Enantioselective/Anion-Selective Incorporation of Tris(ethylenediamine) Complexes into 2D Coordination Spaces between Tripalladium(II) Supramolecular Layers with d-Penicillaminate

The formation of a cocrystallized coordination compound, [Pd3(d-pen)3]2·[M(en)3](ClO4)3 (d-H2pen = d-penicillamine; M = CoIII or RhIII), from [Pd3(d-pen)3] and [M(en)3](ClO4)3 is reported. In this compound, only the Δ-configurational [M(en)3]3+ cations were incorporated when its racemic (Δ/Λ) isomer...

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Veröffentlicht in:	Inorganic chemistry 2011-03, Vol.50 (6), p.2040-2042
Hauptverfasser:	Hirai, Yusuke, Nagao, Yoshinori, Igashira-Kamiyama, Asako, Konno, Takumi
Format:	Artikel
Sprache:	eng
Schlagworte:	Anions - chemistry Crystallography, X-Ray Ethylenediamines - chemistry Macromolecular Substances - chemical synthesis Macromolecular Substances - chemistry Models, Molecular Molecular Structure Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry Palladium - chemistry Penicillamine - chemistry Stereoisomerism
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