K, and the corrosion resistance as well as the interfacial contact resistance (ICR) are measured in a simulated proton exchange membrane fuel cell (...

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Veröffentlicht in:International journal of hydrogen energy 2011-02, Vol.36 (3), p.2207-2212
Hauptverfasser: Hong, Wonhyuk, Han, Dong-Hoon, Choi, Hyoseok, Kim, Min-Woo, Lee, Jung-Joong
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container_issue 3
container_start_page 2207
container_title International journal of hydrogen energy
container_volume 36
creator Hong, Wonhyuk
Han, Dong-Hoon
Choi, Hyoseok
Kim, Min-Woo
Lee, Jung-Joong
description Austenitic stainless steel (AISI 316L) is nitrided by inductively coupled plasma using a gas mixture of N2 and H2 at temperatures between 530 K and 650 K, and the corrosion resistance as well as the interfacial contact resistance (ICR) are measured in a simulated proton exchange membrane fuel cell (PEMFC) environment. After plasma nitriding, a nitrogen-expanded austenite layer, the so-called S-phase is formed in all nitrided samples. The ICR value of the nitrided samples decreases to approximately 10 mΩcm2 after plasma nitriding. The sample nitrided at 590 K shows the best corrosion property, while the corrosion resistance of the sample nitrided at higher temperatures decreases because of the formation of Cr-depleted regions in the nitrided sample. By using high-density plasma, the process temperature can be reduced to such a low temperature that Cr depletion is not significant, but a dense S-phase is formed.
doi_str_mv 10.1016/j.ijhydene.2010.11.077
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subjects Alternative fuels. Production and utilization
Applied sciences
Austenitic stainless steel
Austenitic stainless steels
Bipolar plate
Chromium
Corrosion resistance
Energy
Exact sciences and technology
Fuel cells
Fuels
Hydrogen
Inductively coupled plasma
Inductively coupled plasma (ICP)
Interfacial contact resistance (ICR)
Ion nitriding
Membranes
Plasma nitriding
Proton exchange membrane fuel cell (PEMFC)
Simulation
title High-density plasma nitriding of AISI 316L for bipolar plate in proton exchange membrane fuel cell
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