Gold-Catalyzed Direct Amination of Arenes with Azodicarboxylates
Gold(III) chloride catalyzed direct amination of arenes with azodicarboxylates was developed. The new catalytic system was active to a broad range of substrates, and the reaction was carried out under mild conditions. It represents the first catalytic system for the direct amination of electron-defi...
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| Veröffentlicht in: | Organic letters 2011-04, Vol.13 (7), p.1872-1874 |
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| container_end_page | 1874 |
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| container_issue | 7 |
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| container_title | Organic letters |
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| creator | Gu, Liuqun Neo, Boon Siong Zhang, Yugen |
| description | Gold(III) chloride catalyzed direct amination of arenes with azodicarboxylates was developed. The new catalytic system was active to a broad range of substrates, and the reaction was carried out under mild conditions. It represents the first catalytic system for the direct amination of electron-deficient arenes with azodicarboxylates to the best of our knowledge. This reaction provides an important approach for the synthesis of heterocyclic compounds in pharmaceutical and chemical industries. |
| doi_str_mv | 10.1021/ol200373q |
| format | Article |
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| fulltext | fulltext |
| identifier | ISSN: 1523-7060 |
| ispartof | Organic letters, 2011-04, Vol.13 (7), p.1872-1874 |
| issn | 1523-7060 1523-7052 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_858780244 |
| source | MEDLINE; ACS Publications |
| subjects | Amination Azo Compounds - chemistry Catalysis Dicarboxylic Acids - chemistry Gold - chemistry Molecular Structure |
| title | Gold-Catalyzed Direct Amination of Arenes with Azodicarboxylates |
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