Hydrogeological and biogeochemical constrains of arsenic mobilization in shallow aquifers from the Hetao basin, Inner Mongolia

Little is known about the importance of drainage/irrigation channels and biogeochemical processes in arsenic distribution of shallow groundwaters from the Hetao basin. This investigation shows that although As concentrations are primarily dependent on reducing conditions, evaporation increases As concentration in the centre of palaeo-lake sedimentation. Near drainage channels, groundwater As concentrations are the lowest in suboxic-weakly reducing conditions. Results demonstrate that both drainage and irrigation channels produce oxygen-rich water that recharges shallow groundwaters and therefore immobilize As. Groundwater As concentration increases with a progressive decrease in redox potential along the flow path in an alluvial fan. A negative correlation between SO 4 2− concentrations and δ 34S values indicates that bacterial reduction of SO 4 2− occurs in reducing aquifers. Due to high concentrations of Fe (>0.5 mg L −1), reductive dissolution of Fe oxides is believed to cause As release from aquifer sediments. Target aquifers for safe drinking water resources are available in alluvial fans and near irrigation channels. ► Low As groundwaters occur in alluvial fans. ► We find low As groundwaters near irrigation and drainage channels. ► Both hydrogeologic conditions and biogeochemical processes control As distribution. Both hydrogeologic conditions and biogeochemical processes control As distribution of shallow groundwaters, which results in the occurrence of low As groundwater in alluvial fans and near irrigation channels and drainage channels.