Titanium(IV) Dioxide Surface-Modified with Iron Oxide as a Visible Light Photocatalyst

The light fandango: Anatase and anatase–rutile composite TiO2 has been modified electronically with highly dispersed surface iron oxide species. The chemisorption–calcination cycle technique was used with [Fe(acac)3] as a precursor (acac=acetylacetonate), leading to pronounced visible‐light activity...

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Veröffentlicht in:Angewandte Chemie International Edition 2011-04, Vol.50 (15), p.3501-3505
Hauptverfasser: Tada, Hiroaki, Jin, Qiliang, Nishijima, Hiroaki, Yamamoto, Hironori, Fujishima, Musashi, Okuoka, Shin-ichi, Hattori, Takanori, Sumida, Yasutaka, Kobayashi, Hisayoshi
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container_issue 15
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container_title Angewandte Chemie International Edition
container_volume 50
creator Tada, Hiroaki
Jin, Qiliang
Nishijima, Hiroaki
Yamamoto, Hironori
Fujishima, Musashi
Okuoka, Shin-ichi
Hattori, Takanori
Sumida, Yasutaka
Kobayashi, Hisayoshi
description The light fandango: Anatase and anatase–rutile composite TiO2 has been modified electronically with highly dispersed surface iron oxide species. The chemisorption–calcination cycle technique was used with [Fe(acac)3] as a precursor (acac=acetylacetonate), leading to pronounced visible‐light activity and a concomitant increase in activity under illumination with UV light (cb=conduction band, vb=valence band).
doi_str_mv 10.1002/anie.201007869
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source Wiley Online Library All Journals
subjects electron transfer
iron oxide
photocatalysis
surface modification
TiO2
title Titanium(IV) Dioxide Surface-Modified with Iron Oxide as a Visible Light Photocatalyst
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