Large Magnetocaloric Effect in a Wells-Dawson Type {Ni6Gd6P6} Cage

Cool stuff: The usage of phosphonates has led to formation of a family of 3d–4f heterometallic cages with a Wells–Dawson‐like structure (see picture; Gd, Dy, or Y purple; Ni cyan; P green; O orange; C gray). Magnetic studies show ferromagnetic interactions within the oxo‐centered nickel triangle and...

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Veröffentlicht in:	Angewandte Chemie International Edition 2011-04, Vol.50 (16), p.3692-3695
Hauptverfasser:	Zheng, Yan-Zhen, Evangelisti, Marco, Winpenny, Richard E. P.
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Sprache:	eng
Schlagworte:	cage molecules magnetocaloric effect molecular refrigerants phosphonates polyoxometalates
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description	Cool stuff: The usage of phosphonates has led to formation of a family of 3d–4f heterometallic cages with a Wells–Dawson‐like structure (see picture; Gd, Dy, or Y purple; Ni cyan; P green; O orange; C gray). Magnetic studies show ferromagnetic interactions within the oxo‐centered nickel triangle and huge entropy change in the Gd analogue, which, in principle, can be used as an ultralow‐temperature coolant.
doi_str_mv	10.1002/anie.201008074
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subjects	cage molecules magnetocaloric effect molecular refrigerants phosphonates polyoxometalates
title	Large Magnetocaloric Effect in a Wells-Dawson Type {Ni6Gd6P6} Cage
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