A quasi solid-state dye-sensitized solar cell made of polypyrrole counter electrodes
Quasi-solid state dye-sensitized solar cells have been constructed using nanocrystalline titania, a Ureasil-based nanocomposite gel electrolyte and polypyrrole-functionalized counter electrode. Polypyrrole was synthesized by potentiostatic electrodeposition using pyrrole monomer as precursor by a si...
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Veröffentlicht in: | Electrochimica acta 2011-02, Vol.56 (5), p.2004-2008 |
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container_end_page | 2008 |
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container_issue | 5 |
container_start_page | 2004 |
container_title | Electrochimica acta |
container_volume | 56 |
creator | Makris, Theodoros Dracopoulos, Vassilios Stergiopoulos, Thomas Lianos, Panagiotis |
description | Quasi-solid state dye-sensitized solar cells have been constructed using nanocrystalline titania, a Ureasil-based nanocomposite gel electrolyte and polypyrrole-functionalized counter electrode. Polypyrrole was synthesized by potentiostatic electrodeposition using pyrrole monomer as precursor by a simple procedure in aqueous solution. The thus obtained polypyrrole films were very robust. They were characterized by FE-SEM microscopy and electrochemical impedance spectroscopy and they were used for the construction of solar cells. The employment of polypyrrole electrocatalyst was judged satisfactory for the present application since it was only 30% less efficient than the corresponding counter electrodes functionalized with Pt. |
doi_str_mv | 10.1016/j.electacta.2010.11.076 |
format | Article |
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Polypyrrole was synthesized by potentiostatic electrodeposition using pyrrole monomer as precursor by a simple procedure in aqueous solution. The thus obtained polypyrrole films were very robust. They were characterized by FE-SEM microscopy and electrochemical impedance spectroscopy and they were used for the construction of solar cells. 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The employment of polypyrrole electrocatalyst was judged satisfactory for the present application since it was only 30% less efficient than the corresponding counter electrodes functionalized with Pt.</description><subject>Applied sciences</subject><subject>Construction</subject><subject>Dye-sensitized solar cell</subject><subject>Dyes</subject><subject>Electrodes</subject><subject>Energy</subject><subject>Exact sciences and technology</subject><subject>Gel electrolyte</subject><subject>Nanostructure</subject><subject>Natural energy</subject><subject>Photovoltaic cells</subject><subject>Photovoltaic conversion</subject><subject>Polypyrrole</subject><subject>Polypyrroles</subject><subject>Solar cells</subject><subject>Solar cells. Photoelectrochemical cells</subject><subject>Solar energy</subject><subject>Titanium dioxide</subject><subject>Ureasil</subject><issn>0013-4686</issn><issn>1873-3859</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNqFkE1rwzAMhs3YYN3Hb5gvY6d0dpzY8bGUfUFhl-5sXEcBlzROrWTQ_fo5a-l1IBBIj_RKLyEPnM054_J5O4cW3GBTzHM2VfmcKXlBZrxSIhNVqS_JjDEuskJW8prcIG4ZS4hiM7Je0P1o0VMMra8zHOwAtD5AhtChH_wP1FPLRuqgbenO1kBDQ_vQHvpDjKEF6sLYDRDp3xkx1IB35KqxLcL9Kd-Sr9eX9fI9W32-fSwXq8wJpYbMcW1rxSyXuS0EbxqhbAEbqSUoyyrIU7HKyw0UkuUKtKjUJtfKKa3T42UlbsnTcW8fw34EHMzO43Sn7SCMaCrJS6kZE4lUR9LFgBihMX30OxsPhjMz2Wi25myjmWw0nJvkUZp8PGlYdLZtou2cx_N4LnShRMkTtzhykB7-9hANOg-dg9rHtNfUwf-r9Qsq9YyY</recordid><startdate>20110201</startdate><enddate>20110201</enddate><creator>Makris, Theodoros</creator><creator>Dracopoulos, Vassilios</creator><creator>Stergiopoulos, Thomas</creator><creator>Lianos, Panagiotis</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20110201</creationdate><title>A quasi solid-state dye-sensitized solar cell made of polypyrrole counter electrodes</title><author>Makris, Theodoros ; Dracopoulos, Vassilios ; Stergiopoulos, Thomas ; Lianos, Panagiotis</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c377t-c19ad70a162a431ff37a4eb696e7a08e2431825be46027e9387b297c799016583</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Applied sciences</topic><topic>Construction</topic><topic>Dye-sensitized solar cell</topic><topic>Dyes</topic><topic>Electrodes</topic><topic>Energy</topic><topic>Exact sciences and technology</topic><topic>Gel electrolyte</topic><topic>Nanostructure</topic><topic>Natural energy</topic><topic>Photovoltaic cells</topic><topic>Photovoltaic conversion</topic><topic>Polypyrrole</topic><topic>Polypyrroles</topic><topic>Solar cells</topic><topic>Solar cells. Photoelectrochemical cells</topic><topic>Solar energy</topic><topic>Titanium dioxide</topic><topic>Ureasil</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Makris, Theodoros</creatorcontrib><creatorcontrib>Dracopoulos, Vassilios</creatorcontrib><creatorcontrib>Stergiopoulos, Thomas</creatorcontrib><creatorcontrib>Lianos, Panagiotis</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Electrochimica acta</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Makris, Theodoros</au><au>Dracopoulos, Vassilios</au><au>Stergiopoulos, Thomas</au><au>Lianos, Panagiotis</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A quasi solid-state dye-sensitized solar cell made of polypyrrole counter electrodes</atitle><jtitle>Electrochimica acta</jtitle><date>2011-02-01</date><risdate>2011</risdate><volume>56</volume><issue>5</issue><spage>2004</spage><epage>2008</epage><pages>2004-2008</pages><issn>0013-4686</issn><eissn>1873-3859</eissn><coden>ELCAAV</coden><abstract>Quasi-solid state dye-sensitized solar cells have been constructed using nanocrystalline titania, a Ureasil-based nanocomposite gel electrolyte and polypyrrole-functionalized counter electrode. Polypyrrole was synthesized by potentiostatic electrodeposition using pyrrole monomer as precursor by a simple procedure in aqueous solution. The thus obtained polypyrrole films were very robust. They were characterized by FE-SEM microscopy and electrochemical impedance spectroscopy and they were used for the construction of solar cells. The employment of polypyrrole electrocatalyst was judged satisfactory for the present application since it was only 30% less efficient than the corresponding counter electrodes functionalized with Pt.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.electacta.2010.11.076</doi><tpages>5</tpages></addata></record> |
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source | ScienceDirect Journals (5 years ago - present) |
subjects | Applied sciences Construction Dye-sensitized solar cell Dyes Electrodes Energy Exact sciences and technology Gel electrolyte Nanostructure Natural energy Photovoltaic cells Photovoltaic conversion Polypyrrole Polypyrroles Solar cells Solar cells. Photoelectrochemical cells Solar energy Titanium dioxide Ureasil |
title | A quasi solid-state dye-sensitized solar cell made of polypyrrole counter electrodes |
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